Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userRoom Temperature Light-Mediated Long-Range Coupling of Excitons in Perovskites
70
0
0.0
(
0
)
Added by
I Wayan Gede Tanjung Krisnanda
Publication date
2021
fields
Physics
and research's language is
English
Ask ChatGPT about the research
No Arabic abstract
Perovskites have been the focus of attention due to their multitude of outstanding optoelectronic properties and structural versatility. Two-dimensional halide perovskite such as (C_6H_5C_2H_4NH_3)_2PbI_4, or simply PEPI, forms natural multiple quantum wells with enhanced light-matter interactions, making them attractive systems for further investigation. This work reports tunable splitting of exciton modes in PEPI resulting from strong light-matter interactions, manifested as multiple dips (modes) in the reflection spectra. While the origin of the redder mode is well understood, that for the bluer dip at room temperature is still lacking. Here, it is revealed that the presence of the multiple modes originates from an indirect coupling between excitons in different quantum wells. The long-range characteristic of the mediated coupling between excitons in distant quantum wells is also demonstrated in a structure design along with its tunability. Moreover, a device architecture involving an end silver layer enhances the two excitonic modes and provides further tunability. Importantly, this work will motivate the possibility of coupling of the excitonic modes with a confined light mode in a microcavity to produce multiple exciton-polariton modes.
rate research
Read More
We propose a method for nano-scale characterization of long range magnetic order in diluted magnetic systems to clarify the origins of the room temperature ferromagnetism. The GaN:Mn thin films are grown by metal-organic chemical vapor deposition with the concentration of Ga-substitutional Mn up to 3.8%. Atomic force microscope (AFM) and magnetic force microscope (MFM) characterizations are performed on etched artificial microstructures and natural dislocation pits. Numerical simulations and theoretical analysis on the AFM and MFM data have confirmed the formation of long range magnetic order and ruled out the possibility that nano-clusters contributed to the ferromagnetism. We suggest that delocalized electrons might play a role in the establishment of this long range magnetic order.
Excitonic stimulated emission provides a promising mechanism and route to achieve low-threshold semiconductor lasers for micro-nano optoelectronic integrations. However, excitonic stimulated emission from quantum structure-free semiconductors has rarely been realised at room temperature due to the phase transition between excitonic and electron-hole plasma states. Herein, we show that through trap-state and band-edge engineering, bound exciton states can be stabilised within the hybrid lead bromide perovskite. Under modest pumping conditions, these states enable stimulated emission behaviour that exhibits a low threshold carrier density of only 1.6*1017 cm-3, as well as a high peak gain coefficient of ~1300 cm-1. This is the first time that bound exciton stimulated emission has been realised at room temperature from a quantum structure-free semiconductor. Not only does this open up new research horizons for perovskite materials, but also it has important implications for semiconductor excitonic physics and the development of next-generation optoelectronic applications.
Coulomb bound electron-hole pairs, excitons, govern the optical properties of semi-conducting transition metal dichalcogenides like MoS$_2$ and WSe$_2$. We study optical transitions at the K-point for 2H homobilayer MoS$_2$ in Density Functional Theory (DFT) including excitonic effects and compare with reflectivity measurements in high quality samples encapsulated in hexagonal BN. In both calculated and measured spectra we find a strong interlayer exciton transition in energy between A and B intralayer excitons, observable for T$=4 -300$ K, whereas no such transition is observed for the monolayer in the same structure in this energy range. The interlayer excitons consist of an electron localized in one layer and a hole state delocalized over the bilayer, which results in the unusual combination of high oscillator strength and a static dipole moment. We also find signatures of interlayer excitons involving the second highest valence band (B) and compare absorption calculations for different bilayer stackings. For homotrilayer MoS$_2$ we also observe interlayer excitons and an energy splitting between different intralayer A-excitons originating from the middle and outer layers, respectively.
The time-window for processing electron spin information (spintronics) in solid-state quantum electronic devices is determined by the spin-lattice (T1) and spin-spin (T2) relaxation times of electrons. Minimising the effects of spin-orbit coupling and the local magnetic contributions of neighbouring atoms on T1 and T2 at room temperature remain substantial challenges to practical spintronics. Here, we report a record-high conduction electron T1=T2 of 175 ns at 300 K in 37 nm +/- 7 nm carbon spheres, which exceeds by far the highest values observed for any conducting solid state material of comparable size. The long T1=T2 is due to quantum confinement effects, to the intrinsically weak spin-orbit coupling of carbon, and to the protecting nature of the outer shells of the inner spins from the influences of environmental disturbances. Following the observation of spin polarization by electron spin resonance, we controlled the quantum state of the electron spin by applying short bursts of an oscillating magnetic field and observed coherent oscillations of the spin state. These results demonstrate the feasibility of operating electron spins in conducting carbon nanospheres as quantum bits at room temperature.
Room temperature strong coupling of WS_2 monolayer exciton transitions to metallic Fabry-Perot and plasmonic optical cavities is demonstrated. A Rabi splitting of 101 meV is observed for the Fabry-Perot cavity, more than double those reported to date in other 2D materials. The enhanced magnitude and visibility of WS_2 monolayer strong coupling is attributed to the larger absorption coefficient, the narrower linewidth of the A exciton transition, and greater spin-orbit coupling. For WS_2 coupled to plasmonic arrays, the Rabi splitting still reaches 60 meV despite the less favorable coupling conditions, and displays interesting photoluminescence features. The unambiguous signature of WS_2 monolayer strong coupling in easily fabricated metallic resonators at room temperature suggests many possibilities for combining light-matter hybridization with spin and valleytronics.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
