No Arabic abstract
Unconventional superconductivity and in particular triplet superconductivity have been front and center of topological materials and quantum technology research. Here we report our observation of triplet superconductivity in nonmagnetic CoSi$_2$/TiSi$_2$ heterostructures on silicon. CoSi$_2$ undergoes a sharp superconducting transition at a critical temperature $T_c approx$ 1.5 K, while TiSi$_2$ is a normal metal. We investigate conductance spectra of both two-terminal CoSi$_2$/TiSi$_2$ tunnel junctions and three-terminal T-shaped CoSi$_2$/TiSi$_2$ superconducting proximity structures. We report an unexpectedly large spin-orbit coupling in CoSi$_2$ heterostructures. Below $T_c$, we observe (1) a narrow zero-bias conductance peak on top of a broad hump, accompanied by two symmetric side dips in the tunnel junctions, (2) a narrow zero-bias conductance peak in T-shaped structures, and (3) hysteresis in the junction magnetoresistance. These three independent and complementary observations are indicative of chiral $p$-wave pairing in CoSi$_2$/TiSi$_2$ heterostructures. This chiral triplet superconductivity and the excellent fabrication compatibility of CoSi$_2$ and TiSi$_2$ with present-day silicon integrated-circuit technology facilitate full scalability for potential use in quantum-computing devices.
Coupling between $sigma$-bonding electrons and phonons is generally very strong. To metallize $sigma$-electrons provides a promising route to hunt for new high-T$_c$ superconductors. Based on this picture and first-principles density functional calculation with Wannier interpolation for electronic structure and lattice dynamics, we predict that trilayer film LiB$_2$C$_2$ is a good candidate to realize this kind of high-T$_c$ superconductivity. By solving the anisotropic Eliashberg equations, we find that free-standing trilayer LiB$_2$C$_2$ is a phonon-mediated superconductor with T$_c$ exceeding the liquid-nitrogen temperature at ambient pressure. The transition temperature can be further raised to 125 K by applying a biaxial tensile strain.
Using van der Waals tunnel junctions, we perform spectroscopy of superconducting $mathrm{NbSe_2}$ flakes, of thicknesses ranging from 2--25 monolayers, measuring the quasiparticle density of states as a function of applied in-plane magnetic field up to 33T. In flakes up to $approx$ 15 monolayers thick, we find that the density of states is well-described by a single band superconductor. In these thin samples, the magnetic field acts primarily on the spin (vs orbital) degree of freedom of the electrons, and superconductivity is further protected by Ising spin-orbit coupling (ISOC), which pins Cooper pair spins out-of-plane. The superconducting energy gap, extracted from our tunnelling spectra, decreases as a function of the applied magnetic field. However, in bilayer $mathrm{NbSe_2}$, close to the critical field (up to 30T, much larger than the Pauli limit), superconductivity appears to be even more robust than expected if only ISOC is considered. This can be explained by a predicted subdominant triplet component of the order parameter, coupled to the dominant singlet component at finite field. This equal-spin, odd-parity triplet state arises from the non-colinearity between the applied magnetic field and the Ising field.
Interlayer excitons (IXs) possess a much longer lifetime than intralayer excitons due to the spatial separation of the electrons and holes; hence, they have been pursued to create exciton condensates for decades. The recent emergence of two-dimensional (2D) materials, such as transition metal dichalcogenides (TMDs), and of their van der Waals heterostructures (HSs), in which two different 2D materials are layered together, has created new opportunities to study IXs. Here we present the observation of IX gases within two stacked structures consisting of hBN/WSe$_2$/hBN/p: WSe$_2$/hBN. The IX energy of the two different structures differed by 82 meV due to the different thickness of the hBN spacer layer between the TMD layers. We demonstrate that the lifetime of the IXs is shortened when the temperature and the pump power increase. We attribute this nonlinear behavior to an Auger process.
Nuclear magnetic resonance (NMR) measurements on the $^{195}$Pt nucleus in an aligned powder of the moderately heavy-fermion material U2PtC2 are consistent with spin-triplet pairing in its superconducting state. Across the superconducting transition temperature and to much lower temperatures, the NMR Knight shift is temperature independent for field both parallel and perpendicular to the tetragonal c-axis, expected for triplet equal-spin pairing superconductivity. The NMR spin-lattice relaxation rate 1/T$_1$, in the normal state, exhibits characteristics of ferromagnetic fluctuations, compatible with an enhanced Wilson ratio. In the superconducting state, 1/T$_1$ follows a power law with temperature without a coherence peak giving additional support that U$_2$PtC$_2$ is an unconventional superconductor. Bulk measurements of the AC-susceptibility and resistivity indicate that the upper critical field exceeds the Pauli limiting field for spin-singlet pairing and is near the orbital limiting field, an additional indication for spin-triplet pairing.
Despite growing interest in them, highly crystalline two-dimensional superconductors derived from exfoliated layered materials are few. Employing the anisotropic Migdal-Eliashberg formalism based on {it ab initio} calculations, we find monolayer NiTe$_{2}$ to be an intrinsic superconductor with a $T_{text c}sim$5.7~K, although the bulk crystal is not known to superconduct. Remarkably, bilayer NiTe$_{2}$ intercalated with lithium is found to display two-gap superconductivity with a critical temperature $T_{text{c}}sim 11.3$~K and superconducting gap of $sim$3.1~meV, arising from a synergy of electronic and phononic effects. The comparatively high $T_text{c}$, substrate independence and proximity tunability will make these superconductors ideal platforms for exploring intriguing correlation effects and quantum criticality associated two-dimensional superconductivity.