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Register a new userCosmic ray dissociation of molecular hydrogen and dense cloud chemistry
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Dissociation of molecular hydrogen by secondary electrons produced by cosmic ray or X-ray ionization plays a crucial role in the chemistry of the densest part of molecular clouds. Here we study the effect of the mean kinetic energy of secondary electrons on this process. We compare predictions using a range of secondary electron energies and predictions of the cross-sections with the values in the UMIST database. We find that the predicted column densities change by nearly one dex.
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Cosmic rays pervade the Galaxy and are thought to be accelerated in supernova shocks. The interaction of cosmic rays with dense interstellar matter has two important effects: 1) high energy (>1 GeV) protons produce {gamma}-rays by {pi}0-meson decay; 2) low energy (< 1 GeV) cosmic rays (protons and electrons) ionize the gas. We present here new observations towards a molecular cloud close to the W51C supernova remnant and associated with a recently discovered TeV {gamma}-ray source. Our observations show that the cloud ionization degree is highly enhanced, implying a cosmic ray ionization rate ~ 10-15 s-1, i.e. 100 times larger than the standard value in molecular clouds. This is consistent with the idea that the cloud is irradiated by an enhanced flux of freshly accelerated low-energy cosmic rays. In addition, the observed high cosmic ray ionization rate leads to an instability in the chemistry of the cloud, which keeps the electron fraction high, ~ 10-5, in a large fraction (Av geq 6mag) of the cloud and low, ~ 10-7, in the interior. The two states have been predicted in the literature as high- and low-ionization phases (HIP and LIP). This is the observational evidence of their simultaneous presence in a cloud.
The local cosmic-ray (CR) spectra are calculated for typical characteristic regions of a cold dense molecular cloud, to investigate two so far neglected mechanisms of dust charging: collection of suprathermal CR electrons and protons by grains, and photoelectric emission from grains due to the UV radiation generated by CRs. The two mechanisms add to the conventional charging by ambient plasma, produced in the cloud by CRs. We show that the CR-induced photoemission can dramatically modify the charge distribution function for submicron grains. We demonstrate the importance of the obtained results for dust coagulation: While the charging by ambient plasma alone leads to a strong Coulomb repulsion between grains and inhibits their further coagulation, the combination with the photoemission provides optimum conditions for the growth of large dust aggregates in a certain region of the cloud, corresponding to the densities $n(mathrm{H_2})$ between $sim10^4$ cm$^{-3}$ and $sim10^6$ cm$^{-3}$. The charging effect of CR is of generic nature, and therefore is expected to operate not only in dense molecular clouds but also in the upper layers and the outer parts of protoplanetary discs.
Molecular clouds are complex magnetized structures, with variations over a broad range of length scales. Ionization in dense, shielded clumps and cores of molecular clouds is thought to be caused by charged cosmic rays (CRs). These CRs can also contribute to heating the gas deep within molecular clouds, and their effect can be substantial in environments where CRs are abundant. CRs propagate predominantly by diffusion in media with disordered magnetic fields. The complex magnetic structures in molecular clouds therefore determine the propagation and spatial distribution of CRs within them, and hence regulate their local ionization and heating patterns. Optical and near-infrared (NIR) polarization of starlight through molecular clouds is often used to trace magnetic fields. The coefficients of CR diffusion in magnetized molecular cloud complexes can be inferred from the observed fluctuations in these optical/NIR starlight polarisations. Here, we present calculations of the expected CR heating patterns in the star-forming filaments of IC 5146, determined from optical/NIR observations. Our calculations show that local conditions give rise to substantial variation in CR propagation. This affects the local CR heating power. Such effects are expected to be severe in star-forming galaxies rich in CRs. The molecular clouds in these galaxies could evolve differently to those in galaxies where CRs are less abundant.
Diatomic nitrogen is an archetypal molecular system known for its exceptional stability and complex behavior at high pressures and temperatures, including rich solid polymorphism, formation of energetic states, and an insulator-to-metal transformation coupled to a change in chemical bonding. However, the thermobaric conditions of the fluid molecular-polymer phase boundary and associated metallization have not been experimentally established. Here, by applying dynamic laser heating of compressed nitrogen and using fast optical spectroscopy to study electronic properties, we observe a transformation from insulating (molecular) to conducting dense fluid nitrogen at temperatures that decrease with pressure, and establish that metallization, and presumably fluid polymerization, occurs above 125 GPa at 2500 K. Our observations create a better understanding of the interplay between molecular dissociation, melting, and metallization revealing features that are common in simple molecular systems.
Molecular clouds are a fundamental ingredient of galaxies: they are the channels that transform the diffuse gas into stars. The detailed process of how they do it is not completely understood. We review the current knowledge of molecular clouds and their substructure from scales $sim~$1~kpc down to the filament and core scale. We first review the mechanisms of cloud formation from the warm diffuse interstellar medium down to the cold and dense molecular clouds, the process of molecule formation and the role of the thermal and gravitational instabilities. We also discuss the main physical mechanisms through which clouds gather their mass, and note that all of them may have a role at various stages of the process. In order to understand the dynamics of clouds we then give a critical review of the widely used virial theorem, and its relation to the measurable properties of molecular clouds. Since these properties are the tools we have for understanding the dynamical state of clouds, we critically analyse them. We finally discuss the ubiquitous filamentary structure of molecular clouds and its connection to prestellar cores and star formation.
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