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Diffusion of Fractal Particles in a Fractal Fluid

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 Added by Marco Heinen
 Publication date 2020
  fields Physics
and research's language is English
 Authors Marco Heinen




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Anomalous short- and long-time self-diffusion of non-overlapping fractal particles on a percolation cluster with spreading dimension $1.67(2)$ is studied by dynamic Monte Carlo simulations. As reported in Phys. Rev. Lett. 115, 097801 (2015), the disordered phase formed by these particles is that of an unconfined, homogeneous and monodisperse fluid in fractal space. During particle diffusion in thermodynamic equilibrium, the mean squared chemical displacement increases as a nonlinear power of time, with an exponent of $0.96(1)$ at short times and $0.63(1)$ at long times. At finite packing fractions the steric hindrance among nearest neighbor particles leads to a sub-diffusive regime that separates short-time anomalous diffusion from long-time anomalous diffusion. Particle localization is observed over eight decades in time for packing fractions of $sim 60%$ and higher.

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An exact analytical analysis of anomalous diffusion on a fractal mesh is presented. The fractal mesh structure is a direct product of two fractal sets which belong to a main branch of backbones and side branch of fingers. The fractal sets of both backbones and fingers are constructed on the entire (infinite) $y$ and $x$ axises. To this end we suggested a special algorithm of this special construction. The transport properties of the fractal mesh is studied, in particular, subdiffusion along the backbones is obtained with the dispersion relation $langle x^2(t)ranglesim t^{beta}$, where the transport exponent $beta<1$ is determined by the fractal dimensions of both backbone and fingers. Superdiffusion with $beta>1$ has been observed as well when the environment is controlled by means of a memory kernel.
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