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Register a new userInfrared detection of aliphatic organics on a cometary nucleus
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The ESA Rosetta mission has acquired unprecedented measurements of comet 67/P-Churyumov-Gerasimenko (hereafter 67P) nucleus surface, whose composition, as determined by in situ and remote sensing instruments including VIRTIS (Visible, InfraRed and Thermal Imaging Spectrometer) appears to be made by an assemblage of ices, minerals, and organic material. We performed a refined analysis of infrared observations of the nucleus of comet 67P carried out by the VIRTIS-M hyperspectral imager. We found that the overall shape of the 67P infrared spectrum is similar to that of other carbon-rich outer solar system objects suggesting a possible genetic link with them. More importantly, we are also able to confirm the complex spectral structure of the wide 2.8-3.6 micron absorption feature populated by fainter bands. Among these, we unambiguously identified the presence of aliphatic organics by their ubiquitous 3.38, 3.42 and 3.47 micron bands. This novel infrared detection of aliphatic species on a cometary surface has strong implications for the evolutionary history of the primordial solar system and give evidence that comets provide an evolutionary link between interstellar material and solar system bodies.
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We present an analysis of high-resolution spectroscopy of several bright T Tauri stars using the VLT/CRIRES and Keck/NIRSPEC spectrographs, revealing the first detections of emission from HCN and C2H2 in circumstellar disks at near-infrared wavelengths. Using advanced data reduction techniques we achieve a dynamic range with respect to the disk continuum of ~500 at 3 microns, revealing multiple emission features of H2O, OH, HCN, and C2H2. We also present stringent upper limits for two other molecules thought to be abundant in the inner disk, CH4 and NH3. Line profiles for the different detected molecules are broad but centrally peaked in most cases, even for disks with previously determined inclinations of greater than 20 degrees, suggesting that the emission has both a Keplerian and non-Keplerian component as observed previously for CO emission. We apply two different modeling strategies to constrain the molecular abundances and temperatures: we use a simplified single-temperature LTE slab model with a Gaussian line profile to make line identifications and determine a best-fit temperature and initial abundance ratios, and we compare these values with constraints derived from a detailed disk radiative transfer model assuming LTE excitation but utilizing a realistic temperature and density structure. Abundance ratios from both sets of models are consistent with each other and consistent with expected values from theoretical chemical models, and analysis of the line shapes suggests the molecular emission originates from within a narrow region in the inner disk (R < 1 AU).
The measured nitrogen-to-carbon ratio in comets is lower than for the Sun, a discrepancy which could be alleviated if there is an unknown reservoir of nitrogen in comets. The nucleus of comet 67P/Churyumov-Gerasimenko exhibits an unidentified broad spectral reflectance feature around 3.2 micrometers, which is ubiquitous across its surface. On the basis of laboratory experiments, we attribute this absorption band to ammonium salts mixed with dust on the surface. The depth of the band indicates that semivolatile ammonium salts are a substantial reservoir of nitrogen in the comet, potentially dominating over refractory organic matter and more volatile species. Similar absorption features appear in the spectra of some asteroids, implying a compositional link between asteroids, comets, and the parent interstellar cloud.
We study the visible and near-infrared (NIR) spectral properties of different ACO populations and compare them to the independently determined properties of comets. We select our ACOs sample based on published dynamical criteria and present our own observational results obtained using the 10.4m Gran Telescopio Canarias (GTC), the 4.2m William Herschel Telescope (WHT), the 3.56m Telescopio Nazionale Galileo (TNG), and the 2.5m Isaac Newton Telescope (INT), all located at the El Roque de los Muchachos Observatory (La Palma, Spain), and the 3.0m NASA Infrared Telescope Facility (IRTF), located at the Mauna Kea Observatory, in Hawaii. We include in the analysis the spectra of ACOs obtained from the literature. We derive the spectral class and the visible and NIR spectral slopes. We also study the presence of hydrated minerals by studying the 0.7 $mu$m band and the UV-drop below 0.5 $mu$m associated with phyllosilicates. We present new observations of 17 ACOs, 11 of them observed in the visible, 2 in the NIR and 4 in the visible and NIR. We also discuss the spectra of 12 ACOs obtained from the literature. All but two ACOs have a primitive-like class spectrum (X or D-type). Almost 100% of the ACOs in long-period cometary orbits (Damocloids) are D-types. Those in Jupiter family comet orbits (JFC-ACOs) are $sim$ 60% D-types and $sim$ 40% X-types. The mean spectral slope $S$ of JFC-ACOs is 9.7 $pm$ 4.6 %/1000 AA and for the Damocloids this is 12.2 $pm$ 2.0 %/1000 AA . No evidence of hydration on the surface of ACOs is found from their visible spectra. The slope and spectral class distribution of ACOs is similar to that of comets. The spectral classification, the spectral slope distribution of ACOs, and the lack of spectral features indicative of the presence of hydrated minerals on their surface, strongly suggest that ACOs are likely dormant or extinct comets.
Complex organics are now commonly found in meteorites, comets, asteroids, planetary satellites, and interplanetary dust particles. The chemical composition and possible origin of these organics are presented. Specifically, we discuss the possible link between Solar System organics and the complex organics synthesized during the late stages of stellar evolution. Implications of extraterrestrial organics on the origin of life on Earth and the possibility of existence of primordial organics on Earth are also discussed.
We have obtained new NASA IRTF SpeX spectra of the HR 4796A debris ring system. We find a unique red excess flux that extends out to ~9 um in Spitzer IRS spectra, where thermal emission from cold, ~100K dust from the systems ring at ~75 AU takes over. Matching imaging ring photometry, we find the excess consists of NIR reflectance from the ring which is as red as that of old, processed comet nuclei, plus a tenuous thermal emission component from close-in, T ~ 850 K circumstellar material evincing an organic plus silicate emission feature complex at 7 - 13 um. Unusual, emission-like features due to atomic Si, S, Ca, and Sr were found at 0.96 - 1.07 um, likely sourced by rocky dust evaporating in the 850 K component. An empirical cometary dust phase function can reproduce the scattered light excess and 1:5 balance of scattered vs. thermal energy for the ring with optical depth Tau > 0.10 in an 8 AU wide belt of 4 AU vertical height and Mdust > 0.1-0.7 M_Mars. Our results are consistent with HR 4796A consisting of a narrow sheparded ring of devolatilized cometary material associated with multiple rocky planetesimal subcores, and a small steady stream of dust inflowing from this belt to a rock sublimation zone at approximately 1 AU from the primary. These subcores were built from comets that have been actively emitting large, reddish dust for > 0.4 Myr at 100K, the temperature at which cometary activity onset is seen in our Solar System.
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