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Register a new userHighly Stable and Reproducible Au Nanorod Arrays for Near-Infrared Optofluidic SERS sensor
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Surface-enhanced Raman spectroscopy (SERS) is a sensitive vibrational spectroscopy technique that can enable fast and non-destructive detection of trace molecules. SERS substrates are critical for the advancement of the SERS application. By incorporating SERS substrates into microfluidic devices, the function of microfluidic devices can be extended, and an efficient on-site trace analysis platform with powerful sensing capabilities can be realized. In this paper, we report the fabrication of a rapid and sensitive optofluidic SERS device using a unique Au nanorod array (AuNRA) with a plasmon resonance frequency in the near IR region. The highly stable and reproducible AuNRA were fabricated by a facile dynamic oblique angle deposition technique. A typical spectrum of 4,4-bipyridine (BPY) with enhanced peaks was observed within a few seconds after the injection of an aqueous solution BPY. Time-course measurements revealed an outstandingly quick response of SERS in this system. Using the AuNR microfluidic device, approximately 2x10-12 mole molecules were enough to produce detectable SERS signals. This work demonstrates rapid and sensitive chemical sensing using an optofluidic device equipped with a unique noble metal nanorod array.
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We report the fabrication of a low cost, and highly reproducible large scale surface-enhanced Raman spectroscopy substrate using an inkjet-printed Ag nanoparticle ink (AgNI). The AgNI SERS substrates were evaluated for SERS using BPY as a molecular probe. The printed AgNI dot arrays exhibit an excellent SERS performance and reproducibility. The batch to batch and spot to spot standard deviation value of less than 10 percent was obtained. The results reveal the reproducibility of the AgNI SERS dot arrays and its potential application for SERS substrates.
Capabilities of highly sensitive surface-enhanced infrared absorption (SEIRA) spectroscopy are demonstrated by exploiting large-area templates ($cm^2$) based on self-organized (SO) nanorod antennas. We engineered highly dense arrays of gold nanorod antennas featuring polarization-sensitive localized plasmon resonances, tunable over a broadband near- and mid-infrared (IR) spectrum, in overlap with the so-called functional group window. We demonstrate polarization-sensitive SEIRA activity, homogeneous over macroscopic areas and stable in time, by exploiting prototype self-assembled monolayers of IR-active octadecanthiol (ODT) molecules. The strong coupling between the plasmonic excitation and molecular stretching modes gives rise to characteristic Fano resonances in SEIRA. The SO engineering of the active hotspots in the arrays allows us to achieve signal amplitude improved up to 5.7%. This figure is competitive to the response of lithographic nanoantennas and is stable when the optical excitation spot varies from the micro- to macroscale, thus enabling highly sensitive SEIRA spectroscopy with cost-effective nanosensor devices.
We explore strain-modulated helimagnetism in highly crystalline MnP nanorod films grown on Si(100) substrates using molecular beam epitaxy. The strained MnP film exhibits a paramagnetic to ferromagnetic (PM-FM) phase transition at TC ~ 279 K, and the FM to helical phase transition at TN ~ 110 K. The value of TN is greater than TN ~ 47 K for the MnP single crystal, indicating strong strain-modulated helimagnetic states in the MnP nanorod film. The presence of significant thermal hysteresis in the helical phase indicates coexistence of competing magnetic interactions, leading to the first-order metamagnetic transition. Similar to its single crystal counterpart, an anisotropic magnetic effect is observed in the MnP film, which is independently confirmed by magnetic hysteresis loop and radio-frequency transverse susceptibility (TS) measurements. The evolution of screw (SCR) to CONE and FAN phase is precisely tracked from magnetization versus magnetic field/temperature measurements. The temperature dependence of the anisotropy fields, extracted from the TS spectra, yields further insight into the competing nature of the magnetic phases. Unfolding of the different helical phases at T < 120 K (~TN) is analyzed by the temperature- and field-dependent magnetic entropy change. Based on these findings, the comprehensive magnetic phase diagrams of the MnP nanorod film are constructed for the first time for both the in-plane and out-of-plane magnetic field directions, revealing emergent strain/dimensionality-driven helical magnetic features that are absent in the magnetic phase diagram of the MnP single crystal.
We demonstrate an intense broadband terahertz (THz) source based on the interaction of relativistic-intensity femtosecond lasers with aligned copper nanorod array targets. For copper nanorod targets with length 5 mu m, a maximum 13.8 times enhancement in the THz pulse energy (in $leq$ 20 THz spectral range) is measured as compared to that with a thick plane copper target under the same laser conditions. A further increase in the nanorod length leads to a decrease in the THz pulse energy at medium frequencies ($leq$ 20THz) and increase of the electromagnetic pulse energy in the high-frequency range (from 20 - 200 THz). For the latter, we measure a maximum energy enhancement of 28 times for the nanorod targets of length 60 mu m . Particle-in-cell simulations reveal that THz pulses are mostly generated by coherent transition radiation of laser produced hot electrons, which are efficiently enhanced with the use of nanorod targets. Good agreement is found between the simulation and experimental results.
Part of developing new strategies for fabrications of nanowire structures involves in many cases the aid of metal nanoparticles (NPs). It is highly beneficial if one can define both diameter and position of the initial NPs and make well-defined nanowire arrays. This sets additional requirement on the NPs with respect to being able to withstand a pre-growth annealing process (i.e. de- oxidation of the III-V semiconductor surface) in an epitaxy system. Recently, it has been demonstrated that Ag may be an alternative to using Au NPs as seeds for particle-seeded nanowire fabrication. This work brings light onto the effect of annealing of Au, Ag and Au-Ag alloy NP arrays in two commonly used epitaxial systems, the Molecular Beam Epitaxy (MBE) and the Metalorganic Vapor Phase Epitaxy (MOVPE). The NP arrays are fabricated with the aid of Electron Beam Lithography on GaAs 100 and 111B wafers and the evolution of the NPs with respect to shape, size and position on the surfaces are studied after annealing using Scanning Electron Microscopy (SEM). We find that while the Au NP arrays are found to be stable when annealed up to 600 $^{circ}$C in a MOVPE system, a diameter and pitch dependent splitting of the particles are seen for annealing in a MBE system. The Ag NP arrays are less stable, with smaller diameters ($leq$ 50 nm) dissolving during annealing in both epitaxial systems. In general, the mobility of the NPs is observed to differ between the two the GaAs 100 and 111B surfaces. While the initial pattern is found be intact on the GaAs 111B surface for a particular annealing process and particle type, the increased mobility of the NP on the 100 may influence the initial pre-defined positions at higher annealing temperatures. The effect of annealing on Au-Ag alloy NP arrays suggests that these NP can withstand necessary annealing conditions for a complete de-oxidation of GaAs surfaces.
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