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Register a new userOn the Origin and Thermal Stability of Arrokoths and Plutos Ices
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We discuss in a thermodynamic, geologically empirical way the long-term nature of the stable majority ices that could be present in Kuiper Belt Object 2014 MU69 after its 4.6 Gyr residence in the EKB as a cold classical object. Considering the stability versus sublimation into vacuum for the suite of ices commonly found on comets, Centaurs, and KBOs at the average ~40K sunlit surface temperature of MU69 over Myr to Gyr, we find only 3 common ices that are truly refractory: HCN, CH3OH, and H2O (in order of increasing stability). NH3 and H2CO ices are marginally stable and may be removed by any positive temperature excursions in the EKB, as produced every 1e8 - 1e9 yrs by nearby supernovae and passing O/B stars. To date the NH team has reported the presence of abundant CH3OH and evidence for H2O on MU69s surface (Lisse et al. 2017, Grundy et al. 2020). NH3 has been searched for, but not found. We predict that future absorption feature detections will be due to an HCN or poly-H2CO based species. Consideration of the conditions present in the EKB region during the formation era of MU69 lead us to infer that it formed in the dark, in an optically thick mid-plane, unable to see the nascent, variable, highly luminous Young Stellar Object-TTauri Sun, and that KBOs contain HCN and CH3OH ice phases in addition to the H2O ice phases found in their Short Period comet descendants. Finally, when we apply our ice thermal stability analysis to bodies/populations related to MU69, we find that methanol ice may be ubiquitous in the outer solar system; that if Pluto is not a fully differentiated body, then it must have gained its hypervolatile ices from proto-planetary disk sources in the first few Myr of the solar systems existence; and that hypervolatile rich, highly primordial comet C/2016 R2 was placed onto an Oort Cloud orbit on a similar timescale.
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We report results from monitoring Plutos 0.8 to 2.4 {mu}m reflectance spectrum with IRTF/SpeX on 65 nights over the dozen years from 2001 to 2012. The spectra show vibrational absorption features of simple molecules CH4, CO, and N2 condensed as ices on Plutos surface. These absorptions are modulated by the planets 6.39 day rotation period, enabling us to constrain the longitudinal distributions of the three ices. Absorptions of CO and N2 are concentrated on Plutos anti-Charon hemisphere, unlike absorptions of less volatile CH4 ice that are offset by roughly 90{deg} from the longitude of maximum CO and N2 absorption. In addition to the diurnal variations, the spectra show longer term trends. On decadal timescales, Plutos stronger CH4 absorption bands have been getting deeper, while the amplitude of their diurnal variation is diminishing, consistent with additional CH4 absorption at high northern latitudes rotating into view as the sub-Earth latitude moves north (as defined by the systems angular momentum vector). Unlike the CH4 absorptions, Plutos CO and N2 absorptions appear to be declining over time, suggesting more equatorial or southerly distributions of those species. Comparisons of geometrically-matched pairs of observations favor geometric explanations for the observed secular changes in CO and N2 absorption, although seasonal volatile transport could be at least partly responsible. The case for a volatile transport contribution to the secular evolution looks strongest for CH4 ice, despite it being the least volatile of the three ices.
IRTF/SpeX observations of Plutos near-infrared reflectance spectrum during 2013 show vibrational absorption features of CO and N$_2$ ices at 1.58 and 2.15 {mu}m, respectively, that are weaker than had been observed during the preceding decade. To reconcile declining volatile ice absorptions with a lack of decline in Plutos atmospheric pressure, we suggest these ices could be getting harder to see because of increasing scattering by small CH$_4$ crystals, rather than because they are disappearing from the observed hemisphere.
Given that the macromolecular building blocks of life were likely produced photochemically in the presence of ultraviolet (UV) light, we identify some general constraints on which stars produce sufficient UV for this photochemistry. We estimate how much light is needed for the UV photochemistry by experimentally measuring the rate constant for the UV chemistry (`light chemistry, needed for prebiotic synthesis) versus the rate constants for the bimolecular reactions that happen in the absence of the UV light (`dark chemistry). We make these measurements for representative photochemical reactions involving SO$_3^{2-}$ and HS$^-$. By balancing the rates for the light and dark chemistry, we delineate the abiogenesis zones around stars of different stellar types based on whether their UV fluxes are sufficient for building up this macromolecular prebiotic inventory. We find that the SO$_3^{2-}$ light chemistry is rapid enough to build up the prebiotic inventory for stars hotter than K5 (4400 K). We show how the abiogenesis zone overlaps with the liquid water habitable zone. Stars cooler than K5 may also drive the formation of these building blocks if they are very active. The HS$^-$ light chemistry is too slow to work even for the Early Earth.
The asteroid belt was dynamically shaped during and after planet formation. Despite representing a broad ring of stable orbits, the belt contains less than one one-thousandth of an Earth mass. The asteroid orbits are dynamically excited with a wide range in eccentricity and inclination and their compositions are diverse, with a general trend toward dry objects in the inner belt and more water-rich objects in the outer belt. Here we review models of the asteroid belts origins and dynamical history. The classical view is that the belt was born with several Earth masses in planetesimals, then strongly depleted. However, it is possible that very few planetesimals ever formed in the asteroid region and that the belts story is one of implantation rather than depletion. A number of processes may have implanted asteroids from different regions of the Solar System, dynamically removed them, and excited their orbits. During the gaseous disk phase these include the effects of giant planet growth and migration and sweeping secular resonances. After the gaseous disk phase these include scattering from resident planetary embryos, chaos in the giant planets orbits, the giant planet instability, and long-term dynamical evolution. Different global models for Solar System formation imply contrasting dynamical histories of the asteroid belt. Vesta and Ceres may have been implanted from opposite regions of the Solar System -- Ceres from the Jupiter-Saturn region and Vesta from the terrestrial planet region -- and could therefore represent very different formation conditions.
Transitional disks, protoplanetary disks with deep and wide central gaps, may be the result of planetary sculpting. By comparing numerical planet-opening-gap models with observed gaps, we find systems of 3-6 giant planets are needed in order to open gaps with the observed depths and widths. We explore the dynamical stability of such multi-planet systems using N-body simulations that incorporate prescriptions for gas effects. We find they can be stable over a typical disk lifetime, with the help of eccentricity damping from the residual gap gas that facilitates planets locking into mean motion resonances. However, in order to account for the occurrence rate of transitional disks, the planet sculpting scenario demands gap-opening-friendly disk conditions, in particular, a disk viscosity $alphalesssim0.001$. In addition, the demography of giant planets at $sim 3-30$ AU separations, poorly constrained by current data, has to largely follow occurrence rates extrapolated outward from radial velocity surveys, not the lower occurrence rates extrapolated inward from direct imaging surveys. Even with the most optimistic occurrence rates, transitional disks cannot be a common phase that most gas disks experience at the end of their life, as popularly assumed, simply because there are not enough planets to open these gaps. Finally, as consequences of demanding almost all giant planets at large separations participate in transitional disk sculpting, the majority of such planets must form early and end up in a chain of mean motion resonances at the end of disk lifetime.
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