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Register a new userFull Daytime Sub-ambient Radiative Cooling with High Figure of Merit in Commercial-like Paints
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Radiative cooling is a passive cooling technology by reflecting sunlight and emitting radiation in the atmospheric sky window. Although highly desired, full daytime sub-ambient radiative cooling in commercial-like single-layer particle-matrix paints is yet to be achieved. In this work, we have demonstrated full daytime sub-ambient radiative cooling in CaCO3-acrylic paint by adopting large bandgap fillers, a high particle concentration and a broad size distribution. Our paint shows the highest solar reflectance of 95.5% among paints and a high sky-window emissivity of 0.94. Field tests show cooling power exceeding 37 W/m2 and lower surface temperature more than 1.7C below ambient at noon. A figure of merit RC is proposed to compare the cooling performance under different weather conditions. The RC of our cooling paint is 0.62, among the best radiative cooling performance while offering unprecedented benefits of the convenient paint form, low cost, and the compatibility with commercial paint fabrication process.
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Radiative cooling is a passive cooling technology that offers great promises to reduce space cooling cost, combat the urban island effect and alleviate the global warming. To achieve passive daytime radiative cooling, current state-of-the-art solutions often utilize complicated multilayer structures or a reflective metal layer, limiting their applications in many fields. Attempts have been made to achieve passive daytime radiative cooling with single-layer paints, but they often require a thick coating or show partial daytime cooling. In this work, we experimentally demonstrate remarkable full daytime sub-ambient cooling performance with both BaSO4 nanoparticle films and BaSO4 nanocomposite paints. BaSO4 has a high electron bandgap for low solar absorptance and phonon resonance at 9 um for high sky window emissivity. With an appropriate particle size and a broad particle size distribution, BaSO4 nanoparticle film reaches an ultra-high solar reflectance of 97.6% and high sky window emissivity of 0.96. During field tests, BaSO4 film stays more than 4.5C below ambient temperature or achieves average cooling power of 117 W/m2. BaSO4-acrylic paint is developed with 60% volume concentration to enhance the reliability in outdoor applications, achieving solar reflectance of 98.1% and sky window emissivity of 0.95. Field tests indicate similar cooling performance to the BaSO4 films. Overall, our BaSO4-acrylic paint shows standard figure of merit of 0.77 which is among the highest of radiative cooling solutions, while providing great reliability, the convenient paint form, ease of use and the compatibility with commercial paint fabrication process.
It is well established that nearly all high-quality (Q) Fano-like resonances in terahertz (THz) metasurfaces broaden as asymmetry increases, resulting in a decline of Q-factor and an increase in the resonance intensity. Therefore, in order to determine the optimal design for applications in THz sensing, a Figure of Merit (FoM) is required. Previous studies have identified the asymmetry regimes at which the peak FoM occurs for various, specific unit cell geometries. However to date, there is no systematic comparison of the resulting FoMs for common and novel geometries. Here, a THz planar metafilm featuring split ring resonators with four distributed capacitive gaps is investigated to compare three unique methods of implementing asymmetry: (1) adjacent L-bracket translation, (2) capacitive gap translation and (3) increasing gap width. The results obtained find that by translating two gaps and increasing the bottom gap width of the unit cell, the high-Q Fano-like resonances are $6 times$ higher than the FoM for the fundamental dipole mode. This work further informs the design process for THz metasurfaces and as such will help to define their applications in photonics and sensing.
Energy-saving cooling materials with strong operability are desirable towards sustainable thermal management. Inspired by the cooperative thermo-optical effect in fur of polar bear, we develop a flexible and reusable cooling skin via laminating a polydimethylsiloxane film with a highly-scattering polyethylene aerogel. Owing to its high porosity of 97.9% and tailored pore size of 3.8 +- 1.4 micrometers, superior solar reflectance of 0.96 and high transparency to irradiated thermal energy of 0.8 can be achieved at a thickness of 2.7 mm. Combined with low thermal conductivity of 0.032 W/m/K of the aerogel, the cooling skin exerts midday sub-ambient temperature drops of 5-6 degrees in a metropolitan environment, with an estimated limit of 14 degrees under ideal service conditions. We envision that this generalized bilayer approach will construct a bridge from night-time to daytime radiative cooling and pave the way for economical, scalable, flexible and reusable cooling materials.
The radiative cooling of objects during daytime under direct sunlight has recently been shown to be significantly enhanced by utilizing nanophotonic coatings. Multilayer thin film stacks, 2D photonic crystals, etc. as coating structures improved the thermal emission rate of a device in the infrared atmospheric transparency window reducing considerably devices temperature. Due to the increased heating in photovoltaic (PV) devices, that has significant adverse consequences on both their efficiency and life-time, and inspired by the recent advances in daytime radiative cooling, we developed a coupled thermal-electrical modeling to examine the physical mechanisms on how a radiative cooler affects the overall efficiency of commercial photovoltaic modules. Employing this modeling, which takes into account all the major processes affected by the temperature variation in a PV device, we evaluated the relative impact of the main radiative cooling approaches proposed so far on the PV efficiency, and we established required conditions for optimized radiative cooling. Moreover, we identified the validity regimes of the currently existing PV-cooling models which treat the PV coolers as simple thermal emitters. Finally, we assessed some realistic photonic coolers from the literature, compatible with photovoltaics, to implement the radiative cooling requirements, and demonstrated their associated impact on the temperature reduction and PV efficiency. Providing the physical mechanisms and requirements for cooling radiatively solar cells, our study provides guidelines for utilizing suitable photonic structures as radiative coolers, enhancing the efficiency and the lifetime of PV devices.
Daytime radiative cooling has attracted considerable attention recently due to its tremendous potential for passively exploiting the coldness of deep-sky as clean and renewable energy. Many advanced materials with novel photonic micro-nanostructures have already been developed to enable highly efficient daytime radiative coolers, among which the flexible hierarchical porous coatings (HPCs) are a more distinguished category. However, it is still hard to precisely control the size distribution of the randomized pores within the HPCs, usually resulting in a deficient solar reflection at the near-infrared optical regime under diverse fabrication conditions of the coatings. We report here a three-phase (i.e., air pore-phase, microsphere-phase and polymer-phase) self-assembled hybrid porous composite coating which dramatically increases the average solar reflectance and yields a remarkable temperature drop of ~10 degC and 30 degC compared to the ambient circumstance and black paint, respectively, according to the rooftop measurements. Mie theory and Monte Carlo simulations reveal the origin of the low reflectivity of as-prepared two-phase porous HPCs, and the optical cooling improvement of the three-phase porous composite coatings is attributed to the newly generated interfaces possessing the high scattering efficiency between the hierarchical pores and silica microspheres hybridized with appropriate mass fractions. As a result, the hybrid porous composite approach enhances the whole performance of the coatings, which provides a promising alternative to the flexible daytime radiative cooler.
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