Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userFlexible daytime radiative cooling enhanced by enabling three-phase composites with scattering interfaces between silica-microspheres and hierarchical porous coatings
94
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Daytime radiative cooling has attracted considerable attention recently due to its tremendous potential for passively exploiting the coldness of deep-sky as clean and renewable energy. Many advanced materials with novel photonic micro-nanostructures have already been developed to enable highly efficient daytime radiative coolers, among which the flexible hierarchical porous coatings (HPCs) are a more distinguished category. However, it is still hard to precisely control the size distribution of the randomized pores within the HPCs, usually resulting in a deficient solar reflection at the near-infrared optical regime under diverse fabrication conditions of the coatings. We report here a three-phase (i.e., air pore-phase, microsphere-phase and polymer-phase) self-assembled hybrid porous composite coating which dramatically increases the average solar reflectance and yields a remarkable temperature drop of ~10 degC and 30 degC compared to the ambient circumstance and black paint, respectively, according to the rooftop measurements. Mie theory and Monte Carlo simulations reveal the origin of the low reflectivity of as-prepared two-phase porous HPCs, and the optical cooling improvement of the three-phase porous composite coatings is attributed to the newly generated interfaces possessing the high scattering efficiency between the hierarchical pores and silica microspheres hybridized with appropriate mass fractions. As a result, the hybrid porous composite approach enhances the whole performance of the coatings, which provides a promising alternative to the flexible daytime radiative cooler.
rate research
Read More
Energy-saving cooling materials with strong operability are desirable towards sustainable thermal management. Inspired by the cooperative thermo-optical effect in fur of polar bear, we develop a flexible and reusable cooling skin via laminating a polydimethylsiloxane film with a highly-scattering polyethylene aerogel. Owing to its high porosity of 97.9% and tailored pore size of 3.8 +- 1.4 micrometers, superior solar reflectance of 0.96 and high transparency to irradiated thermal energy of 0.8 can be achieved at a thickness of 2.7 mm. Combined with low thermal conductivity of 0.032 W/m/K of the aerogel, the cooling skin exerts midday sub-ambient temperature drops of 5-6 degrees in a metropolitan environment, with an estimated limit of 14 degrees under ideal service conditions. We envision that this generalized bilayer approach will construct a bridge from night-time to daytime radiative cooling and pave the way for economical, scalable, flexible and reusable cooling materials.
Radiative cooling is a passive cooling technology that offers great promises to reduce space cooling cost, combat the urban island effect and alleviate the global warming. To achieve passive daytime radiative cooling, current state-of-the-art solutions often utilize complicated multilayer structures or a reflective metal layer, limiting their applications in many fields. Attempts have been made to achieve passive daytime radiative cooling with single-layer paints, but they often require a thick coating or show partial daytime cooling. In this work, we experimentally demonstrate remarkable full daytime sub-ambient cooling performance with both BaSO4 nanoparticle films and BaSO4 nanocomposite paints. BaSO4 has a high electron bandgap for low solar absorptance and phonon resonance at 9 um for high sky window emissivity. With an appropriate particle size and a broad particle size distribution, BaSO4 nanoparticle film reaches an ultra-high solar reflectance of 97.6% and high sky window emissivity of 0.96. During field tests, BaSO4 film stays more than 4.5C below ambient temperature or achieves average cooling power of 117 W/m2. BaSO4-acrylic paint is developed with 60% volume concentration to enhance the reliability in outdoor applications, achieving solar reflectance of 98.1% and sky window emissivity of 0.95. Field tests indicate similar cooling performance to the BaSO4 films. Overall, our BaSO4-acrylic paint shows standard figure of merit of 0.77 which is among the highest of radiative cooling solutions, while providing great reliability, the convenient paint form, ease of use and the compatibility with commercial paint fabrication process.
Radiative cooling is a passive cooling technology by reflecting sunlight and emitting radiation in the atmospheric sky window. Although highly desired, full daytime sub-ambient radiative cooling in commercial-like single-layer particle-matrix paints is yet to be achieved. In this work, we have demonstrated full daytime sub-ambient radiative cooling in CaCO3-acrylic paint by adopting large bandgap fillers, a high particle concentration and a broad size distribution. Our paint shows the highest solar reflectance of 95.5% among paints and a high sky-window emissivity of 0.94. Field tests show cooling power exceeding 37 W/m2 and lower surface temperature more than 1.7C below ambient at noon. A figure of merit RC is proposed to compare the cooling performance under different weather conditions. The RC of our cooling paint is 0.62, among the best radiative cooling performance while offering unprecedented benefits of the convenient paint form, low cost, and the compatibility with commercial paint fabrication process.
Normal mode splitting is observed in a cavity QED system, in which nitrogen vacancy centers in diamond nanocrystals are coupled to whispering gallery modes in a silica microsphere. The composite nanocrystal-microsphere system takes advantage of the exceptional spin properties of nitrogen vacancy centers as well as the ultra high quality factor of silica microspheres. The observation of the normal mode splitting indicates that the dipole optical interaction between the relevant nitrogen vacancy center and whispering gallery mode has reached the strong coupling regime of cavity QED.
A fundamental limit of current radiative cooling systems is that only the top surface facing deep-space can provide the radiative cooling effect, while the bottom surface cannot. Here, we propose and experimentally demonstrate a concept of concentrated radiative cooling by nesting a radiative cooling system in a mid-infrared reflective trough, so that the lower surface, which does not contribute to radiative cooling in previous systems, can radiate heat to deep-space via the reflective trough. Field experiments show that the temperature drop of a radiative cooling pipe with the trough is more than double that of the standalone radiative cooling pipe. Furthermore, by integrating the concentrated radiative cooling system as a preconditioner in an air conditioning system, we predict electricity savings of $>75%$ in Phoenix, AZ, and $>80%$ in Reno, NV, for a single-story commercial building.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
