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Register a new userPlasmonic Bubble Nucleation and Growth in Water: Effect of Dissolved Air
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Under continuous laser irradiation, noble metal nanoparticles immersed in water can quickly heat up, leading to the nucleation of so-called plasmonic bubbles. In this work, we want to further understand the bubble nucleation and growth mechanism. In particular, we quantitatively study the effect of the amount of dissolved air on the bubble nucleation and growth dynamics, both for the initial giant bubble, which forms shortly after switching on the laser and is mainly composed of vapor, and for the final life phase of the bubble, during which it mainly contains air expelled from water. We found that the bubble nucleation temperature depends on the gas concentration: the higher the gas concentration, the lower the bubble nucleation temperature. Also, the long-term diffusiondominated bubble growth is governed by the gas concentration. The radius of the bubbles grows as R(t)~t^1/3 for airequilibrated and air-oversaturated water. In contrast, in partially degassed water, the growth is much slower since, even for the highest temperature we achieve, the water remains undersaturated.
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Understanding the growth dynamics of the microbubbles produced by plasmonic heating can benefit a wide range of applications like microfluidics, catalysis, micro-patterning and photo-thermal energy conversion. Usually, surface plasmonic bubbles are generated on plasmonic structures pre-deposited on the surface subject to laser heating. In this work, we investigate the growth dynamics of surface microbubbles generated in plasmonic nanoparticle (NP) suspension. We observe much faster bubble growth rates compared to those in pure water with surface plasmonic structures. Our analyses show that the volumetric heating effect around the surface bubble due to the existence of NPs in the suspension is the key to explain this difference. Such volumetric heating increases the temperature around the surface bubble more efficiently compared to surface heating which enhances the expelling of dissolved gas. We also find that the bubble growth rates can be tuned in a very wide range by changing the concentration of NPs, besides laser power and dissolved gas concentration.
The term `history effect refers to the contribution of any past mass transfer events between a gas bubble and its liquid surroundings towards the current diffusion-driven growth or dissolution dynamics of that same bubble. The history effect arises from the (non-instantaneous) development of the dissolved gas concentration boundary layer in the liquid in response to changes in the concentration at the bubble interface caused, for instance, by variations of the ambient pressure in time. Essentially, the history effect amounts to the acknowledgement that at any given time the mass flux across the bubble is conditioned by the preceding time-history of the concentration at the bubble boundary. Considering the canonical problem of an isolated spherical bubble at rest, we show that the contribution of the history effect in the current interfacial concentration gradient is fully contained within a memory integral of the interface concentration. Retaining this integral term, we formulate a governing differential equation for the bubble dynamics, analogous to the well-known Epstein-Plesset solution. Our equation does not make use of the quasi-static radius approximation. An analytical solution is presented for the case of multiple step-like jumps in pressure. The nature and relevance of the history effect is then assessed through illustrative examples. Finally, we investigate the role of the history effect in rectified diffusion for a bubble that pulsates under harmonic pressure forcing in the non-inertial, isothermal regime.
Lubricant-infused surfaces (LISs) can promote stable dropwise condensation and improve heat transfer rates due to a low nucleation free-energy barrier and high droplet mobility. Topographical differences in the oil surface cause water microdroplets to rigorously self-propel long distances, continuously redistributing the oil film and potentially refreshing the surface for re-nucleation. Using high-speed microscopy, we reveal that during water condensation on LISs, the smallest visible droplets (diameter ~ 1um, qualitatively representing nucleation) predominantly emerge in oil-poor regions due to a smaller thermal activation barrier. Considering the significant heat transfer performance of microdroplets (< 10um) and transient characteristic of microdroplet movement, we compare the apparent nucleation rate density and water collection rate for LISs with oils of different viscosity and a solid hydrophobic surface at a wide range of subcooling temperatures. Generally, the lowest lubricant viscosity leads to the highest nucleation rate density. We characterize the length and frequency of microdroplet movement and attribute the nucleation enhancement primarily to higher droplet mobility and surface refreshing frequency. Interestingly and unexpectedly, hydrophobic surfaces outperform high-viscosity LISs at high subcooling temperatures, but are generally inferior to any of the tested LISs at low temperature differences. To explain the observed non-linearity between LISs and the solid hydrophobic surface, we introduce two dominant regimes that influence the condensation efficiency: mobility-limited and coalescence-limited. Our findings advance the understanding of dynamic water-lubricant interactions and provide new design rationales for choosing surfaces for enhanced dropwise condensation and water collection efficiencies.
The understanding of the shrinkage dynamics of plasmonic bubbles formed around metallic nanoparticles immersed in liquid and irradiated by a resonant light source is crucial for the usage of these bubbles in numerous applications. In this paper we experimentally show and theoretically explain that a plasmonic bubble during its shrinkage undergoes two different phases: first, a rapid partial bubble shrinkage governed by vapor condensation and, second, a slow diffusion-controlled bubble dissolution. The history of the bubble formation plays an important role in the shrinkage dynamics during the first phase, as it determines the gas-vapor ratio in the bubble composition. Higher laser powers lead to more vaporous bubbles, while longer pulses and higher dissolved air concentrations lead to more gaseous bubbles. The dynamics of the second phase barely depends on the history of bubble formation, i.e. laser power and pulse duration, but strongly on the dissolved air concentration, which defines the concentration gradient at the bubble interface. Finally, for the bubble dissolution in the second phase, with decreasing dissolved air concentration, we observe a gradual transition from a $R(t) propto (t_0 - t) ^{1/3}$ scaling law to a $R(t) propto (t_0 - t) ^{1/2}$ scaling law, where $t_0$ is the lifetime of the bubble and theoretically explain this transition.
The macroscopic dynamics of a droplet impacting a solid is crucially determined by the intricate air dynamics occurring at the vanishingly small length scale between droplet and substrate prior to direct contact. Here we investigate the inverse problem, namely the role of air for the impact of a horizontal flat disk onto a liquid surface, and find an equally significant effect. Using an in-house experimental technique, we measure the free surface deflections just before impact, with a precision of a few micrometers. Whereas stagnation pressure pushes down the surface in the center, we observe a lift-up under the edge of the disk, which sets in at a later stage, and which we show to be consistent with a Kelvin-Helmholtz instability of the water-air interface.
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