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A system in thermal equilibrium with a bath will generally be in an athermal state, if the system-bath coupling is strong. In some cases, it will be possible to extract work from that athermal state, after disconnecting the system from the bath. We use this observation to devise a battery charging and storing unit, simply consisting of a system, acting as the battery, and a bath. The charging cycle---connect, let thermalize, disconnect, extract work---requires very little external control and the charged state of the battery, being a part of global thermal equilibrium, can be maintained indefinitely and for free. The efficiency, defined as the ratio of the extractable work stored in the battery and the total work spent on connecting and disconnecting, is always $leq 1$, which is a manifestation of the second law of thermodynamics. Moreover, coupling, being a resource for the device, is also a source of dissipation: the entropy production per charging cycle is always significant, strongly limiting the efficiency in all coupling strength regimes. We show that our general results also hold for generic microcanonical baths. We illustrate our theory on the Caldeira-Leggett model with a harmonic oscillator (the battery) coupled to a harmonic bath, for which we derive general asymptotic formulas in both weak and ultrastrong coupling regimes, for arbitrary Ohmic spectral densities. We show that the efficiency can be increased by connecting several copies of the battery to the bath. Finally, as a side result, we derive a general formula for Gaussian ergotropy, that is, the maximal work extractable by Gaussian unitary operations from Gaussian states of multipartite continuous-variable systems.
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When studying thermalization of quantum systems, it is typical to ask whether a system interacting with an environment will evolve towards a local thermal state. Here, we show that a more general and relevant question is when does a system thermalize relative to a particular reference? By relative thermalization we mean that, as well as being in a local thermal state, the system is uncorrelated with the reference. We argue that this is necessary in order to apply standard statistical mechanics to the study of the interaction between a thermalized system and a reference. We then derive a condition for relative thermalization of quantum systems interacting with an arbitrary environment. This condition has two components: the first is state-independent, reflecting the structure of invariant subspaces, like energy shells, and the relative sizes of system and environment; the second depends on the initial correlations between reference, system and environment, measured in terms of conditional entropies. Intuitively, a small system interacting with a large environment is likely to thermalize relative to a reference, but only if, initially, the reference was not highly correlated with the system and environment. Our statement makes this intuition precise, and we show that in many natural settings this thermalization condition is approximately tight. Established results on thermalization, which usually ignore the reference, follow as special cases of our statements.
We study the heat statistics of a multi-level $N$-dimensional quantum system monitored by a sequence of projective measurements. The late-time, asymptotic properties of the heat characteristic function are analyzed in the thermodynamic limit of a high, ideally infinite, number $M$ of measurements $(M to infty)$. In this context, the conditions allowing for an Infinite-Temperature Thermalization (ITT), induced by the repeated monitoring of the quantum system, are discussed. We show that ITT is identified by the fixed point of a symmetric random matrix that models the stochastic process originated by the sequence of measurements. Such fixed point is independent on the non-equilibrium evolution of the system and its initial state. Exceptions to ITT, to which we refer to as partial thermalization, take place when the observable of the intermediate measurements is commuting (or quasi-commuting) with the Hamiltonian of the quantum system, or when the time interval between measurements is smaller or comparable with the system energy scale (quantum Zeno regime). Results on the limit of infinite-dimensional Hilbert spaces ($N to infty$), describing continuous systems with a discrete spectrum, are also presented. We show that the order of the limits $Mtoinfty$ and $Ntoinfty$ matters: when $N$ is fixed and $M$ diverges, then ITT occurs. In the opposite case, the system becomes classical, so that the measurements are no longer effective in changing the state of the system. A non trivial result is obtained fixing $M/N^2$ where instead partial ITT occurs. Finally, an example of partial thermalization applicable to rotating two-dimensional gases is presented.
We study the role of the system-bath coupling for the generalized canonical thermalization [S. Popescu, et al., Nature Physics 2,754(2006) and S. Goldstein et al., Phys. Rev. Lett. 96, 050403(2006)] that reduces almost all the pure states of the universe [formed by a system S plus its surrounding heat bath $B$] to a canonical equilibrium state of S. We present an exactly solvable, but universal model for this kinematic thermalization with an explicit consideration about the energy shell deformation due to the interaction between S and B. By calculating the state numbers of the universe and its subsystems S and B in various deformed energy shells, it is found that, for the overwhelming majority of the universe states (they are entangled at least), the diagonal canonical typicality remains robust with respect to finite interactions between S and B. Particularly, the kinematic decoherence is utilized here to account for the vanishing of the off-diagonal elements of the reduced density matrix of S. It is pointed out that the non-vanishing off-diagonal elements due to the finiteness of bath and the stronger system-bath interaction might offer more novelties of the quantum thermalization.
We introduce deterministic state-transformation protocols between many-body quantum states which can be implemented by low-depth Quantum Circuits (QC) followed by Local Operations and Classical Communication (LOCC). We show that this gives rise to a classification of phases in which topologically-ordered states or other paradigmatic entangled states become trivial. We also investigate how the set of unitary operations is enhanced by LOCC in this scenario, allowing one to perform certain large-depth QC in terms of low-depth ones.
In this work, we show how Gibbs or thermal states appear dynamically in closed quantum many-body systems, building on the program of dynamical typicality. We introduce a novel perturbation theorem for physically relevant weak system-bath couplings that is applicable even in the thermodynamic limit. We identify conditions under which thermalization happens and discuss the underlying physics. Based on these results, we also present a fully general quantum algorithm for preparing Gibbs states on a quantum computer with a certified runtime and error bound. This complements quantum Metropolis algorithms, which are expected to be efficient but have no known runtime estimates and only work for local Hamiltonians.
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