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Register a new userDetection of Propadiene on Titan
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The atmosphere of Titan, the largest moon of Saturn, is rich in organic molecules, and it has been suggested that the moon may serve as an analog for the pre-biotic Earth due to its highly reducing chemistry and existence of global hazes. Photochemical models of Titan have predicted the presence of propadiene (historically referred to as allene), CH$_{2}$CCH$_{2}$, an isomer of the well-measured propyne (also called methylacetylene) CH$_{3}$CCH, but its detection has remained elusive due to insufficient spectroscopic knowledge of the molecule - which has recently been remedied with an updated spectral line list. Here we present the first unambiguous detection of the molecule in any astronomical object, observed with the Texas Echelle Cross Echelle Spectrograph (TEXES) on the NASA Infrared Telescope Facility (IRTF) in July 2017. We model its emission line near 12 $mu$m and measure a volume mixing ratio (VMR) of (6.9 $pm$ 0.8) $times$10$^{-10}$ at 175 km, assuming a vertically increasing abundance profile as predicted in photochemical models. Cassini measurements of propyne made during April 2017 indicate that the abundance ratio of propyne to propadiene is 8.2$pm$1.1 at the same altitude. This initial measurement of the molecule in Titans stratosphere paves the way towards constraining the amount of atomic hydrogen available on Titan, as well as future mapping of propadiene on Titan from 8 meter and larger ground based observatories, and future detection on other planetary bodies.
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Thanks to the Cassini-Huygens mission, Titan, the pale orange dot of Pioneer and Voyager encounters has been revealed to be a dynamic, hydrologically-shaped, organic-rich ocean world offering unparalleled opportunities to explore prebiotic chemistry. And while Cassini-Huygens revolutionized our understanding of each of the three layers of Titan--the atmosphere, the surface, and the interior--we are only beginning to hypothesize how these realms interact. In this paper, we summarize the current state of Titan knowledge and discuss how future exploration of Titan would address some of the next decades most compelling planetary science questions. We also demonstrate why exploring Titan, both with and beyond the Dragonfly New Frontiers mission, is a necessary and complementary component of an Ocean Worlds Program that seeks to understand whether habitable environments exist elsewhere in our solar system.
We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C3H2) from high sensitivity spectroscopic observations made with the Atacama Large Millimeter/sub-millimeter Array (ALMA). Multiple lines of cyclopropenylidene were detected in two separate datasets: ~251 GHz in 2016 (Band 6) and ~352 GHz in 2017 (Band 7). Modeling of these emissions indicates abundances of 0.50 +/- 0.14 ppb (2016) and 0.28 +/- 0.08 (2017) for a 350 km step model, which may either signify a decrease in abundance, or a mean value of 0.33 +/- 0.07 ppb. Inferred column abundances are (3-5)E12 cm-2 in 2016 and (1-2)E12 cm-2 in 2017, similar to photochemical model predictions. Previously the C3H3+ ion has been measured in Titans ionosphere by Cassinis Ion and Neutral Mass Spectrometer (INMS), but the neutral (unprotonated) species has not been detected until now, and aromatic versus aliphatic structure could not be determined by the INMS. Our work therefore represents the first unambiguous detection of cyclopropenylidene, the second known cyclic molecule in Titans atmosphere along with benzene (C6H6) and the first time this molecule has been detected in a planetary atmosphere. We also searched for the N-heterocycle molecules pyridine and pyrimidine finding non-detections in both cases, and determining 2-{sigma} upper limits of 1.15 ppb (c-C5H5N) and 0.85 ppb (c-C4H4N2) for uniform abundances above 300 km. These new results on cyclic molecules provide fresh constraints on photochemical pathways in Titans atmosphere, and will require new modeling and experimental work to fully understand the implications for complex molecule formation.
We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titans atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter array (ALMA). The presence of C$_2$H$_5$CN in Titans ionosphere was previously inferred from Cassini ion mass spectrometry measurements of C$_2$H$_5$CNH$^+$. Here we report the detection of 27 rotational lines from C$_2$H$_5$CN (in 19 separate emission features detected at $>3sigma$ confidence), in the frequency range 222-241 GHz. Simultaneous detections of multiple emission lines from HC$_3$N, CH$_3$CN and CH$_3$CCH were also obtained. In contrast to HC$_3$N, CH$_3$CN and CH$_3$CCH, which peak in Titans northern (spring) hemisphere, the emission from C$_2$H$_5$CN is found to be concentrated in the southern (autumn) hemisphere, suggesting a distinctly different chemistry for this species, consistent with a relatively short chemical lifetime for C$_2$H$_5$CN. Radiative transfer models show that most of the C$_2$H$_5$CN is concentrated at altitudes 300-600 km, suggesting production predominantly in the mesosphere and above. Vertical column densities are found to be in the range (2-5)$times10^{14}$ cm$^{-2}$.
Conditions on Saturns moon Titan suggest dust devils, which are convective, dust-laden plumes, may be active. Although the exact nature of dust on Titan is unclear, previous observations confirm an active aeolian cycle, and dust devils may play an important role in Titans aeolian cycle, possibly contributing to regional transport of dust and even production of sand grains. The Dragonfly mission to Titan will document dust devil and convective vortex activity and thereby provide a new window into these features, and our analysis shows that associated winds are likely to be modest and pose no hazard to the mission.
Winds in Titans lower and middle atmosphere have been determined by a variety of techniques, including direct measurements from the Huygens Probe over 0-150 km, Doppler shifts of molecular spectral lines in the optical, thermal infrared and mm ranges, probing altogether the ~100-450 km altitude range, and inferences from thermal field over 10 mbar - 10 -3 mbar (i.e. ~100-500 km) and from central flashes in stellar occultation curves. These measurements predominantly indicated strong prograde winds, reaching maximum speeds of ~150-200 m/s in the upper stratosphere, with important latitudinal and seasonal variations. However, these observations provided incomplete atmospheric sounding; in particular, the wind regime in Titans upper mesosphere and thermosphere (500- 1200 km) has remained unconstrained so far. Here we report direct wind measurements based on Doppler shifts of six molecular species observed with ALMA. We show that unlike expectations, strong prograde winds extend up to the thermosphere, with the circulation progressively turning into an equatorial jet regime as altitude increases, reaching ~340 m/s at 1000 km. We suggest that these winds may represent the dynamical response of forcing by waves launched at upper stratospheric/mesospheric levels and/or magnetospheric-ionospheric interaction. We also demonstrate that the HNC distribution is restricted to Titans thermosphere above ~870 km altitude.
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