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Register a new userFundamental bounds on rotational state change in sympathetic cooling of molecular ions
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Sympathetic cooling of molecular ions through the Coulomb interaction with laser-cooled atomic ions is an efficient tool to prepare translationally cold molecules. Even at relatively high collisional energies of about 1$,$eV ($Tsim 10000 ,$K), the nearest approach in the ion-ion collisions never gets closer than $sim$$1,$nm such that naively perturbations of the internal molecular state are not expected. The Coulomb field may, however, induce rotational transitions changing the purity of initially quantum state prepared molecules. Here, we investigate such rotational state changing collisions for both polar and apolar diatomic molecular ions and derive closed-form estimates for rotational excitation based on the initial scattering energy and the molecular parameters.
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Current experimental efforts to test the fundamental CPT symmetry with single (anti-)protons are progressing at a rapid pace but are hurt by the nonzero temperature of particles and the difficulty of spin state detection. We describe a laser-based and quantum logic inspired approach to single (anti-)proton cooling and state detection.
We demonstrate sympathetic sideband cooling of a $^{40}$CaH$^{+}$ molecular ion co-trapped with a $^{40}$Ca$^{+}$ atomic ion in a linear Paul trap. Both axial modes of the two-ion chain are simultaneously cooled to near the ground state of motion. The center of mass mode is cooled to an average quanta of harmonic motion $overline{n}_{mathrm{COM}} = 0.13 pm 0.03$, corresponding to a temperature of $12.47 pm 0.03 ~mu$K. The breathing mode is cooled to $overline{n}_{mathrm{BM}} = 0.05 pm 0.02$, corresponding to a temperature of $15.36 pm 0.01~mu$K.
We investigate the dynamics of an ion sympathetically cooled by another laser-cooled ion or small ion crystal. To this end, we develop simple models of the cooling dynamics in the limit of weak Coulomb interactions. Experimentally, we create a two-ion crystal of Ca$^+$ and Al$^+$ by photo-ionization of neutral atoms produced by laser ablation. We characterize the velocity distribution of the laser-ablated atoms crossing the trap by time-resolved fluorescence spectroscopy. We observe neutral atom velocities much higher than the ones of thermally heated samples and find as a consequence long sympathethic cooling times before crystallization occurs. Our key result is a new technique for detecting the loading of an initially hot ion with energy in the eV range by monitoring the motional state of a Doppler-cooled ion already present in the trap. This technique not only detects the ion but also provides information about dynamics of the sympathetic cooling process.
A mixed system of cooled and trapped, ions and atoms, paves the way for ion assisted cold chemistry and novel many body studies. Due to the different individual trapping mechanisms, trapped atoms are significantly colder than trapped ions, therefore in the combined system, the strong binary ion$-$atom interaction results in heat flow from ions to atoms. Conversely, trapped ions can also get collisionally heated by the cold atoms, making the resulting equilibrium between ions and atoms intriguing. Here we experimentally demonstrate, Rubidium ions (Rb$^+$) cool in contact with magneto-optically trapped (MOT) Rb atoms, contrary to the general expectation of ion heating for equal ion and atom masses. The cooling mechanism is explained theoretically and substantiated with numerical simulations. The importance of resonant charge exchange (RCx) collisions, which allows swap cooling of ions with atoms, wherein a single glancing collision event brings a fast ion to rest, is discussed.
We discuss the dynamics of sympathetic cooling of atomic mixtures in realistic, nonlinear trapping potentials using a microscopic effective model developed earlier for harmonic traps. We contrast the effectiveness of different atomic traps, such as Ioffe-Pritchard magnetic traps and optical dipole traps, and the role their intrinsic nonlinearity plays in speeding up or slowing down thermalization between the two atomic species. This discussion includes cases of configurations with lower effective dimensionality. From a more theoretical standpoint, our results provide the first exploration of a generalized Caldeira-Leggett model with nonlinearities both in the trapping potential as well as in the interspecies interactions, and no limitations on their coupling strength.
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