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Efficient methanol production on the dark side of a prestellar core

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 Added by Jorma Harju
 Publication date 2019
  fields Physics
and research's language is English




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We present ALMA maps of the starless molecular cloud core Ophiuchus/H-MM1 in the lines of deuterated ammonia (ortho-NH2D), methanol (CH3OH), and sulphur monoxide (SO). The dense core is seen in NH2D emission, whereas the CH3OH and SO distributions form a halo surrounding the core. Because methanol is formed on grain surfaces, its emission highlights regions where desorption from grains is particularly efficient. Methanol and sulphur monoxide are most abundant in a narrow zone that follows the eastern side of the core. This side is sheltered from the stronger external radiation field coming from the west. We show that photodissociation on the illuminated side can give rise to an asymmetric methanol distribution, but that the stark contrast observed in H-MM1 is hard to explain without assuming enhanced desorption on the shaded side. The region of the brightest emission has a wavy structure that rolls up at one end. This is the signature of Kelvin-Helmholtz instability occurring in sheared flows. We suggest that in this zone, methanol and sulphur are released as a result of grain-grain collisions induced by shear vorticity.



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273 - Laurent Pagani 2009
Exploring the structure and dynamics of cold starless clouds is necessary to understand the different steps leading to the formation of protostars. Because clouds evolve slowly, many of them must be studied in detail to pick up different moments of a clouds lifetime. We study here L1506C in the Taurus region, a core with interesting dust properties which have been evidenced with the PRONAOS balloon-borne telescope. To trace the mass content of L1506C and its kinematics, we mapped the dust emission, and the line emission of two key species, C18O and N2H+ (plus 13CO and C17O). This cloud shows peculiar features: i) a large envelope traced solely by 13CO holding a much smaller core with a strong C18O depletion in its center despite a low maximum opacity (Av~20 mag), ii) extremely narrow C18O lines indicating a low, non-measurable turbulence, iii) contraction traced by C18O itself (plus rotation), iv) unexpectedly, the kinematical signature from the external envelope is opposite to the core one: the 13CO and C18O velocity gradients have opposite directions and opposite profiles (C18O blue peaked, 13CO red peaked). The core is large (r = 3E4 AU) and not very dense (n(H2) ? 5E4 cm-3 or less). This core is therefore not prestellar yet. All these facts suggest that the core is kinematically detached from its envelope and in the process of forming a prestellar core. This is the first time that the dynamical formation of a prestellar core is witnessed. The extremely low turbulence could be the reason for the strong depletion of this core despite its relatively low density and opacity in contrast with undepleted cores such as L1521E which shows a turbulence at least 4 times as high.
129 - B. Parise , A. Belloche , F. Du 2010
Context: In the last years, the H2D+ and D2H+ molecules have gained great attention as probes of cold and depleted dense molecular cloud cores. These ions are at the basis of molecular deuterium fractionation, a common characteristic observed in star forming regions. H2D+ is now routinely observed, but the search for its isotopologue D2H+ is still difficult because of the high frequency of its ground para transition (692 GHz). Aims: We have observed molecular transitions of H2D+ and D2H+ in a cold prestellar core to characterize the roots of deuterium chemistry. Methods: Thanks to the sensitive multi-pixel CHAMP+ receiver on the APEX telescope where the required excellent weather conditions are met, we not only successfully detect D2H+ in the H-MM1 prestellar core located in the L1688 cloud, but also obtain information on the spatial extent of its emission. We also detect H2D+ at 372 GHz in the same source. We analyse these detections using a non-LTE radiative transfer code and a state-of-the-art spin-dependent chemical model. Results: This observation is the first secure detection of D2H+ in space. The emission is moreover extended over several pixels of the CHAMP+ array, i.e. on a scale of at least 40, corresponding to ~ 4800 AU. We derive column densities on the order of 1e12-1e13 cm-2 for both molecules in the LTE approximation depending on the assumed temperature, and up to two orders of magnitude higher based on a non-LTE analysis. Conclusions: Our modeling suggests that the level of CO depletion must be extremely high (>10, and even >100 if the temperature of the core is around 10 K) at the core center, in contradiction with CO depletion levels directly measured in other cores. Observation of the H2D+ spatial distribution and direct measurement of the CO depletion in H-MM1 will be essential to confirm if present chemical models investigating the basis of deuterium [...].
(abridged) We correlated near-infrared stellar H-Ks colour excesses of background stars from NTT/SOFI with the far-IR optical depth map, tauFIR, derived from Herschel 160, 250, 350, and 500 um data. The Herschel maps were also used to construct a model for the cloud to examine the effect of temperature gradients on the estimated optical depths and dust absorption cross-sections. A linear correlation is seen between the colour H-Ks and tauFIR up to high extinctions (AV ~ 25). The correlation translates to the average extinction ratio A250um/AJ = 0.0014 +/- 0.0002, assuming a standard near-infrared extinction law and a dust emissivity index beta=2. Using an empirical NH/AJ ratio we obtain an average absorption cross-section per H nucleus of sigmaH(250um) = (1.8 +/- 0.3) * 10^(-25) cm^2 / H-atom, corresponding to a cross-section per unit mass of gas kappaG(250 um) = 0.08 +/- 0.01 cm^2 / g. The cloud model however suggests that owing to the bias caused by temperature changes along the line-of-sight these values underestimate the true cross-sections by up to 40% near the centre of the core. Assuming that the model describes the effect of the temperature variation on tauFIR correctly, we find that the relationship between H-Ks and tauFIR agrees with the recently determined relationship between sigmaH and NH in Orion A. The derived far-IR cross-section agrees with previous determinations in molecular clouds with moderate column densities, and is not particularly large compared with some other cold cores. We suggest that this is connected to the core not beng very dense (the central density is likely to be ~10^5 cm^-3) and judging from previous molecular line data, it appears to be at an early stage of chemical evolution.
Complex organic molecules (COMs) are detected in many regions of the interstellar medium, including prestellar cores. However, their formation mechanisms in cold (~10 K) cores remain to this date poorly understood. The formyl radical HCO is an important candidate precursor for several O-bearing terrestrial COMs in cores, as an abundant building block of many of these molecules. Several chemical routes have been proposed to account for its formation, both on grain surfaces, as an incompletely hydrogenated product of H addition to frozen-out CO molecules, or in the gas phase, either the product of the reaction between H2CO and a radical, or as a product of dissociative recombination of protonated formaldehyde H2COH+. The detection and abundance determination of H2COH+, if present, could provide clues as to whether this latter scenario might apply. We searched for protonated formaldehyde H2COH+ in the prestellar core L1689B using the IRAM 30m telescope. The H2COH+ ion is unambiguously detected, for the first time in a cold (~10 K) source. The derived abundance agrees with a scenario in which the formation of H2COH+ results from the protonation of formaldehyde. We use this abundance value to constrain the branching ratio of the dissociative recombination of H2COH+ towards the HCO channel to ~10-30%. This value could however be smaller if HCO can be efficiently formed from gas-phase neutral-neutral reactions, and we stress the need for laboratory measurements of the rate constants of these reactions at 10 K. Given the experimental difficulties in measuring branching ratios experimentally, observations can bring valuable constraints on these values, and provide a useful input for chemical networks.
Using Galactic Plane surveys, we have selected a massive (1200 M$_odot$), cold (14 K) 3.6-70 $mu$m dark IRDC G331.372-00.116. This IRDC has the potential to form high-mass stars and, given the absence of current star formation signatures, it seems to represent the earliest stages of high-mass star formation. We have mapped the whole IRDC with the Atacama Large Millimeter/submillimeter Array (ALMA) at 1.1 and 1.3 mm in dust continuum and line emission. The dust continuum reveals 22 cores distributed across the IRDC. In this work, we analyze the physical properties of the most massive core, ALMA1, which has no molecular outflows detected in the CO (2-1), SiO (5-4), and H$_2$CO (3-2) lines. This core is relatively massive ($M$ = 17.6 M$_odot$), subvirialized (virial parameter $alpha_{vir}=M_{vir}/M=0.14$), and is barely affected by turbulence (transonic Mach number of 1.2). Using the HCO$^+$ (3-2) line, we find the first detection of infall signatures in a relatively massive, prestellar core (ALMA1) with the potential to form a high-mass star. We estimate an infall speed of 1.54 km s$^{-1}$ and a high accretion rate of 1.96 $times$ 10$^{-3}$ M$_odot$ yr$^{-1}$. ALMA1 is rapidly collapsing, out of virial equilibrium, more consistent with competitive accretion scenarios rather than the turbulent core accretion model. On the other hand, ALMA1 has a mass $sim$6 times larger than the clumps Jeans mass, being in an intermediate mass regime ($M_{J}=2.7<Mlesssim$ 30 M$_odot$), contrary to what both the competitive accretion and turbulent core accretion theories predict.
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