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Register a new userConvergence to the complex balanced equilibrium for some chemical reaction-diffusion systems with boundary equilibria
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In this paper we study the rate of convergence to the complex balanced equilibrium for some chemical reaction-diffusion systems with boundary equilibria. We first analyze a three-species system with boundary equilibria in some stoichiometric classes, and whose right hand side is bounded above by a quadratic nonlinearity in the positive orthant. We prove similar results on the convergence to the positive equilibrium for a fairly general two-species reversible reaction-diffusion network with boundary equilibria.
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The convergence to equilibrium for renormalised solutions to nonlinear reaction-diffusion systems is studied. The considered reaction-diffusion systems arise from chemical reaction networks with mass action kinetics and satisfy the complex balanced condition. By applying the so-called entropy method, we show that if the system does not have boundary equilibria, then any renormalised solution converges exponentially to the complex balanced equilibrium with a rate, which can be computed explicitly up to a finite dimensional inequality. This inequality is proven via a contradiction argument and thus not explicitly. An explicit method of proof, however, is provided for a specific application modelling a reversible enzyme reaction by exploiting the specific structure of the conservation laws. Our approach is also useful to study the trend to equilibrium for systems possessing boundary equilibria. More precisely, to show the convergence to equilibrium for systems with boundary equilibria, we establish a sufficient condition in terms of a modified finite dimensional inequality along trajectories of the system. By assuming this condition, which roughly means that the system produces too much entropy to stay close to a boundary equilibrium for infinite time, the entropy method shows exponential convergence to equilibrium for renormalised solutions to complex balanced systems with boundary equilibria.
A decomposition of a chemical reaction network (CRN) is produced by partitioning its set of reactions. The partition induces networks, called subnetworks, that are smaller than the given CRN which, at this point, can be called parent network. A complex is called a common complex if it occurs in at least two subnetworks in a decomposition. A decomposition is said to be incidence independent if the image of the incidence map of the parent network is the direct sum of the images of the subnetworks incidence maps. It has been recently discovered that the complex balanced equilibria of the parent network and its subnetworks are fundamentally connected in an incidence independent decomposition. In this paper, we utilized the set of common complexes and a developed criterion to investigate decompositions incidence independence properties. A framework was also developed to analyze decomposition classes with similar structure and incidence independence properties. We identified decomposition classes that can be characterized by their sets of common complexes and studied their incidence independence. Some of these decomposition classes occur in some biological and chemical models. Finally, a sufficient condition was obtained for the complex balancing of some power law kinetic (PLK) systems with incidence independent and complex balanced decompositions. This condition led to a generalization of the Defficiency Zero Theorem for some PLK systems.
In this paper, the applicability of the entropy method for the trend towards equilibrium for reaction-diffusion systems arising from first order chemical reaction networks is studied. In particular, we present a suitable entropy structure for weakly reversible reaction networks without detail balance condition. We show by deriving an entropy-entropy dissipation estimate that for any weakly reversible network each solution trajectory converges exponentially fast to the unique positive equilibrium with computable rates. This convergence is shown to be true even in cases when the diffusion coefficients all but one species are zero. For non-weakly reversible networks consisting of source, transmission and target components, it is shown that species belonging to a source or transmission component decay to zero exponentially fast while species belonging to a target component converge to the corresponding positive equilibria, which are determined by the dynamics of the target component and the mass injected from other components. The results of this work, in some sense, complete the picture of trend to equilibrium for first order chemical reaction networks.
This is the second part of our study of the Inertial Manifolds for 1D systems of reaction-diffusion-advection equations initiated in cite{KZI} and it is devoted to the case of periodic boundary conditions. It is shown that, in contrast to the case of Dirichlet or Neumann boundary conditions, considered in the first part, Inertial Manifolds may not exist in the case of systems endowed by periodic boundary conditions. However, as also shown, inertial manifolds still exist in the case of scalar reaction-diffusion-advection equations. Thus, the existence or non-existence of inertial manifolds for this class of dissipative systems strongly depend on the choice of boundary conditions.
When the temperature of a trapped Bose gas is below the Bose-Einstein transition temperature and above absolute zero, the gas is composed of two distinct components: the Bose-Einstein condensate and the cloud of thermal excitations. The dynamics of the excitations can be described by quantum Boltzmann models. We establish a connection between quantum Boltzmann models and chemical reaction networks. We prove that the discrete differential equations for these quantum Boltzmann models converge to an equilibrium point. Moreover, this point is unique for all initial conditions that satisfy the same conservation laws. In the proof, we then employ a toric dynamical system approach, similar to the one used to prove the global attractor conjecture, to study the convergence to equilibrium of quantum kinetic equations, derived in [49,50].
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