No Arabic abstract
We measure the differential polarizability of the $^{176}$Lu$^+$ $^1S_0$ -to- ${^3}D_1$ clock transition at multiple wavelengths. This experimentally characterizes the differential dynamic polarizability for frequencies up to 372 THz and allows an experimental determination of the dynamic correction to the blackbody radiation shift for the clock transition. In addition, measurements at the near resonant wavelengths of 598 and 646 nm determine the two dominant contributions to the differential dynamic polarizability below 372 THz. These additional measurements are carried out by two independent methods to verify the validity of our methodology. We also carry out a theoretical calculation of the polarizabilities using the hybrid method that combines the configuration interaction (CI) and the coupled-cluster approaches, incorporating for the first time quadratic non-linear terms and partial triple excitations in the coupled-cluster calculations. The experimental measurements of the $|langle ^3D_1|| r || ^3P_Jrangle|$ matrix elements provide high-precision benchmarks for this theoretical approach.
High precision spectroscopy of the $^1S_0$-to-${^1}D_2$ clock transition of $^{176}$Lu is reported. Measurements are performed with Hertz level precision with the accuracy of the hyperfine-averaged frequency limited by the calibration of an active hydrogen maser to the SI definition of the second via a GPS link. The measurements also provide accurate determination of the $^1D_2$ hyperfine structure. Hyperfine structure constants associated with the magnetic octupole and electric hexadecapole moments of the nucleus are considered, which includes a derivation of correction terms from third-order perturbation theory.
A calculation of dynamic polarizabilities of rovibrational states with vibrational quantum number $v=0-7$ and rotational quantum number $J=0,1$ in the 1s$sigma_g$ ground-state potential of HD$^+$ is presented. Polarizability contributions by transitions involving other 1s$sigma_g$ rovibrational states are explicitly calculated, whereas contributions by electronic transitions are treated quasi-statically and partially derived from existing data [R.E. Moss and L. Valenzano, textit{Molec. Phys.}, 2002, textbf{100}, 1527]. Our model is valid for wavelengths $>4~mu$m and is used to to assess level shifts due to the blackbody radiation (BBR) electric field encountered in experimental high-resolution laser spectroscopy of trapped HD$^+$ ions. Polarizabilities of 1s$sigma_g$ rovibrational states obtained here agree with available existing accurate textit{ab initio} results. It is shown that the Stark effect due to BBR is dynamic and cannot be treated quasi-statically, as is often done in the case of atomic ions. Furthermore it is pointed out that the dynamic Stark shifts have tensorial character and depend strongly on the polarization state of the electric field. Numerical results of BBR-induced Stark shifts are presented, showing that Lamb-Dicke spectroscopy of narrow vibrational optical lines ($sim 10$ Hz natural linewidth) in HD$^+$ will become affected by BBR shifts only at the $10^{-16}$ level.
We consider hyperfine-mediated effects for clock transitions in $^{176}$Lu$^+$. Mixing of fine structure levels due to the hyperfine interaction bring about modifications to Lande $g$-factors and the quadrupole moment for a given state. Explicit expressions are derived for both $g$-factor and quadrupole corrections, for which leading order terms arise from the nuclear magnetic dipole coupling. High accuracy measurements of the $g$-factors for the $^1S_0$ and $^3D_1$ hyperfine levels are carried out, which provide an experimental determination of the leading order correction terms.
Despite being a canonical example of quantum mechanical perturbation theory, as well as one of the earliest observed spectroscopic shifts, the Stark effect contributes the largest source of uncertainty in a modern optical atomic clock through blackbody radiation. By employing an ultracold, trapped atomic ensemble and high stability optical clock, we characterize the quadratic Stark effect with unprecedented precision. We report the ytterbium optical clocks sensitivity to electric fields (such as blackbody radiation) as the differential static polarizability of the ground and excited clock levels: 36.2612(7) kHz (kV/cm)^{-2}. The clocks fractional uncertainty due to room temperature blackbody radiation is reduced an order of magnitude to 3 times 10^{-17}.
We report a measurement of the dynamical polarizability of dysprosium atoms in their electronic ground state at the optical wavelength of 1064 nm, which is of particular interest for laser trapping experiments. Our method is based on collective oscillations in an optical dipole trap, and reaches unprecedented accuracy and precision by comparison with an alkali atom (potassium) as a reference species. We obtain values of 184.4(2.4) a.u. and 1.7(6) a.u. for the scalar and tensor polarizability, respectively. Our experiments have reached a level that permits meaningful tests of current theo- retical descriptions and provides valuable information for future experiments utilizing the intriguing properties of heavy lanthanide atoms.