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Register a new userLightweight Carbon Fiber Mirrors for Solar Concentrator Applications
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Lightweight parabolic mirrors for solar concentrators have been fabricated using carbon fiber reinforced polymer (CFRP) and a nanometer scale optical surface smoothing technique. The smoothing technique improved the surface roughness of the CFRP surface from ~3 {mu}m root mean square (RMS) for as-cast to ~5 nm RMS after smoothing. The surfaces were then coated with metal, which retained the sub-wavelength surface roughness, to produce a high-quality specular reflector. The mirrors were tested in an 11x geometrical concentrator configuration and achieved an optical efficiency of 78% under an AM0 solar simulator. With further development, lightweight CFRP mirrors will enable dramatic improvements in the specific power, power per unit mass, achievable for concentrated photovoltaics in space.
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The controlled growth of carbon nitride (CN) films with tailored electronic properties and surface area is quite challenging due to the solid-state reaction and the lack of efficient interaction between C-N monomers and substrates. Herein, controlled growth of CN films over robust carbon nanotubes (CNT) fiber fabric is reported, which is obtained by either direct calcination of melamine on their surface, that yields a bulk material, or by its chemical vapor deposition resulting in hybrid films. These materials are effective electrodes consisting of high surface-area CN containing CNT fiber fabrics acting as a scaffold and a highly conducting built-in current collector. The results confirm that CNTs act as nucleation centers for the formation of CN films, forming close contact at the CN/CNT interphase, and resulting in efficient charge transfer upon illumination and enhanced electrochemical surface area.
However, their electrocatalytic activity is still poorly understood. This work deciphers the origin of the catalytic activity of counter-electrodes (CEs)/current collectors made of self-standing carbon nanotubes fibers (CNTfs) using Co$^(+2)$/Co$^(+3)$ redox couple electrolytes. This is based on comprehensive electrochemical and spectroscopic characterizations of fresh and used electrodes applied to symmetric electrochemical cells using platinum-based CEs as a reference. As the most relevant findings, two straight relationships were established: i) the limiting current and stability increase rapidly with surface concentration of oxygen-containing functional groups, and ii) the catalytic potential is inversily related to the amount of residual metallic Fe catalyst nanoparticles interspersed in the CNTf network. Finally, the fine tune of the metallic nanoparticle content and the degree of functionalization enabled fabrication of efficient and stable dye-sensitized solar cells with cobalt electrolytes and CNTf-CE outperforming those with reference Pt-CEs.
We have used copper-coated carbon fiber reinforced plastic (CuCFRP) for the construction of high and ultra-high vacuum recipients. The vacuum performance is found to be comparable to typical stainless steel used for this purpose. In test recipients we have reached pressures of 2E-8 mbar and measured a desorption rate of 1E-11 mbar*liter/s/cm^2; no degradation over time (2 years) has been found. Suitability for baking has been found to depend on the CFRP production process, presumably on the temperature of the autoclave curing. Together with other unique properties of CuCFRP such as low weight and being nearly non-magnetic, this makes it an ideal material for many high-end vacuum applications.
We present a compact and lightweight 1.5 {mu}m lidar using a free-running single-photon detector (SPD) based on a multi-mode fiber (MMF) coupling InGaAs/InP negative feedback avalanche diode. The ultimate light detection sensitivity of SPD highly reduces the power requirement of laser, whilst the enhanced collection efficiency due to MMF coupling significantly reduces the volume and weight of telescopes. We develop a specific algorithm for the corrections of errors caused by the SPD and erbium-doped fiber amplifier to extract accurate backscattering signals. We also perform a comparison between single-mode fiber (SMF) coupling and MMF coupling in the lidar receiver, and the results show that the collection efficiency with MMF coupling is five times higher than SMF coupling. In order to validate the functionality, we use the lidar system for the application of cloud detection. The lidar system exhibits the ability to detect both the cloud base height and the thickness of multi-layer clouds to an altitude of 12 km with a temporal resolution of 1 s and a spatial resolution of 15 m. Due to the advantages of compactness and lightweight, our lidar system can be installed on unmanned aerial vehicles for wide applications in practice.
Patterning of diamond-like carbon (DLC) and DLC:metal nanocomposites is of interest for an increasing number of applications. We demonstrate a nanoimprint lithography process based on silicon containing thermoplastic resist combined with plasma etching for straightforward patterning of such films. A variety of different structures with few hundred nanometer feature size and moderate aspect ratios were successfully realized. The quality of produced patterns was directly investigated by the means of optical and scanning electron microscopy (SEM). Such structures were further assessed by employing them in the development of gratings for guided mode resonance (GMR) effect. Optical characterization of such leaky waveguide was compared with numerical simulations based on rigorous coupled wave analysis method with good agreement. The use of such structures as refractive index variation sensors is demonstrated with sensitivity up to 319 nm/RIU, achieving an improvement close to 450% in sensitivity compared to previously reported similar sensors. This pronounced GMR signal fully validates the employed DLC material, the technology to pattern it and the possibility to develop DLC based gratings as corrosion and wear resistant refractometry sensors that are able to operate under harsh conditions providing great value and versatility.
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