Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userOptical spectroscopy of complex open 4$d$-shell ions Sn$^{7+}$-Sn$^{10+}$
81
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We analyze the complex level structure of ions with many-valence-electron open [Kr] 4$d^textrm{m}$ sub-shells ($textrm{m}$=7-4) with ab initio calculations based on configuration-interaction many-body perturbation theory (CI+MBPT). Charge-state-resolved optical and extreme ultraviolet (EUV) spectra of Sn$^{7+}$-Sn$^{10+}$ ions were obtained using an electron beam ion trap. Semi-empirical spectral fits carried out with the orthogonal parameters technique and Cowan code calculations lead to 90 identifications of magnetic-dipole transitions and the determination of 79 energy ground-configuration levels, questioning some earlier EUV-line assignments. Our results, the most complete data set available to date for these ground configurations, confirm the ab initio predictive power of CI+MBPT calculations for the these complex electronic systems.
rate research
Read More
We experimentally re-evaluate the fine structure of Sn$^{11+...14+}$ ions. These ions are essential in bright extreme-ultraviolet (EUV) plasma-light sources for next-generation nanolithography, but their complex electronic structure is an open challenge for both theory and experiment. We combine optical spectroscopy of magnetic dipole $M1$ transitions, in a wavelength range covering 260,nm to 780,nm, with charge-state selective ionization in an electron beam ion trap. Our measurements confirm the predictive power of emph{ab initio} calculations based on Fock space coupled cluster theory. We validate our line identification using semi-empirical Cowan calculations with adjustable wavefunction parameters. Available Ritz combinations further strengthen our analysis. Comparison with previous work suggests that line identifications in the EUV need to be revisited.
We report optical and infrared spectroscopic observations of the Type Ia SN 1999ee and the Type Ib/c SN 1999ex, both of which were hosted by the galaxy IC 5179. For SN 1999ee we obtained a continuous sequence with an unprecedented wavelength and temporal coverage beginning 9 days before maximum light and extending through day 42. Before maximum light SN 1999ee displayed a normal spectrum with a strong Si II 6355 absorption, thus showing that not all slow-declining SNe are spectroscopically peculiar at these evolutionary phases. A comparative study of the infrared spectra of SN 1999ee and other Type Ia supernovae shows that there is a remarkable homogeneity among the Branch-normal SNe Ia during their first 60 days of evolution. SN 1991bg-like objects, on the other hand, display spectroscopic peculiarities at infrared wavelengths. SN 1999ex was characterized by the lack of hydrogen lines, weak optical He I lines, and strong He I 10830,20581, thus providing an example of an intermediate case between pure Ib and Ic supernovae. We conclude therefore that SN 1999ex provides first clear evidence for a link between the Ib and Ic classes and that there is a continuous spectroscopic sequence ranging from the He deficient SNe Ic to the SNe Ib which are characterized by strong optical He I lines.
We perform optical spectroscopy measurement across the charge density wave (CDW) phase transitions on single-crystal samples of Sr$_{3}$Rh$_{4}$Sn$_{13}$ and (Sr$_{0.5}$Ca$_{0.5}$)$_{3}$Rh$_{4}$Sn$_{13}$. Formation of CDW energy gap was clearly observed for both single-crystal samples when they undergo the phase transitions. The existence of a Drude component in $sigma_1(omega)$ below TCDW indicates that the Fermi surface is only partially gapped in the CDW state. The obtained value of 2$Delta$/K$_{B}$T$_{CDW}$ is roughly 13 for both Sr$_{3}$Rh$_{4}$Sn$_{13}$ and (Sr$_{0.5}$Ca$_{0.5}$)$_{3}$Rh$_{4}$Sn$_{13}$ compounds. The value is considerably larger than the mean-field value based on the weak-coupling BCS theory. The observed spectral feature in (Sr$_{x}$Ca$_{1-x}$)$_{3}$Rh$_{4}$Sn$_{13}$ resembles those seen in many other CDW systems.
X-ray photoabsorption cross sections have been computed for all magnesium ions using the $R$-matrix method. A comparison with the other available data for Mg II-Mg X shows good qualitative agreement in the resultant resonance shapes. However, for the lower ionization stages, and for singly-ionized Mg II in particular, the previous $R$-matrix results (Witthoeft et al.2009; Witthoeft et al. 2011) overestimate the K-edge position due to the neglect of important orbital relaxation effects, and a global shift downward in photon energy of those cross sections is therefore warranted. We have found that the cross sections for Mg I and Mg II are further complicated by the M-shell ($n=3$) occupancy. As a result, the treatment of spectator Auger decay of $1srightarrow np$ resonances using a method based on multichannel quantum defect theory and an optical potential becomes problematic, making it necessary to implement an alternative, approximate treatment of Auger decay for neutral Mg. The new cross sections are used to fit the Mg K edge in XMM-Newton spectra of the low-mass X-ray binary GS 1826-238, where most of the interstellar Mg is found to be in ionized form.
A recent measurement of the dielectronic recombination (DR) of W^20+ [Schippers et al Phys. Rev. A83, 012711 (2011)] found an exceptionally large contribution from near threshold resonances (<1eV). This still affected the Maxwellian rate coefficient at much higher temperatures. The experimental result was found to be a factor 4 or more than that currently in use in the 100-300eV range which is of relevance for modeling magnetic fusion plasmas. We have carried-out DR calculations with AUTOSTRUCTURE which include all significant single electron promotions. Our intermediate coupling (IC) results are more than a factor of 4 larger than our LS-coupling ones at 1eV but still lie a factor 3 below experiment here. If we assume complete (chaotic) mixing of near-threshold autoionizing states then our results come into agreement (to within 20%) with experiment below about 2eV. Our total IC Maxwellian rate coefficients are 50-30% smaller than those based-on experiment over 100-300eV.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
