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Register a new userPhonon Anharmonicity in Bulk $T_d$-MoTe$_2$
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We examine anharmonic contributions to the optical phonon modes in bulk $T_d$-MoTe$_2$ through temperature-dependent Raman spectroscopy. At temperatures ranging from 100 K to 200 K, we find that all modes redshift linearly with temperature in agreement with the Gr{u}neisen model. However, below 100 K we observe nonlinear temperature-dependent frequency shifts in some modes. We demonstrate that this anharmonic behavior is consistent with the decay of an optical phonon into multiple acoustic phonons. Furthermore, the highest frequency Raman modes show large changes in intensity and linewidth near $Tapprox 250$ K that correlate well with the $T_d to 1T^prime$ structural phase transition. These results suggest that phonon-phonon interactions can dominate anharmonic contributions at low temperatures in bulk $T_d$-MoTe$_2$, an experimental regime that is currently receiving attention in efforts to understand Weyl semimetals.
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Crystalline two-dimensional (2D) superconductors with low carrier density are an exciting new class of materials in which superconductivity coexists with strong interactions, the effects of complex topology are not obscured by disorder, and electronic properties can be strongly tuned by electrostatic gating. Very recently, two such materials, magic-angle twisted bilayer graphene and monolayer $T_d$-WTe$_2$, have been reported to show superconductivity at temperatures near 1 K. Here we report superconductivity in semimetallic monolayer $T_d$-MoTe$_2$. The critical temperature $T_textrm{c}$ reaches 8 K, a sixty-fold enhancement as compared to the bulk. This anomalous increase in $T_textrm{c}$ is only observed in monolayers, and may be indicative of electronically mediated pairing. Reflecting the low carrier density, the critical temperature, magnetic field, and current density are all tunable by an applied gate voltage, revealing a superconducting dome that extends across both hole and electron pockets. The temperature dependence of the in-plane upper critical field is distinct from that of $2H$ transition metal dichalcogenides (TMDs), consistent with a tilted spin texture as predicted by textit{ab initio} theory.
In many realistic topological materials, more than one kind of fermions contribute to the electronic bands crossing the Fermi level, leading to various novel phenomena. Here, using momentum-resolved inelastic electron scattering, we investigate the plasmons and their evolution across the phase transition in a type-II Weyl Semimetal MoTe$_2$, in which both Weyl fermions and trivial nonrelativistic fermions contribute to the Fermi surface in the Td phase. One plasmon mode in the 1T phase at high temperature and two plasmon modes in the topological T$_d$ phase at low temperature are observed. Combining with first-priciples calculations, we show that all the plasmon modes are dominated by the interband correlations between the inverted bands of MoTe$_2$. Especially in the T$_d$ phase, since the electronic bands split due to inversion symmetry breaking and spin-orbit coupling, the plasmon modes manifest the interband correlation between the topological Weyl fermions and the trivial nonrelativistic electrons. Our work emphasizes the significance of the interplay between different kinds of carriers in plasmons of topological materials.
We have utilized time-domain magneto-terahertz spectroscopy to investigate the low frequency optical response of topological insulator Cu$_{0.02}$Bi$_2$Se$_3$ and Bi$_2$Se$_3$ films. With both field and frequency dependence, such experiments give sufficient information to measure the mobility and carrier density of multiple conduction channels simultaneously. We observe sharp cyclotron resonances (CRs) in both materials. The small amount of Cu incorporated into the Cu$_{0.02}$Bi$_2$Se$_3$ induces a true bulk insulator with only a textit{single} type of conduction with total sheet carrier density $sim4.9times10^{12}/$cm$^{2}$ and mobility as high as 4000 cm$^{2}/$V$cdot$s. This is consistent with conduction from two virtually identical topological surface states (TSSs) on top and bottom of the film with a chemical potential $sim$145 meV above the Dirac point and in the bulk gap. The CR broadens at high fields, an effect that we attribute to an electron-phonon interaction. This assignment is supported by an extended Drude model analysis of the zero field Drude conductance. In contrast, in normal Bi$_2$Se$_3$ films two conduction channels were observed and we developed a self-consistent analysis method to distinguish the dominant TSSs and coexisting trivial bulk/2DEG states. Our high-resolution Faraday rotation spectroscopy on Cu$_{0.02}$Bi$_2$Se$_3$ paves the way for the observation of quantized Faraday rotation under experimentally achievable conditions to push chemical potential in the lowest Landau Level.
Whereas electron-phonon scattering typically relaxes the electrons momentum in metals, a perpetual exchange of momentum between phonons and electrons conserves total momentum and can lead to a coupled electron-phonon liquid with unique transport properties. This theoretical idea was proposed decades ago and has been revisited recently, but the experimental signatures of an electron-phonon liquid have been rarely reported. We present evidence of such a behavior in a transition metal ditetrelide, NbGe$_2$, from three different experiments. First, quantum oscillations reveal an enhanced quasiparticle mass, which is unexpected in NbGe$_2$ due to weak electron-electron correlations, hence pointing at electron-phonon interactions. Second, resistivity measurements exhibit a discrepancy between the experimental data and calculated curves within a standard Fermi liquid theory. Third, Raman scattering shows anomalous temperature dependence of the phonon linewidths which fits an empirical model based on phonon-electron coupling. We discuss structural factors, such as chiral symmetry, short metallic bonds, and a low-symmetry coordination environment as potential sources of coupled electron-phonon liquids.
Weyl semimetals display a novel topological phase of matter where the Weyl nodes emerge in pairs of opposite chirality and can be seen as either a source or a sink of Berry curvature. The exotic effects in Weyl semimetals, such as surface Fermi arcs and the chiral anomaly, make them a new playground for exploring novel functionalities. Further exploiting their potential applications requires clear understanding of their topological electronic properties, such as Weyl points and Fermi arcs. Here we report a Fourier transform scanning tunneling spectroscopy (FT-STS) study on a type-II Weyl semimetal candidate MoTe$_2$ whose Weyl points are predicated to be located above Fermi level. Although its electronic structure below the Fermi level have been identified by angle resolved photo emission spectroscopy (ARPES), by comparing our experimental data with first-principles calculations, we are able to identify the origins of the multiple scattering channels at energies both below and above Fermi level. Our calculations also show the existence of both trivial and topological arc like states above the Fermi energy. In the FT-STS experiments, we have observed strong signals from intra-arc scatterings as well as from the scattering between the arc-like surface states and the projected bulk states. A detailed comparison between our experimental observations and calculated results reveals the trivial and non-trivial scattering channels are difficult to distinguish in this compound. Interestingly, we find that the broken inversion symmetry changes the terminating states on the two inequivalent surfaces, which in turn changes the relative strength of the scattering channels observed in the FT-STS images on the two surfaces.
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