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Register a new userPhonon Anomalies, Orbital-Ordering and Electronic Raman Scattering in iron-pnictide Ca(Fe0.97Co0.03)2As2: Temperature-dependent Raman Study
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We report inelastic light scattering studies on Ca(Fe0.97Co0.03)2As2 in a wide spectral range of 120-5200 cm-1 from 5K to 300K, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at Tsm ~ 160K. The mode frequencies of two first-order Raman modes B1g and Eg, both involving displacement of Fe atoms, show sharp increase below Tsm. Concomitantly, the linewidths of all the first-order Raman modes show anomalous broadening below Tsm, attributed to strong spin-phonon coupling. The high frequency modes observed between 400-1200 cm-1 are attributed to the electronic Raman scattering involving the crystal field levels of d-orbitals of Fe2+. The splitting between xz and yz d-orbital levels is shown to be ~ 25 meV which increases as temperature decreases below Tsm. A broad Raman band observed at ~ 3200 cm-1 is assigned to two-magnon excitation of the itinerant Fe 3d antiferromagnet.
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Inelastic light scattering studies on single crystal of electron-doped Ca(Fe0.95Co0.05)2As2 superconductor, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at TSM ~ 140 K and superconducting transition temperature Tc ~ 23 K, reveal evidence for superconductivity-induced phonon renormalization; in particular the phonon mode near 260 cm-1 shows hardening below Tc, signaling its coupling with the superconducting gap. All the three Raman active phonon modes show anomalous temperature dependence between room temperature and Tc i.e phonon frequency decreases with lowering temperature. Further, frequency of one of the modes shows a sudden change in temperature dependence at TSM. Using first-principles density functional theory-based calculations, we show that the low temperature phase (Tc < T < TSM) exhibits short-ranged stripe anti-ferromagnetic ordering, and estimate the spin-phonon couplings that are responsible for these phonon anomalies.
Based on a two-band model, we study the electronic Raman scattering intensity in both normal and superconducting states of iron-pnictide superconductors. For the normal state, due to the match or mismatch of the symmetries between band hybridization and Raman vertex, it is predicted that overall $B_{1g}$ Raman intensity should be much weaker than that of the $B_{2g}$ channel. Moreover, in the non-resonant regime, there should exhibit a interband excitation peak at frequency $omegasimeq 7.3 t_1 (6.8t_1)$ in the $B_{1g}$ ($B_{2g}$) channel. For the superconducting state, it is shown that $beta$-band contributes most to the $B_{2g}$ Raman intensity as a result of multiple effects of Raman vertex, gap symmetry, and Fermi surface topology. Both extended $s$- and $d_{xy}$-wave pairings in the unfolded BZ can give a good description to the reported $B_{2g}$ Raman data [Muschler {em et al.}, Phys. Rev. B. {bf 80}, 180510 (2009).], while $d_{x^2-y^2}$-wave pairing in the unfolded BZ seems to be ruled out.
The electronic Raman scattering in overdoped (Y,Ca)Ba2Cu3Oy was investigated with changing hole concentration in the superconducting state. It was found that the superconducting responses such as the pair-breaking peaks in the A1g and B1g spectra and the anisotropy of the pair-breaking peak in XX and YY polarizations radically change at around the carrier doping p=0.19. Since both a- and c-axis resistivities strongly suggest the closing of pseudogap at p~0.18, the observed change at p=0.19 in superconducting Raman response is attributed to the electronic crossover due to the collapse of the pseudogap.
Iron-based superconducting layered compounds have the second highest transition temperature after cuprate superconductors. Their discovery is a milestone in the history of high-temperature superconductivity and will have profound implications for high-temperature superconducting mechanism as well as industrial applications. Raman scattering has been extensively applied to correlated electron systems including the new superconductors due to its unique ability to probe multiple primary excitations and their coupling. In this review, we will give a brief summary of the existing Raman experiments in the iron-based materials and their implication for pairing mechanism in particular. And we will also address some open issues from the experiments.
Electron-phonon coupling (EPC) is one of the most common and fundamental interactions in solids. It not only dominates many basic dynamic processes like resistivity, thermal conductivity etc, but also provides the pairing glue in conventional superconductors. But in high-temperature superconductors (HTSC), it is still controversial whether or not EPC is in favor of paring. Despite the controversies, many experiments have provided clear evidence for EPC in HTSC. In this paper, we briefly review EPC in cuprate and iron-based superconducting systems revealed by Raman scattering. We introduce how to extract the coupling information through phonon lineshape. Then we discuss the strength of EPC in different HTSC systems and possible factors affecting the strength. The comparative study between Raman phonon theories and experiments allows us to gain insight into some crucial electronic properties, especially superconductivity. Finally we summarize and compare EPC in the two existing HTSC systems, and discuss what role it may play in HTSC.
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