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Register a new user31P NMR Investigation of the Superconductor LiFeP (Tc = 5 K)
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We investigate the static and dynamic spin susceptibility of the 111 type Fe-based superconductor LiFeP with Tc ~ 5 K through the measurement of Knight shift 31K and the spin-lattice relaxation rate 1/T1 at 31P site by nuclear magnetic resonance. The constant 31K, small magnitudes of 1/T1T, along with the resistivity rho ~ T^2 all point to the weak spin correlations in LiFeP. 1/T1T display small enhancement toward Tc, indicating that the superconductivity is intimately correlated with the antiferromagnetic spin fluctuations.
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We report $^{75}$As NMR measurements on the new quasi one-dimensional superconductor K$_{2}$Cr$_{3}$As$_{3}$ ($T_{c} sim 6.1$~K) [J. K. Bao et al., Phys. Rev. X {bf 5}, 011013 (2015)]. We found evidence for strong enhancement of Cr spin fluctuations above $T_c$ in the [Cr$_{3}$As$_{3}$]$_{infty}$ double-walled subnano-tubes based on the nuclear spin-lattice relaxation rate $1/T_{1}$. The power law temperature dependence, $1/T_{1}T sim T^{-gamma}$ ($gamma sim 0.25$), is consistent with the Tomonaga-Luttinger liquid. Moreover, absence of the Hebel-Slichter coherence peak of $1/T_{1}$ just below $T_{c}$ suggests unconventional nature of superconductivity.
Unveiling the nature of the bosonic excitations that mediate the formation of Cooper pairs is a key issue for understanding unconventional superconductivity. A fundamen- tal step toward this goal would be to identify the relative weight of the electronic and phononic contributions to the overall frequency (Omega) dependent bosonic function, Pi(Omega). We perform optical spectroscopy on Bi2212 crystals with simultaneous time- and frequency-resolution; this technique allows us to disentangle the electronic and phononic contributions by their different temporal evolution. The strength of the interaction ({lambda}~1.1) with the electronic excitations and their spectral distribution fully account for the high critical temperature of the superconducting phase transition.
We report an easy and versatile route for the synthesis of the parent phase of newest superconducting wonder material i.e. p-Terphenyl. Doped p-terphenyl has recently shown superconductivity with transition temperature as high as 120K. For crystal growth, the commercially available p-Terphenyl powder is pelletized, encapsulated in evacuated (10-4 Torr) quartz tube and subjected to high temperature (260C) melt followed by slow cooling at 5C/hour. Simple temperature controlled heating furnace is used during the process. The obtained crystal is one piece, shiny and plate like. Single crystal surface XRD (X-ray Diffraction) showed unidirectional (00l) lines, indicating that the crystal is grown along c-direction. Powder XRD of the specimen showed that as grown p-Terphenyl is crystallized in monoclinic structure with space group P21/a space group, having lattice parameters a = 8.08(2) A, b = 5.62(5) A and c= 13.58(3) A. Scanning electron microscopy (SEM) pictures of the crystal showed clear layered slab like growth without any visible contamination from oxygen. Characteristic reported Raman active modes related to C-C-C bending, C-H bending, C-C stretching and C-H stretching vibrations are seen clearly for the studied p-Terphenyl crystal. The physical properties of crystal are yet underway. The short letter reports an easy and versatile crystal growth method for obtaining quality p-terphenyl. The same growth method may probably be applied to doped p-terphenyl and to subsequently achieve superconductivity to the tune of as high 120K for the newest superconductivity wonder i.e., High Tc Oraganic Superconductor (HTOS).
Recently a new family of Cr-based A2Cr3As3 (A = K, Rb, Cs) superconductors were reported, which own a rare quasi-one-dimensional (Q1D) crystal structure with infinite (Cr3As3)2- chains and exhibit intriguing superconducting characteristics possibly derived from spin-triplet electron pairing. The crystal structure of A2Cr3As3 is actually a slight variation of the hexagonal TlFe3Te3 prototype although they have different lattice symmetry. Here we report superconductivity in a 133-type KCr3As3 compound that belongs to the latter structure. The single crystals of KCr3As3 were prepared by the deintercalation of K ions from K2Cr3As3 crystals which were grown from a high-temperature solution growth method, and it owns a centrosymmetric lattice in contrast to the non-centrosymmetric K2Cr3As3. After annealing at a moderate temperature, the KCr3As3 crystals show bulk superconductivity at 5 K revealed by electrical resistivity, magnetic susceptibility and heat capacity measurements. The discovery of this KCr3As3 superconductor provides a different structural instance to study the exotic superconductivity in these Q1D Cr-based superconductors.
The entanglement of charge density wave (CDW), superconductivity, and topologically nontrivial electronic structure has recently been discovered in the kagome metal $A$V$_3$Sb$_5$ ($A$ = K, Rb, Cs) family. With high-resolution angle-resolved photoemission spectroscopy, we study the electronic properties of CsV$_3$Sb$_5$ deep in the CDW state. The spectra around $bar{K}$ is found to exhibit a peak-dip-hump structure associated with two separate branches of dispersion, demonstrating the isotropic CDW gap opening. The peak-dip-hump lineshape is contributed by linearly dispersive Dirac bands in the lower branch and a dispersionless flat band close to $E_{rm F}$ in the upper branch. The Fermi surface nesting scenario can account for these CDW-related features. The high density of states at $E_{rm F}$ associated with the flat band could play an essential role in the onset of superconductivity.
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