We report the results of a search for spontaneous magnetism due to a time reversal symmetry breaking phase in the superconducting state of (110)-oriented YBCO films, expected near the surface in this geometry. Zero field and weak transverse field measurements performed using the low-energy muon spin rotation technique with muons implanted few nm inside optimally-doped YBCO-(110) films show no appearance of spontaneous magnetic fields below the superconducting temperature down to 2.9 K. Our results give an upper limit of ~0.02 mT for putative spontaneous internal fields.
Weak spontaneous magnetic fields are observed near the surface of YBCO films using Beta-detected Nuclear Magnetic Resonance. Below Tc, the magnetic field distribution in a silver film evaporated onto the superconductor shows additional line broadening, indicating the appearance of small disordered magnetic fields. The line broadening increases linearly with a weak external magnetic field applied parallel to the surface, and is depth-independent up to 45 nm from the Ag/YBCO interface. The magnitude of the line broadening at 10 K extrapolated to zero applied field is less than 0.2 G, and is close to nuclear dipolar broadening in the Ag. This indicates that any fields due to broken time-reversal symmetry are less than 0.2 G.
We report point contact Andreev Reflection (PCAR) measurements on a high-quality single crystal of the non-centrosymmetric superconductor Re6Zr. We observe that the PCAR spectra can be fitted by taking two isotropic superconducting gaps with Delta_1 ~ 0.79 meV and Delta_2 ~ 0.22 meV respectively, suggesting that there are at least two bands which contribute to superconductivity. Combined with the observation of time reversal symmetry breaking at the superconducting transition from muon spin relaxation measurements (Phys. Rev. Lett. 112, 107002 (2014)), our results imply an unconventional superconducting order in this compound: A multiband singlet state that breaks time reversal symmetry or a triplet state dominated by interband pairing.
Exotic superconductors, such as high T$_C$, topological, and heavy-fermion superconductors, require phase sensitive measurements to determine the underlying pairing. Here we investigate the proximity-induced superconductivity in nanowires of SnTe, where an $spm is^{prime}$ superconducting state is produced that lacks the time-reversal and valley-exchange symmetry of the parent SnTe. This effect, in conjunction with a ferroelectric distortion of the lattice at low temperatures, results in a marked alteration of the properties of Josephson junctions fabricated using SnTe nanowires. This work establishes the existence of a ferroelectric transition in SnTe nanowires and elucidates the role of ferroelectric domain walls on the flow of supercurrent through SnTe weak links. We detail two unique characteristics of these junctions: an asymmetric critical current in the DC Josephson effect and a prominent second harmonic in the AC Josephson effect. Each reveals the broken time-reversal symmetry in the junction. The novel $spm is^{prime}$ superconductivity and the new Josephson effects can be used to investigate fractional vortices [1,2], topological superconductivity in multiband materials [3-5], and new types of Josephson-based devices in proximity-induced multiband and ferroelectric superconductors [6,7].
The symmetry properties of the order parameter characterize different phases of unconventional superconductors. In the case of the heavy-fermion superconductor UPt$_3$, a key question is whether its multiple superconducting phases preserve or break time-reversal symmetry (TRS). We tested for asymmetry in the phase shift between left and right circularly polarized light reflected from a single crystal of UPt$_3$ at normal incidence, finding that this so-called polar Kerr effect appears only below the lower of the two zero-field superconducting transition temperatures. Our results provide evidence for broken TRS in the low-temperature superconducting phase of UPt$_3$, implying a complex two-component order parameter for superconductivity in this system.
A novel superconducting state under the broken time-reversal symmetry is studied in conventional phonon-mediated superconductors. By solving the Eliashberg equation self-consistently with the mass renormalization effect, it is found that the even- and odd-frequency components of the order parameter coexist in the bulk system as a consequence of the broken time-reversal symmetry. This finding would direct more attention to the odd-frequency pairing that affects physical quantities, especially in strong coupling superconductors.