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Register a new userThe Influence of Crystallinity Degree on the Glycine Decomposition Induced by 1 MeV Proton Bombardment in Space Analog Conditions
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Sergio Pilling
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Glycine is the simplest proteinaceous amino acid and is present in all life-forms on Earth. In aqueous solutions, it appears mainly as zwitterion glycine (+NH3CH2COO-); however, in solid phase, it may be found in amorphous or crystalline (alpha, beta, and gamma) forms. This molecular species has been extensively detected in carbonaceous meteorites and was recently observed in the cometary samples returned to Earth by NASAs Stardust spacecraft. We present an experimental study on the destruction of zwitterionic glycine crystals at room temperature by 1 MeV protons, in which the dependence of the destruction rates of the alpha-glycine and beta-glycine crystals on bombardment fluence is investigated. The samples were analyzed in situ by FTIR spectrometry at different proton fluences at under ultrahigh vacuum conditions at the Van de Graaff accelerator lab at PUC-Rio, Brazil. The dissociation cross section of alpha-glycine was observed to be 2.5E-14 cm^-2, a value roughly 5 times higher than the dissociation cross section found for beta-glycine. The estimated half-lives of alpha-glycine and beta-glycine forms extrapolated to the Earth orbit environment are 9E5 and 4E6 years, respectively. In the diffuse interstellar medium the estimated values are 1 order of magnitude lower. These results suggest that pristine interstellar beta-glycine is the one most likely to survive the hostile environments of space radiation. A small feature around 1650-1700 cm^-1, tentatively attributed to an amide functional group, was observed in the IR spectra of irradiated samples, suggesting that cosmic rays may induce peptide bond synthesis in glycine crystals. Combining this finding with the fact that this form has the highest solubility among the other glycine polymorphs, we suggest that beta-glycine is the one most likely to have produced the first peptides on primitive Earth.
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The photochemical haze produced in the upper atmosphere of Titan plays a key role in various atmospheric and surface processes on Titan. The surface energy, one important physical properties of the haze, is crucial for understanding the growth of the haze particles and can be used to predict their wetting behavior with solid and liquid species on Titan. We produced Titan analog haze materials, so-called tholin, with different energy sources and measured their surface energies through contact angle and direct force measurements. From the contact angle measurement, we found that the tholins produced by cold plasma and UV irradiation have total surface energy around 60-70 mJ/m2. The direct force measurement yields a total surface energy of ~66 mJ/m2 for plasma tholin. The surface energy of tholin is relatively high compared to common polymers, indicating its high cohesiveness. Therefore, the Titan haze particles would likely coagulate easily to form bigger particles, while the haze-derived surface sand particles would need higher wind speed to be mobilized because of the high interparticle cohesion. The high surface energy of tholins also makes them easily wettable by Titans atmospheric hydrocarbon condensates and surface liquids. Thus, the hazes particles are likely good cloud condensation nuclei (CCN) for hydrocarbon clouds (methane and ethane) to nucleate and grow. And if the hazes particles are denser compared to the lake liquids, they would likely sink into the lakes instead of forming a floating film to dampen the lake surface waves.
Molecular kinetic simulations are typically used to accurately describe the tenuous regions of the upper atmospheres on planetary bodies. These simulations track the motion of particles representing real atmospheric atoms and/or molecules subject to collisions, the objects gravity, and external influences. Because particles can end up in very large ballistic orbits, upper boundary conditions (UBC) are typically used to limit the domain size thereby reducing the time for the atmosphere to reach steady-state. In the absence of a clear altitude at which all molecules are removed, such as a Hill sphere, an often used condition is to choose an altitude at which collisions become infrequent so that particles on escape trajectories are removed. The remainder are then either specularly reflected back into the simulation domain or their ballistic trajectories are calculated analytically or explicitly tracked so they eventually re-enter the domain. Here we examine the effect of the choice of the UBC on the escape rate and the structure of the atmosphere near the nominal exobase in the convenient and frequently used 1D spherically symmetric approximation. Using Callisto as the example body, we show that the commonly used specular reflection UBC can lead to significant uncertainties when simulating a species with a lifetime comparable to or longer than a dynamical time scale, such as an overestimation of escape rates and an inflated exosphere. Therefore, although specular reflection is convenient, the molecular lifetimes and bodys dynamical time scales need to be considered even when implementing the convenient 1D spherically symmetric simulations in order to accurately estimate the escape rate and the density and temperature structure in the transition regime.
We present a novel mechanism for the outward transport of crystalline dust particles: the outward radial drift of pebbles. The dust ring structure is frequently observed in protoplanetary disks. One of the plausible mechanisms of the formation of dust rings is the accumulation of pebbles around the pressure maximum, which is formed by the mass loss due to magnetically driven disk winds. In evolving protoplanetary disks due to magnetically driven disk winds, dust particles can migrate outwardly from the crystallization front to the pressure maximum by radial drift. We found that the outward radial drift process can transport crystalline dust particles efficiently when the radial drift timescale is shorter than the advection timescale. Our model predicts that the crystallinity of silicate dust particles could be as high as 100% inside the dust ring position.
The timeline of the lunar bombardment in the first Gy of the Solar System remains unclear. Some basin-forming impacts occurred 3.9-3.7Gy ago. Many other basins formed before, but their exact ages are not precisely known. There are two possible interpretations of the data: in the cataclysm scenario there was a surge in the impact rate approximately 3.9Gy ago, while in the accretion tail scenario the lunar bombardment declined since the era of planet formation and the latest basins formed in its tail-end. Here, we revisit the work of Morbidelli et al.(2012) that examined which scenario could be compatible with both the lunar crater record in the 3-4Gy period and the abundance of highly siderophile elements (HSE) in the lunar mantle. We use updated numerical simulations of the fluxes of impactors. Under the traditional assumption that the HSEs track the total amount of material accreted by the Moon since its formation, we conclude that only the cataclysm scenario can explain the data. The cataclysm should have started ~3.95Gy ago. However we show that HSEs could have been sequestered from the lunar mantle due to iron sulfide exsolution during magma ocean crystallization, followed by mantle overturn. Based on the hypothesis that the lunar magma ocean crystallized about 100-150My after Moon formation, and therefore that HSEs accumulated in the lunar mantle only after this time, we show that the bombardment in the 3-4Gy period can be explained in the accretion tail scenario. This hypothesis would also explain why the Moon appears so depleted in HSEs relative to the Earth. We also extend our analysis of the cataclysm and accretion tail scenarios to the case of Mars. The accretion tail scenario requires a global resurfacing event on Mars ~4.4Gy ago, possibly associated with the formation of the Borealis basin, and it is consistent with the HSE budget of the planet.
Double differential cross sections (DDCS) for light charged particles (proton, deuteron, triton, 3He, alpha) and neutrons produced by a proton beam impinging on a 238U target at 62.9 MeV were measured at the CYCLONE facility in Louvain-la-Neuve (Belgium). These measurements have been performed using two independent experimental set-ups ensuring neutron (DeMoN counters) and light charged particles (Si-Si-CsI telescopes) detection. The charged particle data were measured at 11 different angular positions from 25 degrees to 140 degrees allowing the determination of angle differential, energy differential and total production cross sections.
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