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Register a new userPhase Diagram and Calorimetric Properties of NaFe$_{1-x}$Co$_x$As
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We measured the resistivity and magnetic susceptibility to map out the phase diagram of single crystalline NaFe$_{1-x}$Co$_x$As. Replacement of Fe by Co suppresses both the structural and magnetic transition, while enhances the superconducting transition temperature ($T_{rm c}$) and superconducting component fraction. Magnetic susceptibility exhibits temperature-linear dependence in the high temperatures up to 500 K for all the superconducting samples, but such behavior suddenly breaks down for the non-superconducting overdoped crystal, suggesting that the superconductivity is closely related to the T-linear dependence of susceptibility. Analysis on the superconducting-state specific heat for the optimally doped crystal provides strong evidence for a two-band s-wave order parameter with gap amplitudes of $Delta_1(0)/k_{rm B}T_{rm c}$= 1.78 and $Delta_2(0)/k_{rm B}T_{rm c}$=3.11, being consistent with the nodeless gap symmetry revealed by angle-resolved photoemission spectroscopy experiment.
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A series of high quality NaFe$_{1-x}$Cu$_x$As single crystals has been grown by a self-flux technique, which were systematically characterized via structural, transport, thermodynamic, and high pressure measurements. Both the structural and magnetic transitions are suppressed by Cu doping, and bulk superconductivity is induced by Cu doping. Superconducting transition temperature ($T_c$) is initially enhanced from 9.6 to 11.5 K by Cu doping, and then suppressed with further doping. A phase diagram similar to NaFe$_{1-x}$Co$_x$As is obtained except that insulating instead of metallic behavior is observed in extremely overdoped samples. $T_c$s of underdoped, optimally doped, and overdoped samples are all notably enhanced by applying pressure. Although a universal maximum transition temperature ($T_c^{max}$) of about 31 K under external pressure is observed in underdoped and optimally doped NaFe$_{1-x}$Co$_x$As, $T_c^{max}$ of NaFe$_{1-x}$Cu$_x$As is monotonously suppressed by Cu doping, suggesting that impurity potential of Cu is stronger than Co in NaFeAs. The comparison between Cu and Co doping effect in NaFeAs indicates that Cu serves as an effective electron dopant with strong impurity potential, but part of the doped electrons are localized and do not fill the energy bands as predicted by the rigid-band model.
We report electronic transport measurements on single crystals of NaFe$_{1-x}$Co$_x$As system. We found that the cotangent of Hall angle, cot$theta_{rm H}$, follows $T^4$ for the parent compound with filamentary superconductivity and $T^2$ for the heavily-overdoped non-superconducting sample. While it exhibits approximately $T^3$-dependence in all the superconducting samples, suggesting this behaivor is associated with bulk superconductivity in ferropnictides. A deviation develops below a characteristic temperature $T^*$ well above the structural and superconducting transitions, accompanied by a departure from power-law temperature dependence in resistivity. The doping dependence of $T^*$ resembles the crossover line of pseudogap phase in cuprates.
We report a study of the lattice dynamics in superconducting NaFeAs (Tc = 8 K) and doped NaFe0.97Co0.03As (Tc = 20 K) using Raman light scattering. Five of the six phonon modes expected from group theory are observed. In contrast with results obtained on iso-structural and iso-electronic LiFeAs, anomalous broadening of Eg(As) and A1g(Na) modes upon cooling is observed in both samples. In addition, in the Co-doped sample, a superconductivity-induced renormalization of the frequency and linewidth of the B1g(Fe) vibration is observed. This renormalization can not be understood within a single band and simple multi-band approaches. A theoretical model that includes the effects of SDW correlations along with sign-changing s-wave pairing state and interband scattering has been developed to explain the observed behavior of the B1g(Fe) mode.
Systematic measurements of the resistivity, heat capacity, susceptibility and Hall coefficient are presented for single crystal samples of the electron-doped superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$. These data delineate an $x-T$ phase diagram in which the single magnetic/structural phase transition that is observed for undoped BaFe$_2$As$_2$ at 134 K apparently splits into two distinct phase transitions, both of which are rapidly suppressed with increasing Co concentration. Superconductivity emerges for Co concentrations above $x sim 0.025$, and appears to coexist with the broken symmetry state for an appreciable range of doping, up to $x sim 0.06$. The optimal superconducting transition temperature appears to coincide with the Co concentration at which the magnetic/structural phase transitions are totally suppressed, at least within the resolution provided by the finite step size between crystals prepared with different doping levels. Superconductivity is observed for a further range of Co concentrations, before being completely suppressed for $x sim 0.018$ and above. The form of this $x-T$ phase diagram is suggestive of an association between superconductivity and a quantum critical point arising from suppression of the magnetic and/or structural phase transitions.
The thermal conductivity of optimally doped NaFe$_{0.972}$Co$_{0.028}$As ($T_c sim$ 20 K) and overdoped NaFe$_{0.925}$Co$_{0.075}$As ($T_c sim$ 11 K) single crystals were measured down to 50 mK. No residual linear term $kappa_0/T$ is found in zero magnetic field for both compounds, which is an evidence for nodeless superconducting gap. Applying field up to $H$ = 9 T ($approx H_{c2}/4$) does not noticeably increase $kappa_0/T$ in NaFe$_{1.972}$Co$_{0.028}$As, which is consistent with multiple isotropic gaps with similar magnitudes. The $kappa_0/T$ of overdoped NaFe$_{1.925}$Co$_{0.075}$As shows a relatively faster field dependence, indicating the increase of the ratio between the magnitudes of different gaps, or the enhancement of gap anisotropy upon increasing doping.
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