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Register a new userA KInetic Database for Astrochemistry (KIDA)
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We present a novel chemical database for gas-phase astrochemistry. Named the KInetic Database for Astrochemistry (KIDA), this database consists of gas-phase reactions with rate coefficients and uncertainties that will be vetted to the greatest extent possible. Submissions of measured and calculated rate coefficients are welcome, and will be studied by experts before inclusion into the database. Besides providing kinetic information for the interstellar medium, KIDA is planned to contain such data for planetary atmospheres and for circumstellar envelopes. Each year, a subset of the reactions in the database (kida.uva) will be provided as a network for the simulation of the chemistry of dense interstellar clouds with temperatures between 10 K and 300 K. We also provide a code, named Nahoon, to study the time-dependent gas-phase chemistry of 0D and 1D interstellar sources.
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Chemical models used to study the chemical composition of the gas and the ices in the interstellar medium are based on a network of chemical reactions and associated rate coefficients. These reactions and rate coefficients are partially compiled from data in the literature, when available. We present in this paper kida.uva.2014, a new updated version of the kida.uva public gas-phase network first released in 2012. In addition to a description of the many specific updates, we illustrate changes in the predicted abundances of molecules for cold dense cloud conditions as compared with the results of the previous version of our network, kida.uva.2011.
This paper presents a review of ideas that interconnect Astrochemistry and Galactic Dynamics. Since these two areas are vast and not recent, each one has already been covered separately by several reviews. After a general historical introduction, and a needed quick review of processes like the stellar nucleosynthesis which gives the base to understand the interstellar formation of simple chemical compounds (H2, CO, NH3 and H2O), we focus on a number of topics which are at the crossing of the two areas, Dynamics and Astrochemistry. Astrochemistry is a flourishing field which intends to study the presence and formation of molecules as well as the influence of them into the structure, evolution and dynamics of astronomical objects. The progress in the knowledge on the existence of new complex molecules and of their process of formation originates from the observational, experimental and theoretical areas which compose the field. The interfacing areas include star formation, protoplanetary disks, the role of the spiral arms and the chemical abundance gradients in the galactic disk. It often happens that the physical conditions in some regions of the ISM are only revealed by means of molecular observations. To organise a classification of chemical evolution processes, we discuss about how astrochemistry can act in three different contexts: i. the chemistry of the early universe, including external galaxies, ii. star forming regions, and iii. AGB stars and circumstellar envelopes. We mention that our research is stimulated by plans for instruments and projects, such as the on-going LLAMA, which consists in the construction of a 12m sub-mm radio telescope in the Andes. Thus, modern and new facilities can play a key role in new discoveries not only in astrochemistry but also in radio astronomy and related areas. Furthermore, the research of the origin of life is also a stimulating perspective.
Laboratory experiments play a key role in deciphering the chemistry of the interstellar medium (ISM) and the role that product complex organic molecules (COMs) may play in the origins of life. However, to date, most studies in experimental astrochemistry have made use of reductionist approaches to experimental design in which chemical responses to variations in a single parameter are investigated while all other parameters are held constant. Although such work does afford insight into the chemistry of the ISM, it is likely that several important points, such as the relative importance of an experimental parameter in determining the chemical outcome of a reaction and the interaction between parameters, remain ambiguous. In light of this, we propose adopting a new systems astrochemistry framework for experimental studies which draws on current work performed in the field of prebiotic chemistry, and present the basic tenants of such an approach in this article. This systems approach would focus on the emergent properties of the chemical system by performing the simultaneous variation of multiple experimental parameters and would allow for the effect of each parameter, as well as their interactions, to be quantified. We anticipate that the application of systems science to laboratory astrochemistry, coupled with developments in hyphenated analytical techniques and data analytics, will uncover significant new data hitherto unknown, and will aid in better linking laboratory experiments to observations and modelling work.
Astrochemistry aims at studying chemical processes in astronomical environments. This discipline -- located at the crossroad between astrophysics and chemistry -- is rapidly evolving and explores the issue of the formation of molecules of increasing complexity in particular physical conditions that deviate significantly from those frequently encountered in chemistry laboratories. The main goal of this paper is to provide an overview of this discipline. So far, about 170 molecules have been identified in the interstellar medium (ISM). The presence of this molecular diversity constitutes a firm evidence that efficient formation processes are at work in the interstellar medium. This paper aims at summarizing most of present ideas that are explored by astrochemists to investigate the chemistry taking place in various astronomical environments, with emphasis on the particular conditions which are met in space (including radiation fields, cosmic-rays, low densities...). The more ambitious question of the molecular complexity is addressed following two approaches presented to be converging. The first approach considers the growing complexity starting from the most simple chemical species in interstellar environments, and the second approach envisages successive precursors of the most complex species commonly found on Earth, and in particular in our biochemistry. The issue of molecular complexity constitutes one of the main modern scientific questions addressed by astrochemistry, and it is used as a guideline across this paper.
Due to its location and climate, Antarctica offers unique conditions for long-period observations across a broad wavelength regime, where important diagnostic lines for molecules and ions can be found, that are essential to understand the chemical properties of the interstellar medium. In addition to the natural benefits of the site, new technologies, resulting from astrophotonics, may allow miniaturised instruments, that are easier to winterise and advanced filters to further reduce the background in the infrared.
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