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Register a new userCritical holes in undercooled wetting layers
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The profile of a critical hole in an undercooled wetting layer is determined by the saddle-point equation of a standard interface Hamiltonian supported by convenient boundary conditions. It is shown that this saddle-point equation can be mapped onto an autonomous dynamical system in a three-dimensional phase space. The corresponding flux has a polynomial form and in general displays four fixed points, each with different stability properties. On the basis of this picture we derive the thermodynamic behaviour of critical holes in three different nucleation regimes of the phase diagram.
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Recent experimental data for the complete wetting behavior of pure 4He and of 3He-4He mixtures exposed to solid substrates show that there is a change of the corresponding film thicknesses L upon approaching thermodynamically the lambda-transition and the tricritical end point, respectively, which can be attributed to critical Casimir forces f_C. We calculate the scaling functions vartheta of f_C within models representing the corresponding universality classes. For the mixtures our analysis provides an understanding of the rich behavior of vartheta deduced from the experimental data and predicts the crossover behavior between the tricritical point and the lambda-transition of pure 4He which are connected by a line of critical points. The formation of a soft-mode phase within the wetting films gives rise to a pronounced maximum of f_C below the tricritical point as observed experimentally. Near the tricritical point we find logarithmic corrections ~L^(-3)(ln L)^(1/2) for the leading behavior of vartheta dominating the contributions from the background dispersion forces.
An ultralow-temperature binary mixture of Bose-Einstein condensates adsorbed at an optical wall can undergo a wetting phase transition in which one of the species excludes the other from contact with the wall. Interestingly, while hard-wall boundary conditions entail the wetting transition to be of first order, using Gross-Pitaevskii theory we show that first-order wetting as well as critical wetting can occur when a realistic exponential optical wall potential (evanescent wave) with a finite turn-on length $lambda$ is assumed. The relevant surface excess energies are computed in an expansion in $lambda/xi_i$, where $xi_i$ is the healing length of condensate $i$. Experimentally, the wetting transition may best be approached by varying the interspecies scattering length $a_{12}$ using Feshbach resonances. In the hard-wall limit, $lambda rightarrow 0$, exact results are derived for the prewetting and first-order wetting phase boundaries.
The excess adsorption $Gamma $ in two-dimensional Ising strips $(infty times L)$ subject to identical boundary fields, at both one-dimensional surfaces decaying in the orthogonal direction $j$ as $-h_1j^{-p}$, is studied for various values of $p$ and along various thermodynamic paths below the critical point by means of the density-matrix renormalization-group method. The crossover behavior between the complete wetting and critical adsorption regimes, occurring in semi-infinite systems, are strongly influenced by confinement effects. Along isotherms $T=const$ the asymptotic power law dependences on the external bulk field, which characterize these two regimes, are undercut by capillary condensation. Along the pseudo first-order phase coexistence line of the strips, which varies with temperature, we find a broad crossover regime where both the thickness of the wetting film and $Gamma$ increase as function of the reduced temperature $tau$ but do not follow any power law. Above the wetting temperature the order parameter profiles are not slab-like but exhibit wide interfacial variations and pronounced tails. Inter alia, our explicit calculations demonstrate that, contrary to opposite claims by Kroll and Lipowsky [Phys. Rev. B {bf 28}, 5273 (1983)], for $p=2$ critical wetting transitions do exist and we determine the corresponding wetting phase diagram in the $(h_1,T)$ plane.
A simple one-dimensional microscopic model of the depinning transition of an interface from an attractive hard wall is introduced and investigated. Upon varying a control parameter, the critical behaviour observed along the transition line changes from a directed-percolation to a multiplicative-noise type. Numerical simulations allow for a quantitative study of the multicritical point separating the two regions, Mean-field arguments and the mapping on a yet simpler model provide some further insight on the overall scenario.
We study the effect of the composition of the genetic sequence on the melting temperature of double stranded DNA, using some simple analytically solvable models proposed in the framework of the wetting problem. We review previous work on disorder
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