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Ferromagnetic and superconducting instabilities in graphite

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 Added by Yakov Kopelevich
 Publication date 2006
  fields Physics
and research's language is English




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We review our recent work on magnetic properties of graphite and related carbon materials. The results demonstrate that a structural disorder, topological defects, as well as adsorbed foreign atoms can be responsible for the occurrence of both ferromagnetic and superconducting patches in graphitic structures.



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We have identified ferromagnetic- and superconducting-like magnetization hysteresis loops in highly oriented pyrolytic graphite samples below and above room temperature. We also found that both behaviors are very sensitive to low-temperature -- as compared to the sample synthesis temperature -- heat treatment. The possible contribution of magnetic impurities and why these do not appear to be the reason for the observed phenomena is discussed.
Measurements of the basal-plane resistivity rho_a(T,H) performed on highly oriented pyrolitic graphite, with magnetic field H parallel to the c-axis in the temperature interval 2 - 300 K and fields up to 8 T, provide evidence for the occurrence of both field - induced and zero-field superconducting instabilities. Additionally, magnetization M(T,H) measurements suggest the occurrence of Fermi surface instabilities which compete with the superconducting correlations.
The field-reentrant (field-reinforced) superconductivity on ferromagnetic superconductors is one of the most interesting topics in unconventional superconductivity. The enhancement of effective mass and the induced ferromagnetic fluctuations play key roles for reentrant superconductivity. However, the associated change of the Fermi surface, which is often observed at (pseudo-) metamagnetic transition, can also be a key ingredient. In order to study the Fermi surface instability, we performed Hall effect measurements in the ferromagnetic superconductor URhGe. The Hall effect of URhGe is well explained by two contributions, namely by the normal Hall effect and by the large anomalous Hall effect due to skew scattering. The large change in the Hall coefficient is observed at low fields between the paramagnetic and ferromagnetic states for H // c-axis (easy-magnetization axis) in the orthorhombic structure, indicating that the Fermi surface is reconstructed in the ferromagnetic state below the Curie temperature (T_Curie=9.5K). At low temperatures (T << T_Curie), when the field is applied along the b-axis, the reentrant superconductivity was observed in both the Hall resistivity and the magnetoresistance below 0.4K. Above 0.4K, a large jump with the first-order nature was detected in the Hall resistivity at a spin-reorientation field H_R ~ 12.5T, demonstrating that the marked change of the Fermi surface occurs between the ferromagnetic state and the polarized state above H_R. The results can be understood by the Lifshitz-type transition, induced by the magnetic field or by the change of the effective magnetic field.
We introduce a spinful variant of the Sachdev-Ye-Kitaev model with an effective time reversal symmetry, which can be solved exactly in the limit of a large number $N$ of degrees of freedom. At low temperature, its phase diagram includes a compressible non-Fermi liquid and a strongly-correlated spin singlet superconductor that shows a tunable enhancement of the gap ratio predicted by BCS theory. These two phases are separated by a first-order transition, in the vicinity of which a gapless superconducting phase, characterized by a non-zero magnetization, is stabilized upon applying a Zeeman field. We study equilibrium transport properties of such superconductors using a lattice construction, and propose a physical platform based on topological insulator flakes where they may arise from repulsive electronic interactions.
Multiple superconducting order parameters are extremely rare. Here we show that a very small pressure can induce this phenomenon in the recently discovered heavy fermion superconductor UTe2. This nearly ferromagnetic system shows several intriguing phenomena, including an extraordinary reinforcement of superconductivity in very strong magnetic fields. We find that pressure can tune the system to a more correlated state and probable magnetic order. The superconducting critical temperature is strongly enhanced, reaching almost 3K, a new record for Ce- and U-based heavy fermion superconductors. Most spectacularly under pressure we find a transition within the superconducting state, putting UTe2 among the very rare systems having multiple superconducting phases. UTe2 under pressure is a treasure trove of several of the most fascinating phenomena in unconventional superconductivity and may well be a keystone in their understanding.
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