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Register a new userSome New Aspects of Dendrimer Applications
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Dendrimers are characterized by special features that make them promising candidates for many applications. Here we focus on two such applications: dendrimers as light harvesting antennae, and dendrimers as molecular amplifiers, which may serve as novel platforms for drug delivery. Both applications stem from the unique structure of dendrimers. We present a theoretical framework based on the master equation within which we describe these applications. The quantities of interest are the first passage time (FPT) probability density function (PDF), and its moments. We examine how the FPT PDF and its characteristics depend on the geometric and energetic structures of the dendrimeric system. In particular, we investigate the dependence of the FPT properties on the number of generations (dendrimer size), and the system bias. We present analytical expressions for the FPT PDF for very efficient dendrimeric antennae and for dendrimeric amplifiers. For these cases the mean first passage time scales linearly with the system length, and fluctuations around the mean first passage time are negligible for large systems. Relationships of the FPT to light harvesting process for other types of system-bias are discussed.
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The effective pair potentials between different kinds of dendrimers in solution can be well approximated by appropriate Gaussian functions. We find that in binary dendrimer mixtures the range and strength of the effective interactions depend strongly upon the specific dendrimer architecture. We consider two different types of dendrimer mixtures, employing the Gaussian effective pair potentials, to determine the bulk fluid structure and phase behavior. Using a simple mean field density functional theory (DFT) we find good agreement between theory and simulation results for the bulk fluid structure. Depending on the mixture, we find bulk fluid-fluid phase separation (macro-phase separation) or micro-phase separation, i.e., a transition to a state characterized by undamped periodic concentration fluctuations. We also determine the inhomogeneous fluid structure for confinement in spherical cavities. Again, we find good agreement between the DFT and simulation results. For the dendrimer mixture exhibiting micro-phase separation, we observe rather striking pattern formation under confinement.
We briefly review some recent Cold Dark Matter (CDM) models. Our main focus are charge symmetric models of WIMPs which are not the standard SUSY LSPs (Lightest Supersymmetric Partners). We indicate which experiments are most sensitive to certain aspects of the models. In particular we discuss the manifestations of the new models in neutrino telescopes and other set-ups. We also discuss some direct detection experiments and comment on measuring the direction of recoil ions--which is correlated with the direction of the incoming WIMP. This could yield daily variations providing along with the annual modulation signatures for CDM.
Matter collapsing to a singularity in a gravitational field is still an intriguing question. Similar situation arises when discussing the very early universe or a universe recollapsing to a singularity. It is suggested that inclusion of mutual gravitational interactions among the collapsing particles can avert a singularity and give finite value for various physical quantities like entropy, density, etc.
We indicate that Herons formula (which relates the square of the area of a triangle to a quartic function of its edge lengths) can be interpreted as a scissors congruence in 4-dimensional space. In the process of demonstrating this, we examine a number of decompositions of hypercubes, hyper-parallelograms, and other elementary 4-dimensional solids.
Multiparticle production processes provide valuable information about the mechanism of the conversion of the initial energy of projectiles into a number of secondaries by measuring their multiplicity distributions and their distributions in phase space. They therefore serve as a reference point for more involved measurements. Distributions in phase space are usually investigated using the statistical approach, very successful in general but failing in cases of small colliding systems, small multiplicities, and at the edges of the allowed phase space, in which cases the underlying dynamical effects competing with the statistical distributions take over. We discuss an alternative approach, which applies to the whole phase space without detailed knowledge of dynamics. It is based on a modification of the usual statistics by generalizing it to a superstatistical form. We stress particularly the scaling and self-similar properties of such an approach manifesting themselves as the phenomena of the log-periodic oscillations and oscillations of temperature caused by sound waves in hadronic matter. Concerning the multiplicity distributions we discuss in detail the phenomenon of the oscillatory behaviour of the modified combinants apparently observed in experimental data.
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