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Register a new userLarge dielectric constant and giant nonlinear conduction in the organic conductor theta-(BEDT-TTF)_2CsZn(SCN)_4
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The dielectric constant and ac conductivity have been measured for the layered organic conductor theta-(BEDT-TTF)_2CsZn(SCN)_4 along the out-of-plane direction, which show a relaxation behavior similar to those in the charge-density-wave conductor. Most unexpectedly, they exhibit a large bias dependence with a hysteresis, and changes in magnitude by 100-1000 times at a threshold. These findings are very similar to the collective excitation of the charge density wave. theta-$(BEDT-TTF)_2CsZn(SCN)_4 has collective excitations associated with charge ordering, though it shows no clear indication of long range order.
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The low temperature phase (LTP) of alpha-(BEDT-TTF)_2KHg(SCN)_4 salt is known for its surprising angular dependent magnetoresistance (ADMR), which has been studied intensively in the last decade. However, the nature of the LTP has not been understood until now. Here we analyse theoretically ADMR in unconventional (or nodal) charge density wave (UCDW). In magnetic field the quasiparticle spectrum in UCDW is quantized, which gives rise to spectacular ADMR. The present model accounts for many striking features of ADMR data in alpha-(BEDT-TTF)_2KHg(SCN)_4.
The organic charge-transfer salt $kappa$-(BEDT-TTF)$_{2}$Hg(SCN)$_{2}$Br is a quasi two-dimensional metal with a half-filled conduction band at ambient conditions. When cooled below $T=80$ K it undergoes a pronounced transition to an insulating phase where the resistivity increases many orders of magnitude. In order to elucidate the nature of this metal-insulator transition we have performed comprehensive transport, dielectric and optical investigations. The findings are compared with other dimerized $kappa$-(BEDT-TTF) salts, in particular the Cl-analogue, where a charge-order transition takes place at $T_{rm CO}=30$ K.
In spite of extensive experimental studies of the angular dependent magnetoresistance (ADMR) of the low temperature phase (LTP) of alpha-(BEDT-TTF)_2KHg(SCN)_4 about a decade ago, the nature of LTP remains elusive. Here we present a new study of ADMR of LTP in alpha-(ET)_2 salts assuming that LTP is unconventional charge density wave (UCDW). In the presence of magnetic field the quasiparticle spectrum in UCDW is quantized, which gives rise to striking ADMR in UCDW. The present model appears to account for many existing ADMR data of alpha-(BEDT-TTF)_2KHg(SCN)_4 remarkably well.
The ground state of $lambda$-(BEDT-TTF)$_2$GaCl$_4$, which has the same structure as the organic superconductor $lambda$-(BETS)$_2$GaCl$_4$, was investigated by magnetic susceptibility and $^{13}$C NMR measurements. The temperature dependence of the magnetic susceptibility revealed an antiferromagnetic (AF) correlation with $J/k_{rm B} simeq$ 98 K. NMR spectrum splitting and the divergence of $1/T_1$ were observed at approximately 13 K, which is associated with the AF transition. We found that the AF structure is commensurate according to discrete NMR peak splitting, suggesting that the ground state of $lambda$-(BEDT-TTF)$_2$GaCl$_4$ is an AF dimer-Mott insulating state. Our results suggest that the superconducting phase of $lambda$-type salts would be located near the AF insulating phase.
Interlayer magnetoconductance of the quasi-two dimensional organic metal (BEDT-TTF)8Hg4Cl12(C6H5Cl)2 has been investigated in pulsed magnetic fields extending up to 36 T and in the temperature range from 1.6 to 15 K. A complex oscillatory spectrum, built on linear combinations of three basic frequencies only is observed. These basic frequencies arise from the compensated closed hole and electron orbits and from the two orbits located in between. The field and temperature dependencies of the amplitude of the various oscillation series are studied within the framework of the coupled orbits model of Falicov and Stachowiak. This analysis reveals that these series result from the contribution of either conventional Shubnikov-de Haas effect (SdH) or quantum interference (QI), both of them being induced by magnetic breakthrough. Nevertheless, discrepancies between experimental and calculated parameters indicate that these phenomena alone cannot account for all of the data. Due to its low effective mass, one of the QI oscillation series - which corresponds to the whole first Brillouin zone area - is clearly observed up to 13 K.
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