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Register a new userWhat High Pressure Studies Have Taught Us about High-Temperature Superconductivity
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James S. Schilling
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Superconductivity is an important area of modern research which has benefited enormously from experiments under high pressure conditions. The focus of this paper will be on three classes of high-temperature superconductors: (1) the new binary compound MgB2, (2) the alkali-doped fullerenes, and (3) the cuprate oxides. We will discuss results from experiment and theory which illustrate the kinds of vital information the high-pressure variable can give to help better understand these fascinating materials.
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To raise the superconducting-transition temperature (Tc) has been the driving force for the long, sustained effort in superconductivity research. Recent progress in hydrides with Tcs up to 287 K under 267 GPa has heralded a new era of room-temperature superconductivity (RTS) with immense technological promise. Indeed, RTS has lifted the temperature barrier for the ubiquitous application of superconductivity. Unfortunately, formidable pressure is required to attain such high Tcs. The most effective relief to this impasse is to remove the pressure needed while retaining the pressure-induced Tc without pressure. Here we show such a possibility in the pure and doped high-temperature superconductor (HTS) FeSe by retaining, at ambient via pressure-quenching (PQ), its Tc up to 37 K (quadrupling that of a pristine FeSe) and other pressure-induced phases. We have also observed that some phases remain stable without pressure at up to 300 K and for at least 7 days. The observations are in qualitative agreement with our ab initio simulations using the solid-state nudged elastic band (SSNEB) method. We strongly believe that the PQ technique developed here can be adapted to the RTS hydrides and other materials of value with minimal effort.
Due to its low atomic mass hydrogen is the most promising element to search for high-temperature phononic superconductors. However, metallic phases of hydrogen are only expected at extreme pressures (400 GPa or higher). The measurement of a record superconducting critical temperature of 190 K in a hydrogen-sulfur compound at 200 GPa of pressure[1], shows that metallization of hydrogen can be reached at significantly lower pressure by inserting it in the matrix of other elements. In this work we re-investigate the phase diagram and the superconducting properties of the H-S system by means of minima hopping method for structure prediction and Density Functional theory for superconductors. We also show that Se-H has a similar phase diagram as its sulfur counterpart as well as high superconducting critical temperature. We predict SeH3 to exceed 120 K superconductivity at 100 GPa. We show that both SeH3 and SH3, due to the critical temperature and peculiar electronic structure, present rather unusual superconducting properties.
SrxBi2Se3 is recently reported to be a superconductor derived from topological insulator Bi2Se3. It shows a maximum resistive Tc of 3.25 K at ambient pressure. We report magnetic (upto 1 GPa) and transport properties (upro 8 Gpa) under pressure for single crystalline Sr0.1Bi2Se3 superconductor. Magnetic measurements show that Tc decreases from ~2.6 K (0 GPa) to ~1.9 K (0.81 GPa). Similar behavior is observed in transport properties as well without much change in the metallic characteristics in normal state resistivity. No reentrant superconducting phase (Physical Review B 93, 144514 (2016)) is observed at high pressure. Normal state resistivity near Tc is explained by Fermi liquid model. Above 100 K, a polaronic hopping conduction mechanism with two parallel channels for current flow is indicated. Band structure calculations indicate decreasing density of states at Fermi level with pressure. In consonance with transition temperature suppression in conventional BCS low Tc superconductors, the pressure effect in SrxBi2Se3 is well accounted by pressure induced band broadening.
The long-sought goal of room-temperature superconductivity has reportedly recently been realized in a carbonaceous sulfur hydride compound under high pressure, as reported by Snider et al. [1]. The evidence presented in that paper is stronger than in other similar recent reports of high temperature superconductivity in hydrides under high pressure [2-7], and has been received with universal acclaim [8-10]. Here we point out that features of the experimental data shown in Ref. [1] indicate that the phenomenon observed in that material is not superconductivity. This observation calls into question earlier similar claims of high temperature conventional superconductivity in hydrides under high pressure based on similar or weaker evidence [2-7].
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