No Arabic abstract
The Infrared Space Observatory (ISO) has provided the first complete mid-IR spectra for a wide range of objects. Almost all of these spectra are dominated by the well-known infrared emission features at 3.3, 6.2, 7.7, and 11.2 $mu$m, the so-called Unidentified Infra-Red (UIR) features. Besides the major features, there is an array of minor features and broad plateaux stretching from 3 to 20 $mu$m which reveal subtle details of conditions in the emission zones and properties of the carriers. Generally attributed to the vibrational relaxation of UV-pumped Polycyclic Aromatic Hydrocarbon molecules (PAHs) containing some 50--100 C-atoms, these UIR spectra are a treasure trove of information. The ISO spectra have, for the first time, allowed a systematic analysis of the spectral characteristics of the UIR features in a wide variety of environments. The peak positions, profiles, and relative strengths of the major features vary from source to source and spatially within sources. These specific profiles are not unique to certain object types but can occur within each individual source. Here, we review ISO and recent ground-based observations and assess some of their implications.
Comet 21P/Giacobini-Zinner (hereafter, comet 21P/G-Z) is a Jupiter-family comet and a parent comet of the October Draconids meteor shower. If meteoroids originating from a Jupiter-family comet contain complex organic molecules, such as amino acids, they are essential pieces of the puzzle regarding the origin of life on Earth. We observed comet 21P/G-Z in the mid-infrared wavelength region using the Cooled Mid-infrared Camera and Spectrometer (COMICS) on the 8.2 m Subaru Telescope on UT 2005 July 5. Here, we report the unidentified infrared (UIR) emission features of comet 21P/G-Z, which are likely due to complex organic molecules (both aliphatic and aromatic hydrocarbons), and the thermal emission from amorphous/crystalline silicates and amorphous carbon grains in its mid-infrared low-resolution spectrum. The UIR features at ~8.2 micron, ~8.5 micron, and ~11.2 micron found in the spectrum of comet 21P/G-Z could be attributed to polycyclic aromatic hydrocarbons (or hydrogenated amorphous carbons) contaminated by N- or O-atoms, although part of the feature at ~11.2 micron comes from crystalline olivine. The other feature at ~9.2 micron might originate from aliphatic hydrocarbons. Comet 21P/G-Z is enriched in complex organic molecules. Considering that the derived mass fraction of crystalline silicates in comet 21P/G-Z is typical of comets, we propose that the comet originated from a circumplanetary disk of giant planets (similar to Jupiter and Saturn) where was warmer than the typical comet-forming region (5-30 au from the Sun) and was suitable for the formation of complex organic molecules. Comets from circumplanetary disks might be enriched in complex organic molecules, such as comet 21P/G-Z, and may have provided pre-biotic molecules to ancient Earth by direct impact or meteor showers.
Galaxy source counts that simultaneously fit the deep mid-infrared surveys at 24 microns and 15 microns made by the Spitzer Space Telescope and the Infrared Space Observatory (ISO) respectively are presented for two phenomenological models. The models are based on starburst and luminous infrared galaxy dominated populations. Both models produce excellent fits to the counts in both wavebands and provide an explanation for the high redshift population seen in the longer Spitzer 24 micron band supporting the hypothesis that they are luminous-ultraluminous infrared galaxies at z=2-3, being the mid-infrared counterparts to the sub-mm galaxy population. The source counts are characterized by strong evolution to redshift unity, followed by less drastic evolution to higher redshift. The number-redshift distributions in both wavebands are well explained by the effect of the many mid-infrared features passing through the observation windows. The sharp upturn at around a milliJansky in the 15 micron counts in particular depends critically on the distribution of mid-infrared features around 12 microns, in the assumed spectral energy distribution.
The 3.3 $mu$m unidentified infrared emission feature is commonly attributed to C-H stretching band of aromatic molecules. Astronomical observations have shown that this feature is composed of two separate bands at 3.28 and 3.30 $mu$m and the origin of these two bands is unclear. In this paper, we perform vibrational analyses based on quantum mechanical calculations of 153 organic molecules, including both pure aromatic molecules and molecules with mixed aromatic/olefinic/aliphatic hydridizations. We find that many of the C-H stretching vibrational modes in polycyclic aromatic hydrocarbon (PAH) molecules are coupled. Even considering the un-coupled modes only, the correlation between the band intensity ratios and the structure of the PAH molecule is not observed and the 3.28 and 3.30 $mu$m features cannot be directly interpreted in the PAH model. Based on these results, the possible aromatic, olefinic and aliphatic origins of the 3.3 $mu$m feature are discussed. We suggest that the 3.28 $mu$m feature is assigned to aromatic C-H stretch whereas the 3.30 $mu$m feature is olefinic. From the ratio of these two features, the relative olefinic to aromatic content of the carrier can be determined.
We present low resolution near-infrared spectroscopy of an unbiased sample of 24 ultraluminous infrared galaxies (ULIRGs), selected from samples previously observed spectroscopically in the mid-infrared with the Infrared Space Observatory (ISO). Qualitatively, the near-infrared spectra resemble those of starbursts. Only in one ULIRG, IRAS 04114-5117E, do we find spectroscopic evidence for AGN activity. The spectroscopic classification in the near-infrared is in very good agreement with the mid-infrared one. For a subset of our sample for which extinction corrections can be derived from Pa-alpha and Br-gamma, we find rather high Pa-alpha luminosities, in accordance with the powering source of these galaxies being star formation.[Fe] emission is strong in ULIRGs and may be linked to starburst and superwind activity. Additionally, our sample includes two unusual objects. The first, IRAS F00183-7111, exhibits extreme [Fe] emission and the second, IRAS F23578-5307, is according to our knowledge one of the most luminous infrared galaxies in H2 rotation-vibration emission.
To study the nature of Bulge AGB stars and in particular their circumstellar dust, we have analysed mid-infrared spectra obtained with the ISOCAM CVF spectrometer in three Bulge fields. The ISOCAM 5-16.5 micron CVF spectra were obtained as part of the ISOGAL infrared survey of the inner Galaxy. A classification of the shape of the 10 micron dust feature was made for each case. The spectra of the individual sources were modelled using a radiative transfer model. Different combinations of amorphous silicates and aluminium-oxide dust were used in the modelling. Spectra were obtained for 29 sources of which 26 are likely to be Bulge AGB stars. Our modelling shows that the stars suffer mass loss rates in the range of 10^{-8} - 5 x 10^{-7} Msun / yr, which is at the low end of the mass-loss rates experienced on the Thermally Pulsing AGB. The luminosities range from 1,700 to 7,700 Lsun as expected for a population of AGB stars with Minit of 1.5 - 2Msun. In agreement with the condensation sequence scenario, we find that the dust content is dominated by Al_2O_3 grains in this sample of low mass-loss rate stars.