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Register a new userRandom-walk shielding-potential viscosity model for warm dense metals
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The collective effect on the viscosity is essential for warm dense metals. The statistics of random-walk ions and the Debye shielding effect describing the collective properties are introduced in the random-walk shielding-potential viscosity model (RWSP-VM). As a test, the viscosities of several metals (Be, Al, Fe and U) are obtained, which cover from low-Z to high-Z elements. The results indicate that RWSP-VM is a universal accurate and highly efficient model for calculating the viscosity of metals in warm dense state.
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Expanding media are typical in many different fields, e.g. in Biology and Cosmology. In general, a medium expansion (contraction) brings about dramatic changes in the behavior of diffusive transport properties. Here, we focus on such effects when the diffusion process is described by the Continuous Time Random Walk (CTRW) model. For the case where the jump length and the waiting time probability density functions (pdfs) are long-tailed, we derive a general bifractional diffusion equation which reduces to a normal diffusion equation in the appropriate limit. We then study some particular cases of interest, including Levy flights and subdiffusive CTRWs. In the former case, we find an analytical exact solution for the Greens function (propagator). When the expansion is sufficiently fast, the contribution of the diffusive transport becomes irrelevant at long times and the propagator tends to a stationary profile in the comoving reference frame. In contrast, for a contracting medium a competition between the spreading effect of diffusion and the concentrating effect of contraction arises. For a subdiffusive CTRW in an exponentially contracting medium, the latter effect prevails for sufficiently long times, and all the particles are eventually localized at a single point in physical space. This Big Crunch effect stems from inefficient particle spreading due to subdiffusion. We also derive a hierarchy of differential equations for the moments of the transport process described by the subdiffusive CTRW model. In the case of an exponential expansion, exact recurrence relations for the Laplace-transformed moments are obtained. Our results confirm the intuitive expectation that the medium expansion hinders the mixing of diffusive particles occupying separate regions. In the case of Levy flights, we quantify this effect by means of the so-called Levy horizon.
Continuous time random Walk model has been versatile analytical formalism for studying and modeling diffusion processes in heterogeneous structures, such as disordered or porous media. We are studying the continuous limits of Heterogeneous Continuous Time Random Walk model, when a random walk is making jumps on a graph within different time-length. We apply the concept of a generalized master equation to study heterogeneous continuous-time random walks on networks. Depending on the interpretations of the waiting time distributions the generalized master equation gives different forms of continuous equations.
In a simple model of a continuous random walk a particle moves in one dimension with the velocity fluctuating between V and -V. If V is associated with the thermal velocity of a Brownian particle and allowed to be position dependent, the model accounts readily for the particles drift along the temperature gradient and recovers basic results of the conventional thermophoresis theory.
The random walk with hyperbolic probabilities that we are introducing is an example of stochastic diffusion in a one-dimensional heterogeneous media. Although driven by site-dependent one-step transition probabilities, the process retains some of the features of a simple random walk, shows other traits that one would associate with a biased random walk and, at the same time, presents new properties not related with either of them. In particular, we show how the system is not fully ergodic, as not every statistic can be estimated from a single realization of the process. We further give a geometric interpretation for the origin of these irregular transition probabilities.
A physical-mathematical approach to anomalous diffusion may be based on generalized diffusion equations (containing derivatives of fractional order in space or/and time) and related random walk models. The fundamental solution (for the {Cauchy} problem) of the fractional diffusion equations can be interpreted as a probability density evolving in time of a peculiar self-similar stochastic process that we view as a generalized diffusion process. By adopting appropriate finite-difference schemes of solution, we generate models of random walk discrete in space and time suitable for simulating random variables whose spatial probability density evolves in time according to a given fractional diffusion equation.
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