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A Note on Fluctuation Theorems and Thermodynamic Uncertainty Relations

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 Added by Gianluca Francica
 Publication date 2021
  fields Physics
and research's language is English




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Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also applies to non-cyclic and time-reversal non-symmetric protocols.



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79 - Yunxin Zhang 2019
In recent letter [Phys.~Rev.~Lett {bf 123}, 110602 (2019)], Y.~Hasegawa and T.~V.~Vu derived a thermodynamic uncertainty relation. But the bound of their relation is loose. In this comment, through minor changes, an improved bound is obtained. This improved bound is the same as the one obtained in [Phys.~Rev.~Lett {bf 123}, 090604 (2019)] by A.~M.~Timpanaro {it et. al.}, but the derivation here is straightforward.
80 - David H. Wolpert 2019
Recent research has considered the stochastic thermodynamics of multiple interacting systems, representing the overall system as a Bayes net. I derive fluctuation theorems governing the entropy production (EP)of arbitrary sets of the systems in such a Bayes net. I also derive ``conditional fluctuation theorems, governing the distribution of EP in one set of systems conditioned on the EP of a different set of systems. I then derive thermodynamic uncertainty relations relating the EP of the overall system to the precisions of probability currents within the individual systems.
We introduce a new technique to bound the fluctuations exhibited by a physical system, based on the Euclidean geometry of the space of observables. Through a simple unifying argument, we derive a sweeping generalization of so-called Thermodynamic Uncertainty Relations (TURs). We not only strengthen the bounds but extend their realm of applicability and in many cases prove their optimality, without resorting to large deviation theory or information-theoretic techniques. In particular, we find the best TUR based on entropy production alone and also derive a novel bound for stationary Markov processes, which surpasses previous known bounds. Our results derive from the non-invariance of the system under a symmetry which can be other than time reversal and thus open a wide new spectrum of applications.
Irreversibility is usually captured by a comparison between the process that happens and a corresponding reverse process. In the last decades, this comparison has been extensively studied through fluctuation relations. Here we revisit fluctuation relations from the standpoint, suggested decades ago by Watanabe, that the comparison should involve the prediction and the retrodiction on the unique process, rather than two processes. We identify a necessary and sufficient condition for a retrodictive reading of a fluctuation relation. The retrodictive narrative also brings to the fore the possibility of deriving fluctuation relations based on various statistical divergences, and clarifies some of the traditional assumptions as arising from the choice of a reference prior.
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