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Unifying Thermodynamic Uncertainty Relations

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 Added by Gianmaria Falasco
 Publication date 2019
  fields Physics
and research's language is English




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We introduce a new technique to bound the fluctuations exhibited by a physical system, based on the Euclidean geometry of the space of observables. Through a simple unifying argument, we derive a sweeping generalization of so-called Thermodynamic Uncertainty Relations (TURs). We not only strengthen the bounds but extend their realm of applicability and in many cases prove their optimality, without resorting to large deviation theory or information-theoretic techniques. In particular, we find the best TUR based on entropy production alone and also derive a novel bound for stationary Markov processes, which surpasses previous known bounds. Our results derive from the non-invariance of the system under a symmetry which can be other than time reversal and thus open a wide new spectrum of applications.

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Fluctuation theorems are fundamental results in non-equilibrium thermodynamics. Considering the fluctuation theorem with respect to the entropy production and an observable, we derive a new thermodynamic uncertainty relation which also applies to non-cyclic and time-reversal non-symmetric protocols.
79 - Yunxin Zhang 2019
In recent letter [Phys.~Rev.~Lett {bf 123}, 110602 (2019)], Y.~Hasegawa and T.~V.~Vu derived a thermodynamic uncertainty relation. But the bound of their relation is loose. In this comment, through minor changes, an improved bound is obtained. This improved bound is the same as the one obtained in [Phys.~Rev.~Lett {bf 123}, 090604 (2019)] by A.~M.~Timpanaro {it et. al.}, but the derivation here is straightforward.
140 - L. Velazquez , S. Curilef 2009
Recently, we have presented some simple arguments supporting the existence of certain complementarity between thermodynamic quantities of temperature and energy, an idea suggested by Bohr and Heinsenberg in the early days of Quantum Mechanics. Such a complementarity is expressed as the impossibility of perform an exact simultaneous determination of the system energy and temperature by using an experimental procedure based on the thermal equilibrium with other system regarded as a measure apparatus (thermometer). In this work, we provide a simple generalization of this latter approach with the consideration of a thermodynamic situation with several control parameters.
Thermodynamic uncertainty relation (TUR) provides a stricter bound for entropy production (EP) than that of the thermodynamic second law. This stricter bound can be utilized to infer the EP and derive other trade-off relations. Though the validity of the TUR has been verified in various stochastic systems, its application to general Langevin dynamics has not been successful in a unified way, especially for underdamped Langevin dynamics, where odd parity variables in time-reversal operation such as velocity get involved. Previous TURs for underdamped Langevin dynamics is neither experimentally accessible nor reduced to the original form of the overdamped Langevin dynamics in the zero-mass limit. Here, we find an operationally accessible TUR for underdamped Langevin dynamics with an arbitrary time-dependent protocol. We show that the original TUR is a consequence of our underdamped TUR in the zero-mass limit. This indicates that the TUR formulation presented here can be regarded as the universal form of the TUR for general Langevin dynamics. The validity of our result is examined and confirmed for three prototypical underdamped Langevin systems and their zero-mass limits; free diffusion dynamics, charged Brownian particle in a magnetic field, and molecular refrigerator.
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