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Spin-Triplet Superconductivity in K2Cr3As3

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 Added by Guo-Qing Zheng
 Publication date 2021
  fields Physics
and research's language is English




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A spin-triplet superconductor can harbor Majorana bound states that can be used in topological quantum computing. Recently, K2Cr3As3 and its variants with critical temperature Tc as high as 8 K have emerged as a new class of superconductors with ferromagnetic spin fluctuations. Here we report a discovery in K2Cr3As3 single crystal that, the spin susceptibility measured by 75As Knight shift below Tc is unchanged with the magnetic field H0 applied in the ab plane, but vanishes toward zero temperature when H0 is along the c axis, which unambiguously establishes this compound as a spin-triplet superconductor described by a vector order-parameter d parallel to the c axis. Combining with points-nodal gap we show that K2Cr3As3 is a new platform for the study of topological superconductivity and its possible technical application.



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The superconducting state of the newly discovered superconductor K$_2$Cr$_3$As$_3$ with a quasi-one-dimensional crystal structure ($T_{bf c}sim$ 6 K) has been investigated by using magnetization and muon-spin relaxation or rotation ($mu$SR) measurements. Our analysis of the temperature dependence of the superfluid density obtained from the transverse field (TF) $mu$SR measurements fit very well to an isotropic $s$-wave character for the superconducting gap. Furthermore a similarly good fit can also be obtained using a $d$-wave model with line nodes. Our zero-field $mu$SR measurements do reveal very weak evidence of the spontaneous appearance of an internal magnetic field near the transition temperature, which might indicate that the superconducting state is not conventional. This observation suggests that the electrons are paired via unconventional channels such as spin fluctuations, as proposed on the basis of theoretical models of K$_2$Cr$_3$As$_3$. Furthermore, from our TF $mu$SR study the magnetic penetration depth $lambda_L$, superconducting carrier density $n_s$, and effective-mass enhancement $m^*$ have been estimated to be $lambda_L(0)$ = 454(4) nm, $n_s$ = 2.4$times$10$^{27}$ carriers/m$^3$, and $m^*$ = 1.75 $m_e$, respectively.
This review presents a summary and evaluations of the superconducting properties of the layered ruthenate Sr2RuO4 as they are known in the autumn of 2011. This paper appends the main progress that has been made since the preceding review by Mackenzie and Maeno was published in 2003. Here, special focus is placed on the critical evaluation of the spin-triplet, odd-parity pairing scenario applied to Sr2RuO4. After an introduction to superconductors with possible odd-parity pairing, accumulated evidence for the pairing symmetry of Sr2RuO4 is examined. Then, significant recent progress on the theoretical approaches to the superconducting pairing by Coulomb repulsion is reviewed. A section is devoted to some experimental properties of Sr2RuO4 that seem to defy simple explanations in terms of currently available spin-triplet scenario. The next section deals with some new developments using eutectic boundaries and micro-crystals, which reveals novel superconducting phenomena related to chiral edge states, odd-frequency pairing states, and half-fluxoid states. Some of these properties are intimately connected with the properties as a topological superconductor. The article concludes with a summary of knowledge emerged from the study of Sr2RuO4 that are now more widely applied to understand the physics of other unconventional superconductors, as well as with a brief discussion of relatively unexplored but promising areas of ongoing and future studies of Sr2RuO4.
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We report the first measurements of the anisotropic upper critical field $H_{c2}(T)$ for K$_{2}$Cr$_{3}$As$_{3}$ single crystals up to 60 T and $T > 0.6$ K. Our results show that the upper critical field parallel to the Cr chains, $H_{c2}^parallel (T)$, exhibits a paramagnetically-limited behavior, whereas the shape of the $H_{c2}^perp (T)$ curve (perpendicular to the Cr chains) has no evidence of paramagnetic effects. As a result, the curves $H_{c2}^perp (T)$ and $H_{c2}^parallel(T)$ cross at $Tapprox 4$ K, so that the anisotropy parameter $gamma_H(T)=H_{c2}^perp/H_{c2}^parallel (T)$ increases from $gamma_H(T_c)approx 0.35$ near $T_c$ to $gamma_H(0)approx 1.7$ at 0.6 K. This behavior of $H_{c2}^|(T)$ is inconsistent with triplet superconductivity but suggests a form of singlet superconductivity with the electron spins locked onto the direction of Cr chains.
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