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Register a new userOn the magnitude of dissipation in open quantum systems
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If an open quantum system is initially uncorrelated from its environment, then its dynamics can be written in terms of a Lindblad-form master equation. The master equation is divided into a unitary piece, represented by an effective Hamiltonian, and a dissipative piece, represented by a hermiticity-preserving superoperator; however, the division of open system dynamics into unitary and dissipative pieces is non-unique. For finite-dimensional quantum systems, we resolve this non-uniqueness by specifying a norm on the space of dissipative superoperators and defining the canonical Hamiltonian to be the one whose dissipator is minimal. We show that the canonical Hamiltonian thus defined is equivalent to the Hamiltonian initially defined by Lindblad, and that it is uniquely specified by requiring the dissipators jump operators to be traceless. For a system weakly coupled to its environment, we give a recursive formula for computing the canonical effective Hamiltonian to arbitrary orders in perturbation theory, which we can think of as a perturbative scheme for renormalizing the systems bare Hamiltonian.
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Continuing our work on the nature and existence of fluctuation-dissipation relations (FDR) in linear and nonlinear open quantum systems [1-3], here we consider such relations when a linear system is in a nonequilibrium steady state (NESS). With the model of two-oscillators (considered as a short harmonic chain with the two ends) each connected to a thermal bath of different temperatures we find that when the chain is fully relaxed due to interaction with the baths, the relation that connects the noise kernel and the imaginary part of the dissipation kernel of the chain in one bath does not assume the conventional form for the FDR in equilibrium cases. There exists an additional term we call the `bias current that depends on the difference of the baths initial temperatures and the inter-oscillator coupling strength. We further show that this term is related to the steady heat flow between the two baths when the system is in NESS. The ability to know the real-time development of the inter-heat exchange (between the baths and the end-oscillators) and the intra-heat transfer (within the chain) and their dependence on the parameters in the system offers possibilities for quantifiable control and in the design of quantum heat engines or thermal devices.
Irreversibility is a fundamental concept with important implications at many levels. It pinpoints the fundamental difference between the intrinsically reversible microscopic equations of motion and the unidirectional arrow of time that emerges at the macroscopic level. More pragmatically, a full quantification of the degree of irreversibility of a given process can help in the characterisation of the performance of thermo-machines operating at the quantum level. Here, we review the concept of entropy production, which is commonly intended as {it the} measure of thermodynamic irreversibility of a process, pinpointing the features and shortcomings of its current formulation.
The dissipation generated during a quasistatic thermodynamic process can be characterised by introducing a metric on the space of Gibbs states, in such a way that minimally-dissipating protocols correspond to geodesic trajectories. Here, we show how to generalize this approach to open quantum systems by finding the thermodynamic metric associated to a given Lindblad master equation. The obtained metric can be understood as a perturbation over the background geometry of equilibrium Gibbs states, which is induced by the Kubo-Mori-Bogoliubov (KMB) inner product. We illustrate this construction on two paradigmatic examples: an Ising chain and a two-level system interacting with a bosonic bath with different spectral densities.
We investigate the time evolution of an open quantum system described by a Lindblad master equation with dissipation acting only on a part of the degrees of freedom ${cal H}_0$ of the system, and targeting a unique dark state in ${cal H}_0$. We show that, in the Zeno limit of large dissipation, the density matrix of the system traced over the dissipative subspace ${cal H}_0$, evolves according to another Lindblad dynamics, with renormalized effective Hamiltonian and weak effective dissipation. This behavior is explicitly checked in the case of Heisenberg spin chains with one or both boundary spins strongly coupled to a magnetic reservoir. Moreover, the populations of the eigenstates of the renormalized effective Hamiltonian evolve in time according to a classical Markov dynamics. As a direct application of this result, we propose a computationally-efficient exact method to evaluate the nonequilibrium steady state of a general system in the limit of strong dissipation.
We derive a general scheme to obtain quantum fluctuation relations for dynamical observables in open quantum systems. For concreteness we consider Markovian non-unitary dynamics that is unraveled in terms of quantum jump trajectories, and exploit techniques from the theory of large deviations like the tilted ensemble and the Doob transform. Our results here generalise to open quantum systems fluctuation relations previously obtained for classical Markovian systems, and add to the vast literature on fluctuation relations in the quantum domain, but without resorting to the standard two-point measurement scheme. We illustrate our findings with three examples in order to highlight and discuss the main features of our general result.
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