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Register a new userNitrogen-doped graphene based triboelectric nanogenerators
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Harvesting all sources of available clean energy is an essential strategy to contribute to healing current dependence on non-sustainable energy sources. Recently, triboelectric nanogenerators (TENGs) have gained visibility as new mechanical energy harvester offering a valid alternative to batteries, being particularly suitable for portable devices. Here, the increased capacitance of a few-layer graphene-based electrode is obtained by incorporating nitrogen-doped graphene (N_graphene), enabling a 3_fold enhancement in TENGs power output. The dependence of TENGs performance on the electronic properties of different N_graphene types, varying in the doping concentration and in the relative content of N-pyridinic and N-graphitic sites is investigated. These sites have different electron affinities, and synergistically contribute to the variation of the capacitive and resistive properties of N-graphene and consequently, TENG performance. It is demonstrated that the power enhancement of the TENG occurs when the N_graphene, an n-semiconductor, is interfaced between the positive triboelectric material and the electrode, while a deterioration of the electrical performance is observed when it is placed at the interface with the negative triboelectric material. This behavior is explained in terms of the dependence of N_graphene quantum capacitance on the electrode chemical potential which shifts according to the opposite polarization induced at the two electrodes upon triboelectrification.
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We introduce herein the advanced application of low pressure plasma procedures for the development of piezo and triboelectric mode I hybrid nanogenerators. Thus, plasma assisted deposition and functionalization methods are presented as key enabling technologies for the nanoscale design of ZnO polycrystalline shells, the formation of conducting metallic cores in core@shell nanowires, and for the solventless surface modification of polymeric coatings and matrixes. We show how the perfluorinated chains grafting of PDMS provides a reliable approach to increase the hydrophobicity and surface charges at the same time that keeping the PDMS mechanical properties. In this way, we produce efficient Ag/ZnO convoluted piezoelectric nanogenerators supported on flexible substrates and embedded in PDMS compatible with a contact separation triboelectric architecture. Factors like crystal-line texture, ZnO thickness, nanowires aspect ratio, and surface chemical modification of the PDMS are explored to optimize the power output of the nanogenerators aimed for harvesting from low-frequency vibrations. Just by manual trigger-ing, the hybrid device can charge a microcapacitor to switch on an array of color LEDs. Outstandingly, this simple three-layer architecture allows for harvesting vibration energy in a wide bandwidth, thus, we show the performance characteristics for frequencies between 1 Hz to 50 Hz and demonstrate the successful activation of the system up to ca. 800 Hz
Sulfur and nitrogen dual doped graphene have been extensively investigated in the field of oxygen reduction reaction, supercapacitors and batteries, but their magnetic and absorption performance have not been explored. Besides, the effects of doping sequence of sulfur and nitrogen atoms on the morphology, structural property and the corresponding microwave absorption performance of the dual doped graphene remain unexplored. In this work, nitrogen and sulfur dual doped graphene with different doping sequence were successfully prepared using a controllable two steps facile thermal treatment method. The first doping process played a decisive role on the morphology, crystal size, interlayer distance, doping degree and ultimately magnetic and microwave absorption properties of the dual doped graphene samples. Meanwhile, the second doping step affected the doping sites and further had a repairing or damaging effect on the final doped graphene. The dual doped graphene samples exhibited two pronounced absorption peaks which intensity was decided by the order of the doping elements. This nitrogen and sulfur dual doped graphene with controlled doping order provides a strategy for understanding of the interaction between nitrogen and sulfur as dual dopants in graphene and further acquiring microwave absorbing materials with tunable absorption bands by varying the doping sequence.
The thin film configuration presents obvious practical advantages over the 1D implementation in energy harvesting systems such as easily manufacturing and processing and long lasting and stable devices. However, most of the ZnO-based piezoelectric nanogenerators (PENGs) reported so far relay in the exploitation of single-crystalline ZnO nanowires because their self-orientation in the c-axis and ability to accommodate long deformations resulting in a high piezoelectric performance. Herein, we show an innovative approach aiming to produce PENGs by combining polycrystalline ZnO layers fabricated at room temperature by plasma assisted deposition with supported small-molecule organic nanowires (ONWs) acting as 1D scaffold. The resulting hybrid nanostructure is formed by a single-crystalline organic nanowire conformally surrounded by a three dimensional (3D) ZnO shell that combines the mechanical properties of the organic core with the piezoelectric response of the ZnO layer. In a loop forward towards the integration of multiple functions within a single wire, we have also developed ONW@Au@ZnO nanowires including a gold shell acting as inner nanoscopic electrode. Thus, we have built and compare thin films and 3D core@shell ONW@ZnO and ONW@Au@ZnO PENGs showing output piezo-voltages up to 170 mV. The synergistic combination of functionalities in the ONW@Au@ZnO devices promotes an enhanced performance generating piezo-currents almost twenty times larger than the ONW@ZnO nanowires and superior to the thin film nanogenerators for equivalent and higher thicknesses.
Graphene oxide (GO) membranes continue to attract intense interest due to their unique molecular sieving properties combined with fast permeation rates. However, the membranes use has been limited mostly to aqueous solutions because GO membranes appear to be impermeable to organic solvents, a phenomenon not fully understood yet. Here, we report efficient and fast filtration of organic solutions through GO laminates containing smooth two-dimensional (2D) capillaries made from flakes with large sizes of ~ 10-20 micron. Without sacrificing their sieving characteristics, such membranes can be made exceptionally thin, down to ~ 10 nm, which translates into fast permeation of not only water but also organic solvents. We attribute the organic solvent permeation and sieving properties of ultrathin GO laminates to the presence of randomly distributed pinholes that are interconnected by short graphene channels with a width of 1 nm. With increasing the membrane thickness, the organic solvent permeation rates decay exponentially but water continues to permeate fast, in agreement with previous reports. The application potential of our ultrathin laminates for organic-solvent nanofiltration is demonstrated by showing >99.9% rejection of various organic dyes with small molecular weights dissolved in methanol. Our work significantly expands possibilities for the use of GO membranes in purification, filtration and related technologies.
Graphitic nitrogen-doped graphene is an excellent platform to study scattering processes of massless Dirac fermions by charged impurities, in which high mobility can be preserved due to the absence of lattice defects through direct substitution of carbon atoms in the graphene lattice by nitrogen atoms. In this work, we report on electrical and magnetotransport measurements of high-quality graphitic nitrogen-doped graphene. We show that the substitutional nitrogen dopants in graphene introduce atomically sharp scatters for electrons but long-range Coulomb scatters for holes and, thus, graphitic nitrogen-doped graphene exhibits clear electron-hole asymmetry in transport properties. Dominant scattering processes of charge carriers in graphitic nitrogen-doped graphene are analyzed. It is shown that the electron-hole asymmetry originates from a distinct difference in intervalley scattering of electrons and holes. We have also carried out the magnetotransport measurements of graphitic nitrogen-doped graphene at different temperatures and the temperature dependences of intervalley scattering, intravalley scattering and phase coherent scattering rates are extracted and discussed. Our results provide an evidence for the electron-hole asymmetry in the intervalley scattering induced by substitutional nitrogen dopants in graphene and shine a light on versatile and potential applications of graphitic nitrogen-doped graphene in electronic and valleytronic devices.
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