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Register a new userA superior two-dimensional nanoporous graphene membrane for hydrogen separation
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Hydrogen is one of the prime candidates for clean energy source with high energy density. However, current industrial methods of hydrogen production are difficult to provide hydrogen with high purity, thus hard to meet the requirements in many application scenarios. Consequently, the development of large-scale and low-cost hydrogen separation technology is urgently needed. In this work, the gas separation properties of a newly synthesized two-dimensional nanoporous graphene (NPG) membrane material with patterned dumbbell-shape nanopores are investigated. The permeation energy barriers of different gases through this membrane are calculated using the density functional theory (DFT) calculations. Molecular dynamics (MD) simulations are also employed to study the permeation behavior of H2 in binary mixtures with O2, CO2, CO, and CH4. Both the DFT and MD calculation results show that this newly synthesized NPG membrane material can provide a high permeability as well as an ultrahigh selectivity simultaneously, making it a prospective H2 separation membrane with superior performance.
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A series of composites based on (100-x)wt.%Ce0.9Pr0.1O2-{delta}-xwt.%Pr0.6Ca0.4FeO3-{delta} (x = 25, 40 and 50) doped with the cheap and abundant alkaline earth metal Ca2+ at the A-site has been successfully designed and fabricated. The crystal structure, oxygen permeability, phase and CO2 stability were evaluated. The composition of 60wt.%Ce0.9Pr0.1O2-{delta}-40wt.%Pr0.6Ca0.4FeO3-{delta}(60CPO-40PCFO) possesses the highest oxygen permeability among three studied composites. At 1000 oC, the oxygen permeation fluxes through the 0.3 mm-thickness 60CPO-40PCFO membranes after porous La0.6Sr0.4CoO3-{delta} each to 1.00 mL cm-2 min-1 and 0.62 mL cm-2 min-1 under air/He and air/CO2 gradients, respectively. In situ XRD results demonstrated that the 60CPO-40PCFO sample displayed a perfect structural stability in air as well as CO2-containing atmosphere. Thus, low-cost, Co-free and Sr-free 60CPO-40PCFO has high CO2 stability and is economical and environmental friendly since the expensive and volatile element Co was replaced by Fe and Sr was waived since it easily forms carbonates.
We synthesized three-dimensional nanoporous graphene films by a chemical vapor deposition method with nanoporous copper as a catalytic substrate. The resulting nanoporous graphene has the same average pore size as the underlying copper substrate. Our surface-enhanced Raman scattering (SERS) investigation indicates that the nanoporosity of graphene significantly improves the SERS efficiency of graphene as a substrate as compared to planar graphene substrates.
The high flexibility, impermeability and strength of graphene membranes are key properties that can enable the next generation of nanomechanical sensors. However, for capacitive pressure sensors the sensitivity offered by a single suspended graphene membrane is too small to compete with commercial sensors. Here, we realize highly sensitive capacitive pressure sensors consisting of arrays of nearly ten thousand small, freestanding double-layer graphene membranes. We fabricate large arrays of small diameter membranes using a procedure that maintains the superior material and mechanical properties of graphene, even after high-temperature anneals. These sensors are readout using a low cost battery-powered circuit board, with a responsivity of up to 47.8 aF Pa$^{-1}$ mm$^{-2}$, thereby outperforming commercial sensors.
Two dimensional (2D) materials exhibit superior properties in electronic and optoelectronic fields. The wide demand for high performance optoelectronic devices promotes the exploration of diversified 2D materials. Recently, 2D covalent organic frameworks (COFs) have emerged as next-generation layered materials with predesigned pi electronic skeletons and highly ordered topological structures, which are promising for tailoring their optoelectronic properties. However, COFs are usually produced as solid powders due to anisotropic growth, making them unreliable to integrate into devices. Here, by selecting tetraphenylethylene (TPE) monomers with photoelectric activity, we designed and synthesized photosensitive 2D COFs with highly ordered topologies and grew 2D COFs in situ on graphene to form well ordered COF graphene heterostructures. Ultrasensitive photodetectors were successfully fabricated with the COFETBC TAPT graphene heterostructure and exhibited an excellent overall performance. Moreover, due to the high surface area and the polarity selectivity of COFs, the photosensing properties of the photodetectors can be reversibly regulated by specific target molecules. Our research provides new strategies for building advanced functional devices with programmable material structures and diversified regulation methods, paving the way for a generation of high performance applications in optoelectronics and many other fields.
Graphene oxide (GO) membranes continue to attract intense interest due to their unique molecular sieving properties combined with fast permeation rates. However, the membranes use has been limited mostly to aqueous solutions because GO membranes appear to be impermeable to organic solvents, a phenomenon not fully understood yet. Here, we report efficient and fast filtration of organic solutions through GO laminates containing smooth two-dimensional (2D) capillaries made from flakes with large sizes of ~ 10-20 micron. Without sacrificing their sieving characteristics, such membranes can be made exceptionally thin, down to ~ 10 nm, which translates into fast permeation of not only water but also organic solvents. We attribute the organic solvent permeation and sieving properties of ultrathin GO laminates to the presence of randomly distributed pinholes that are interconnected by short graphene channels with a width of 1 nm. With increasing the membrane thickness, the organic solvent permeation rates decay exponentially but water continues to permeate fast, in agreement with previous reports. The application potential of our ultrathin laminates for organic-solvent nanofiltration is demonstrated by showing >99.9% rejection of various organic dyes with small molecular weights dissolved in methanol. Our work significantly expands possibilities for the use of GO membranes in purification, filtration and related technologies.
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