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Register a new userPossible detection of interstellar glycine in the hot molecular core G10.47+0.03
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Amino acids are the essential keys in chemistry that contribute to the study of the formation of life. The complex organic molecule glycine (NH$_{2}$CH$_{2}$COOH) is the simplest amino acid that has been investigated in the interstellar medium for a long period to search for a potential connection between the Universe and the origin of life. In the last forty years, several attempts have failed to detect the interstellar glycine in the hot molecular cores and star-forming regions. We report the possible detection of the rotational emission lines of interstellar glycine with conformer I and II in the hot molecular core G10.47+0.03 between the frequency range of $ u$ = 158.6$-$160.4 GHz with Atacama Large Millimeter/Submillimeter Array (ALMA) observation. Under the Local Thermodynamic Equilibrium (LTE) condition, we apply the rotational diagram method to estimate the column density ($N$) and rotational temperature ($T_{rot}$) of the detected amino acid glycine. Using rotational diagram, we find the column density of glycine $N$(NH$_{2}$CH$_{2}$COOH) = 2.8$times$10$^{18}$ cm$^{-2}$ with rotational temperature $T_{rot}$ = 115.9 K. We also apply the Levenberg$-$Marquardt algorithm to extract the line parameters of detected emission lines of glycine.
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After hydrogen, oxygen, and carbon, nitrogen is one of the most chemically active species in the interstellar medium (ISM). Nitrogen bearing molecules have great importance as they are actively involved in the formation of biomolecules. Therefore, it is essential to look for nitrogen-bearing species in various astrophysical sources, specifically around high-mass star-forming regions where the evolutionary history is comparatively poorly understood. In this paper, we report the observation of three potential pre-biotic molecules, namely, isocyanic acid (HNCO), formamide (NH2CHO), and methyl isocyanate (CH3NCO), which contain peptide-like bonds (-NH-C(=O)-) in a hot molecular core, G10.47+0.03 (hereafter, G10). Along with the identification of these three complex nitrogen-bearing species, we speculate their spatial distribution in the source and discuss their possible formation pathways under such conditions. The rotational diagram method under the LTE condition has been employed to estimate the excitation temperature and the column density of the observed species. Markov Chain Monte Carlo method was used to obtain the best suited physical parameters of G10 as well as line properties of some species. We also determined the hydrogen column density and the optical depth for different continuum observed in various frequency ranges. Finally, based on these observational results, we have constructed a chemical model to explain the observational findings. We found that HNCO, NH2CHO, and CH3NCO are chemically linked with each other.
We present the first detection of interstellar acetone [(CH3)2CO] toward the high mass star forming region Orion-KL and the first detection of vibrationally excited (CH3)2CO in the ISM. Using the BIMA Array, 28 emission features that can be assigned to 54 acetone transitions were detected. Furthermore, 37 of these transitions have not been previously observed in the ISM. The observations also show that the acetone emission is concentrated toward the hot core region of Orion-KL, contrary to the distribution of other large oxygen bearing molecules. From our rotational-temperature diagram we find a beam averaged (CH3)2CO column density of (2.0(0.3)-8.0(1.2))x10^16 cm^-2 and a rotational temperature of 176(48)-194(66) K.
Using APEX-1 and APEX-2 observations, we have detected and studied the rotational lines of the HC$_3$N molecule (cyanoacetylene) in the powerful outflow/hot molecular core G331.512-0.103. We identified thirty-one rotational lines at $J$ levels between 24 and 39; seventeen of them in the ground vibrational state $v$=0 (9 lines corresponding to the main C isotopologue and 8 lines corresponding to the $^{13}$C isotopologues), and fourteen in the lowest vibrationally excited state $v_7$=1. Using LTE-based population diagrams for the beam-diluted $v$=0 transitions, we determined $T_{rm exc}$=85$pm$4 K and $N$(HC$_3$N)=(6.9$pm$0.8)$times$10$^{14}$ cm$^{-2}$, while for the beam-diluted $v_7$=1 transitions we obtained $T_{rm exc}$=89$pm$10 K and $N$(HC$_3$N)=2$pm$1$times$10$^{15}$ cm$^{-2}$. Non-LTE calculations using H$_2$ collision rates indicate that the HC$_3$N emission is in good agreement with LTE-based results. From the non-LTE method we estimated $T_{rm kin}$ $simeq$90~K, $n$(H$_2$)$simeq$2$times$10$^7$~cm$^{-3}$ for a central core of 6 arcsec in size. A vibrational temperature in the range from 130~K to 145~K was also determined, values which are very likely lower limits. Our results suggest that rotational transitions are thermalized, while IR radiative pumping processes are probably more efficient than collisions in exciting the molecule to the vibrationally excited state $v_7$=1. Abundance ratios derived under LTE conditions for the $^{13}$C isotopologues suggest that the main formation pathway of HC$_3$N is ${rm C}_2{rm H}_2 + {rm CN} rightarrow {rm HC}_3{rm N} + {rm H}$.
We present Submillimeter Array (SMA) observations toward the high-mass star-forming region IRAS 18566+0408. Observations at 1.3 mm continuum and in several molecular line transitions were performed in the compact (2.4 angular resolution) and very-extended (~0.4 angular resolution) configurations. The continuum emission from the compact configuration shows a dust core of 150 Msun, while the very-extended configuration reveals a dense (2.6 x 10^7 cm^-3) and compact (~4,000 AU) condensation of 8 Msun. We detect 31 molecular transitions from 14 species including CO isotopologues, SO, CH3OH, OCS, and CH3CN. Using the different k-ladders of the CH3CN line, we derive a rotational temperature at the location of the continuum peak of 240 K. The 12CO(2-1), 13CO(2-1), and SO(6_5-5_4) lines reveal a molecular outflow at PA ~135^o centered at the continuum peak. The extended 12CO(2-1) emission has been recovered with the IRAM 30 m telescope observations. Using the combined data set, we derive an outflow mass of 16.8 Msun. The chemically rich spectrum and the high rotational temperature confirm that IRAS 18566+0408 is harboring a hot molecular core. We find no clear velocity gradient that could suggest the presence of a rotational disk-like structure, even at the high resolution observations obtained with the very-extended configuration.
Methyl carbamate CH$_3$OC(O)NH$_2$ is an isomer of glycine. Quantum chemical analyses show that methyl carbamate is more stable isomer than glycine. Because of this, there could be a higher chance for methyl carbamte to exist in the interstellar medium as compared to glycine. Despite immense searches, till now glycine has not been detected in the ISM, therefore it is worthwhile to search its isomer methyl carbamate. In this paper, we present the constraints of methyl carbamate formation under the interstellar conditions. Large complex organic molecules are favorably produced in hot-corino environments of low mass protostars. We for the first time carried out astrochemical modeling focusing on the formation of methyl carbamate in physical conditions similar to hot-corino objects. Consequently, we examined ALMA archival data for existing spectral line observations toward hot corinos NGC1333 IRAS 4A2 and IRAS 16293B. Within the common spectral range towards these sources, we found three features are possibly related to the spectral transitions of methyl carbamate and consequently estimate the upper limit of column densities. Results of chemical modeling are consistent with the observational upper limit of estimated column density/abundance toward the sources. This may hint the validation of the proposed formation mechanism. Future observations using telescope like ngVLA may confirm the presence of MC toward the hot corinos.
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