Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userEffect of binding energies on the encounter desorption
81
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
The abundance of interstellar ice constituents is usually expressed with respect to the water ice because, in denser regions, a significant portion of the interstellar grain surface would be covered by water ice. The binding energy (BE), or adsorption energy of the interstellar species regulates the chemical complexity of the interstellar grain mantle. Due to the high abundance of water ice, the BE of surface species with the water is usually provided and widely used in astrochemical modeling. However, the hydrogen molecules would cover some part of the grain mantle in the denser and colder part of the interstellar medium. Even at around ~ 10K, few atoms and simple molecules with lower adsorption energies can migrate through the surface. The BE of the surface species with H2 substrate would be very different from that of a water substrate. However, adequate information regarding these differences is lacking. Here, we employ the quantum chemical calculation to provide the BE of 95 interstellar species with H2 substrate. These are representative of the BEs of species to a H2 overlayer on a grain surface. On average, we notice that the BE with the H2 monomer substrate is almost ten times lower than the BE of these species reported earlier with the H2 O c-tetramer configuration. The encounter desorption of H and H2 was introduced (with ED (H, H2 ) =45 K and ED (H2 , H2 ) =23 K) to have a realistic estimation of the abundances of the surface species in the colder and denser region. Our quantum chemical calculations yield higher adsorption energy of H2 than that of H (ED (H, H2 ) = 23 - 25 K and ED (H2, H2 ) =67 - 79 K). We further implement an astrochemical model to study the effect of encounter desorption with the resent realistic estimation. The encounter desorption of the N atom (calculations yield ED (N, H2 ) =83 K) is introduced to study the differences with its inclusion.
rate research
Read More
Recent laboratory measurements have confirmed that chemical desorption (desorption of products due to exothermic surface reactions) can be an efficient process. The impact of including this process into gas-grain chemical models entirely depends on the formalism used and the associated parameters. Among these parameters, binding energies are probably the most uncertain ones for the moment. We propose a new model to compute binding energy of species to water ice surfaces. We have also compared the model results using either the new chemical desorption model proposed by Minissale et al. (2016) or the one of Garrod et al. (2007). The new binding energies have a strong impact on the formation of complex organic molecules. In addition, the new chemical desorption model from Minissale produces a much smaller desorption of these species and also of methanol. Combining the two effects, the abundances of CH3OH and COMs observed in cold cores cannot be reproduced by astrochemical models anymore.
Nuclear deformation effects on the binding energies in heavy ions are investigated. Approximate formulas for the nuclear-size correction and the isotope shift for deformed nuclei are derived. Combined with direct numerical evaluations, these formulas are employed to reanalyse experimental data on the nuclear-charge-distribution parameters in $^{238}textrm{U}$ and to revise the nuclear-size corrections to the binding energies in H- and Li-like $^{238}textrm{U}$. As a result, the theoretical uncertainties for the ground-state Lamb shift in $^{238}textrm{U}^{91+}$ and for the $2p_{1/2}-2s$ transition energy in $^{238}textrm{U}^{89+}$ are significantly reduced. The isotope shift of the $2p_{j}-2s$ transition energies for $^{142}textrm{Nd}^{57+}$ and $^{150}textrm{Nd}^{57+}$ is also evaluated including nuclear size and nuclear recoil effects within a full QED treatment.
In this study we demonstrate that stellar masses of galaxies (Mstar) are universally correlated through a double power law function with the product of the dynamical velocities (Ve) and sizes to one-fourth power (Re^0.25) of galaxies, both measured at the effective radii. The product VeRe^0.25 represents the fourth root of the total binding energies within effective radii of galaxies. This stellar mass-binding energy correlation has an observed scatter of 0.14 dex in log(VeRe^0.25) and 0.46 dex in log(Mstar). It holds for a variety of galaxy types over a stellar mass range of nine orders of magnitude, with little evolution over cosmic time. A toy model of self-regulation between binding energies and supernovae feedback is shown to be able to reproduce the observed slopes, but the underlying physical mechanisms are still unclear. The correlation can be a potential distance estimator with an uncertainty of 0.2 dex independent of the galaxy type.
The most precise to-date evaluation of the nuclear recoil effect on the $n=1$ and $n=2$ energy levels of He-like ions is presented in the range $Z=12-100$. The one-electron recoil contribution is calculated within the framework of the rigorous QED approach to first order in the electron-to-nucleus mass ratio $m/M$ and to all orders in the parameter $alpha Z$. The two-electron $m/M$ recoil term is calculated employing the $1/Z$ perturbation theory. The recoil contribution of the zeroth order in $1/Z$ is evaluated to all orders in $alpha Z$, while the $1/Z$ term is calculated using the Breit approximation. The recoil corrections of the second and higher orders in $1/Z$ are taken into account within the nonrelativistic approach. The obtained results are compared with the previous evaluation of this effect [A. N. Artemyev et al., Phys. Rev. A 71, 062104 (2005)].
Physisorbed atoms on the surface of interstellar dust grains play a central role in solid state astrochemistry. Their surface reactivity is one source of the observed molecular complexity in space. In experimental astrophysics, the high reactivity of atoms also constitutes an obstacle to measuring two of the fundamental properties in surface physics, namely desorption and diffusion energies, and so far direct measurements are non-existent for O and N atoms. We investigated the diffusion and desorption processes of O and N atoms on cold surfaces in order to give boundary conditions to astrochemical models. Here we propose a new technique for directly measuring the N- and O-atom mass signals. Including the experimental results in a simple model allows us to almost directly derive the desorption and diffusion barriers of N atoms on amorphous solid water ice (ASW) and O atoms on ASW and oxidized graphite. We find a strong constraint on the values of desorption and thermal diffusion energy barriers. The measured barriers for O atoms are consistent with recent independent estimations and prove to be much higher than previously believed (E$_{des}=1410_{-160}^{+290}$; E$_{dif}=990_{-360}^{+530}$ K on ASW). As for oxygen atoms, we propose that the combination E$_{des}$-E$_{dif}$=1320-750 K is a sensible choice among the possible pairs of solutions. Also, we managed to measure the desorption and diffusion energy of N atoms for the first time (E$_{des}=720_{-80}^{+160}$; E$_{dif}=525_{-200}^{+260}$ K on ASW) in the thermal hopping regime and propose that the combination E$_{des}$-E$_{dif}$=720-400 K can be reasonably adopted in models. The value of E$_{dif}$ for N atoms is slightly lower than previously suggested, which implies that the N chemistry on dust grains might be richer.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
