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Register a new userIsocyanic acid (HNCO) in the Hot Molecular Core G331.512-0.103: Observations and Chemical Modelling
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Carla Martinez Canelo
Publication date
2021
fields
Physics
and research's language is
English
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Isocyanic acid (HNCO) is a simple molecule with a potential to form prebiotic and complex organic species. Using a spectral survey collected with the Atacama Pathfinder EXperiment (APEX), in this work we report the detection of 42 transitions of HNCO in the hot molecular core/outflow G331.512-0.103 (hereafter G331). The spectral lines were observed in the frequency interval $sim$ 160 - 355 GHz. By means of Local Thermodynamic Equilibrium (LTE) analyses, applying the rotational diagram method, we studied the excitation conditions of HNCO. The excitation temperature and column density are estimated to be $T_{ex}$ = 58.8 $pm$ 2.7 K and $N$ = (3.7 $pm$ 0.5) $times$ 10$^{15}$ cm$^{-2}$, considering beam dilution effects. The derived relative abundance is between (3.8 $pm$ 0.5) $times $10$^{-9}$ and (1.4 $pm$ 0.2) $times $10$^{-8}$. In comparison with other hot molecular cores, our column densities and abundances are in agreement. An update of the internal partition functions of the four CHNO isomers: HNCO; cyanic acid, HOCN; fulminic acid, HCNO; and isofulminic acid, HONC is provided. We also used the astrochemical code Nautilus to model and discuss HNCO abundances. The simulations could reproduce the abundances with a simple zero-dimensional model at a temperature of 60 K and for a chemical age of $sim$ 10$^5$ years, which is larger than the estimated dynamical age for G331. This result could suggest the need for a more robust model and even the revision of chemical reactions associated with HNCO.
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Using APEX-1 and APEX-2 observations, we have detected and studied the rotational lines of the HC$_3$N molecule (cyanoacetylene) in the powerful outflow/hot molecular core G331.512-0.103. We identified thirty-one rotational lines at $J$ levels between 24 and 39; seventeen of them in the ground vibrational state $v$=0 (9 lines corresponding to the main C isotopologue and 8 lines corresponding to the $^{13}$C isotopologues), and fourteen in the lowest vibrationally excited state $v_7$=1. Using LTE-based population diagrams for the beam-diluted $v$=0 transitions, we determined $T_{rm exc}$=85$pm$4 K and $N$(HC$_3$N)=(6.9$pm$0.8)$times$10$^{14}$ cm$^{-2}$, while for the beam-diluted $v_7$=1 transitions we obtained $T_{rm exc}$=89$pm$10 K and $N$(HC$_3$N)=2$pm$1$times$10$^{15}$ cm$^{-2}$. Non-LTE calculations using H$_2$ collision rates indicate that the HC$_3$N emission is in good agreement with LTE-based results. From the non-LTE method we estimated $T_{rm kin}$ $simeq$90~K, $n$(H$_2$)$simeq$2$times$10$^7$~cm$^{-3}$ for a central core of 6 arcsec in size. A vibrational temperature in the range from 130~K to 145~K was also determined, values which are very likely lower limits. Our results suggest that rotational transitions are thermalized, while IR radiative pumping processes are probably more efficient than collisions in exciting the molecule to the vibrationally excited state $v_7$=1. Abundance ratios derived under LTE conditions for the $^{13}$C isotopologues suggest that the main formation pathway of HC$_3$N is ${rm C}_2{rm H}_2 + {rm CN} rightarrow {rm HC}_3{rm N} + {rm H}$.
We present observations and analysis of the massive molecular outflow G331.512-0.103, obtained with ALMA band 7, continuing the work from Merello et al. (2013). Several lines were identified in the observed bandwidth, consisting of two groups: lines with narrow profiles, tracing the emission from the core ambient medium; and lines with broad velocity wings, tracing the outflow and shocked gas emission. The physical and chemical conditions, such as density, temperature, and fractional abundances are calculated. The ambient medium, or core, has a mean density of $sim 5times 10^6$ cm$^{-3}$ and a temperature of $sim 70$ K. The SiO and SO$_2$ emission trace the very dense and hot part of the shocked outflow, with values of $n_{rm H_2}sim10^9$ cm$^{-3}$ and $T sim 160-200$ K. The interpretation of the molecular emission suggests an expanding cavity geometry powered by stellar winds from a new-born UCHII region, alongside a massive and high-velocity molecular outflow. This scenario, along with the estimated physical conditions, is modeled using the 3D geometry radiative transfer code MOLLIE for the SiO(J$=8-7$) molecular line. The main features of the outflow and the expanding shell are reproduced by the model.
Isocyanic acid (HNCO), the most stable of the simplest molecules containing the four main elements essential for organic chemistry, has been observed in several astrophysical environments such as molecular clouds, star-forming regions, external galaxies and comets. In this work, we model HNCO spectral line profiles toward the low-mass solar type protostar IRAS 16293$-2$422 observed with the ALMA interferometer, the IRAM, JCMT and APEX single-dish radio telescopes, and the HIFI instrument on board the Herschel Space Observatory. In star-forming environments, the HNCO emission is not always in Local Thermodynamical Equilibrium (LTE). A non-LTE radiative transfer approach is necessary to properly interpret the line profiles, and accurate collisional rate coefficients are needed. Here, we used the RADEX package with a completely new set of collisional quenching rates between HNCO and both ortho-H$_2$ and para-H$_2$ obtained from quantum chemical calculations yielding a novel potential energy surface in the rigid rotor approximation. We find that the lines profiles toward IRAS 16293$-$2422 are very well reproduced if we assume that the HNCO emission arises from a compact, dense and hot physical component associated with the hot corino, a warm component associated with the internal part of the protostellar envelope, and a cold and more extended component associated with the outer envelope. The derived HNCO abundances from our model agree well with those computed with the Nautilus chemical code.
We present Submillimeter Array (SMA) observations toward the high-mass star-forming region IRAS 18566+0408. Observations at 1.3 mm continuum and in several molecular line transitions were performed in the compact (2.4 angular resolution) and very-extended (~0.4 angular resolution) configurations. The continuum emission from the compact configuration shows a dust core of 150 Msun, while the very-extended configuration reveals a dense (2.6 x 10^7 cm^-3) and compact (~4,000 AU) condensation of 8 Msun. We detect 31 molecular transitions from 14 species including CO isotopologues, SO, CH3OH, OCS, and CH3CN. Using the different k-ladders of the CH3CN line, we derive a rotational temperature at the location of the continuum peak of 240 K. The 12CO(2-1), 13CO(2-1), and SO(6_5-5_4) lines reveal a molecular outflow at PA ~135^o centered at the continuum peak. The extended 12CO(2-1) emission has been recovered with the IRAM 30 m telescope observations. Using the combined data set, we derive an outflow mass of 16.8 Msun. The chemically rich spectrum and the high rotational temperature confirm that IRAS 18566+0408 is harboring a hot molecular core. We find no clear velocity gradient that could suggest the presence of a rotational disk-like structure, even at the high resolution observations obtained with the very-extended configuration.
Spectral line surveys reveal rich molecular reservoirs in G331.512-0.103, a compact radio source in the center of an energetic molecular outflow. In this first work, we analyse the physical conditions of the source by means of CH$_3$OH and CH$_3$CN. The observations were performed with the APEX telescope. Six different system configurations were defined to cover most of the band within (292-356) GHz; as a consequence we detected a forest of lines towards the central core. A total of 70 lines of $A/E$-CH$_3$OH and $A/E$-CH$_3$CN were analysed, including torsionally excited transitions of CH$_3$OH ($ u_t$=1). In a search for all the isotopologues, we identified transitions of $^{13}$CH$_3$OH. The physical conditions were derived considering collisional and radiative processes. We found common temperatures for each $A$ and $E$ symmetry of CH$_3$OH and CH$_3$CN; the derived column densities indicate an $A/E$ equilibrated ratio for both tracers. The results reveal that CH$_3$CN and CH$_3$OH trace a hot and cold component with $T_k sim$ 141 K and $T_k sim$ 74 K, respectively. In agreement with previous ALMA observations, the models show that the emission region is compact ($lesssim$ 5.5 arcsec) with gas density $n$(H$_2$)=(0.7-1) $times$ 10$^7$ cm$^{-3}$. The CH$_3$OH/CH$_3$CN abundance ratio and the evidences for pre-biotic and complex organic molecules suggest a rich and active chemistry towards G331.512-0.103.
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