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Register a new userComments on diffraction experiments at high-field on uranium dioxide in the ordered state
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D. J. Antonio et al. report an x-ray diffraction experiment on uranium dioxide at high-magnetic field and low temperature. The authors have apparently not realized that the diffraction data actually shows unambiguously the presence of a rhombohedral distortion induced by the field at low temperature and the presence of more than one domain. Our note correctly analyses their data. The crystallographic analysis we perform is based on simple arguments with respect to plane spacings in slightly distorted cubic materials. Similar studies have been reported in many materials over the last 50 years. Our analysis explains quantitatively the observations, the presence of the two peaks (the appearance of which the authors regard as unexpected) and their different variations with respect to the applied field, which is a simple consequence of the conservation of atomic volume.
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We have investigated the grain boundary scattering effect on the thermal transport behavior of uranium dioxide (UO$_2$). The polycrystalline samples having different grain-sizes (0.125, 1.8, and 7.2 $mu$m) have been prepared by spark plasma sintering technique and characterized by x-ray powder diffraction (XRD), scanning electron microscope (SEM), and Raman spectroscopy. The thermal transport properties (the thermal conductivity and thermoelectric power) have been measured in the temperature range 2-300~K and the results were analyzed in terms of various physical parameters contributing to the thermal conductivity in these materials in relation to grain-size. We show that thermal conductivity decreases systematically with lowering grain-size in the temperatures below 30 K, where the boundary scattering dominates the thermal transport. At higher temperatures more scattering processes are involved in the heat transport in these materials, making the analysis difficult. We determined the grain boundary Kapitza resistance that would result in the observed increase in thermal conductivity with grain size, and compared the value with Kapitza resistances calculated for UO$_2$ using molecular dynamics from the literature.
Uranium mononitride, UN, is considered a potential accident tolerant fuel due to its high uranium density, high thermal conductivity, and high melting point. Compared with the relatively inert UO2, UN has a high reactivity in water, however, studies have not considered the significant effect of radiation, which is known to cause corrosion of UO2. This study uses 0.1 M H2O2 to simulate the effects of water radiolysis in order to compare the radiolytic corrosion rates of UO2, UN, and U2N3 thin films at room temperature. X-ray reflectivity was used to investigate the changes in film morphology as a function of H2O2 exposure time, allowing changes in film thickness and roughness to be observed on the Angstrom length-scale. Results showed significant differences between UO2, UN, and U2N3, with corrosion rates of 0.083(3), 0.020(4), and 0.47(8) A/s, respectively, showing that UN corrodes more slowly than UO2 in 0.1 M H2O2.
The equation of state, structural behavior and phase stability of {alpha}-uranium have been investigated up to 1.3 TPa using density functional theory, adopting a simple description of electronic structure that neglects the spin-orbit coupling and strong electronic correlations. The comparison of the enthalpies of Cmcm (alpha-U), bcc, hcp, fcc, and bct predicts that the aplpha-U phase is stable up to a pressure of ~285 GPa, above which it transforms to a bct-U phase. The enthalpy differences between the bct and bcc phase decrease with pressure, but bcc is energetically unfavorable at least up to 1.3 TPa, the upper pressure limit of this study. The enthalpies of the close-packed hcp and fcc phases are 0.7 eV and 1.0 eV higher than that of the stable bct-U phase at a pressure of 1.3 TPa, supporting the wide stability field of the bcc phase. The equation of state, the lattice parameters and the anisotropic compression parameters are in good agreement with experiment up 100 GPa and previous theory. The elastic constants at the equilibrium volume of alpha-U confirm our bulk modulus. This suggests that our simplified description of electronic structure of uranium captures the relevant physics and may be used to describe bonding and other light actinides that show itinerant electronic behavior especially at high pressure.
Experiments have been performed to measure magnetoelectric properties of room temperature spirally ordered Sr3Co2Fe24O41 hexaferrite slabs. The measured properties include the magnetic permeability, the magnetization and the strain all as a function of the electric field E and the magnetic intensity H. The material hexaferrite Sr3Co2Fe24O41 exhibits broken symmetries for both time reversal and parity. The product of the two symmetries remains unbroken. This is the central feature of these magnetoelectric materials. A simple physical model is proposed to explain the magnetoelectric effect in these materials.
Vanadium dioxide (VO$_2$) undergoes a metal-insulator transition (MIT) at 340 K with the structural change between tetragonal and monoclinic crystals as the temperature is lowered. The conductivity $sigma$ drops at MIT by four orders of magnitude. The low-temperature monoclinic phase is known to have a lower ground-state energy. The existence of a $k$-vector ${boldsymbol k}$ is prerequisite for the conduction since the ${boldsymbol k}$ appears in the semiclassical equation of motion for the conduction electron (wave packet). Each wave packet is, by assumption, composed of the plane waves proceeding in the ${boldsymbol k}$ direction perpendicular to the plane. The tetragonal (VO$_2$)$_3$ unit cells are periodic along the crystals $x$-, $y$-, and z-axes, and hence there are three-dimensional $k$-vectors. The periodicity using the non-orthogonal bases does not legitimize the electron dynamics in solids. There are one-dimensional ${boldsymbol k}$ along the c-axis for a monoclinic crystal. We believe this decrease in the dimensionality of the $k$-vectors is the cause of the conductivity drop. Triclinic and trigonal (rhombohedral) crystals have no $k$-vectors, and hence they must be insulators. The majority carriers in graphite are electrons, which is shown by using an orthogonal unit cell for the hexagonal lattice.
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