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Oxygen as a control over 2.4 billion years of Earths atmospheric evolution

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 Added by Gregory Cooke
 Publication date 2021
  fields Physics
and research's language is English
 Authors Gregory Cooke




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Since the formation of the terrestrial planets, atmospheric loss has irreversibly altered their atmospheres, leading to remarkably different surface environments - Earth has remained habitable while Venus and Mars are apparently desolate. The concept of habitability centres around the availability of liquid water which depends greatly on the composition of the atmosphere. While the history of molecular oxygen O$_2$ in Earths atmosphere is debated, geological evidence supports at least two major episodes of increasing oxygenation: the Great Oxidation Event and the Neoproterozoic Oxidation Event. Both are thought to have been pivotal for the development and evolution of life. We demonstrate through three-dimensional simulations that atmospheric O$_2$ concentrations on Earth directly control the evolution and distribution of greenhouse gases (such as O$_3$, H$_2$O, CH$_4$ and CO$_2$) and the atmospheric temperature structure. In particular, at $leq 1$% the present atmospheric level (PAL) of O$_2$, the stratosphere collapses. Our simulations show that a biologically ineffective ozone shield, lower than previously thought, existed during the Proterozoic, with a need for a Phanerozoic ozone shield to allow the emergence of surface life. We find that O$_2$ acts as a valve for the loss rate of atmospheric hydrogen through the exosphere. Estimated levels of hydrogen escape for the Proterozoic eon are all lower than present day, enabling us to establish Earths water loss timeline. Furthermore, we demonstrate how O$_2$ on terrestrial exoplanets determines their theoretical transmission spectra, challenging signal-to-nose ratio assumptions contributing to the design of next generation telescopes that will facilitate the characterisation of Earth-like worlds.

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The magma ocean period was a critical phase determining how Earth atmosphere developed into habitability. However there are major uncertainties in the role of key processes such as outgassing from the planetary interior and escape of species to space that play a major role in determining the atmosphere of early Earth. We investigate the influence of outgassing of various species and escape of H$_2$ for different mantle redox states upon the composition and evolution of the atmosphere for the magma ocean period. We include an important new atmosphere-interior coupling mechanism namely the redox evolution of the mantle which strongly affects the outgassing of species. We simulate the volatile outgassing and chemical speciation at the surface for various redox states of the mantle by employing a C-H-O based chemical speciation model combined with an interior outgassing model. We then apply a line-by-line radiative transfer model to study the remote appearance of the planet in terms of the infrared emission and transmission. Finally, we use a parameterized diffusion-limited and XUV energy-driven atmospheric escape model to calculate the loss of H$_2$ to space. We have simulated the thermal emission and transmission spectra for reduced or oxidized atmospheres present during the magma ocean period of Earth. Reduced or thin atmospheres consisting of H$_2$ in abundance emit more radiation to space and have larger effective height as compared to oxidized or thick atmospheres which are abundant in H$_2$O and CO$_2$. We obtain the outgassing rates of H2 from the mantle into the atmosphere to be a factor of ten times larger than the rates of diffusion-limited escape to space. Our work presents useful insight into the development of Earth atmosphere during the magma ocean period as well as input to guide future studies discussing exoplanetary interior compositions.
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The radius valley, a bifurcation in the size distribution of small, close-in exoplanets, is hypothesized to be a signature of planetary atmospheric loss. Such an evolutionary phenomenon should depend on the age of the star-planet system. In this work, we study the temporal evolution of the radius valley using two independent determinations of host star ages among the California-Kepler Survey (CKS) sample. We find evidence for a wide and nearly empty void of planets in the period-radius diagram at the youngest system ages ($lesssim$2-3 Gyr) represented in the CKS sample. We show that the orbital period dependence of the radius valley among the younger CKS planets is consistent with that found among those planets with asteroseismically determined host star radii. Relative to previous studies of preferentially older planets, the radius valley determined among the younger planetary sample is shifted to smaller radii. This result is compatible with an atmospheric loss timescale on the order of gigayears for progenitors of the largest observed super-Earths. In support of this interpretation, we show that the planet sizes which appear to be unrepresented at ages $lesssim$2-3 Gyr are likely to correspond to planets with rocky compositions. Our results suggest the size distribution of close-in exoplanets, and the precise location of the radius valley, evolves over gigayears.
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