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Register a new userDesigning a Concentrated High-Efficiency Thermionic Solar Cell Enabled by Graphene Collector
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We propose a concentrated thermionic emission solar cell design, which demonstrates a high solar-to-electricity energy conversion efficiency larger than 10% under 600 sun, by harnessing the exceptional electrical, thermal and radiative properties of the graphene as a collector electrode. By constructing an analytical model that explicitly takes into account the non-Richardson behavior of the thermionic emission current from graphene, space charge effect in vacuum gap, and the various irreversible energy losses within the subcomponents, we perform a detailed characterization on the conversion efficiency limit and electrical power output characteristics of the proposed system. We systematically model and compare the energy conversion efficiency of various configurations of graphene-graphene and graphene-diamond and diamond-diamond thermionic emitter, and show that utilizing diamond films as an emitter and graphene as a collector offers the highest maximum efficiency, thus revealing the important role of graphene in achieving high-performance thermionic emission solar cell. A maximum efficiency of 12.8% under 800 sun has been revealed, which is significantly higher than several existing solid-state solar cell designs, such as the solar-driven thermoelectric and thermophotovoltaic converters. Our work thus opens up new avenues to advance the efficiency limit of thermionic solar energy conversion and the development of next-generation novel-nanomaterial-based solar energy harvesting technology.
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Accurate extraction of liquid is the first step towards low-volume liquid delivery and nanocharacterization, which plays a significant role in biomedical research. In this study, a tip-shaped graphene nanopipette (GNP) is proposed by encapsulating the biomolecule solution on the prefabricated metal tip with graphene. The volume of the encapsulated liquid is highly controllable at zeptoliter precision by tuning the encapsulating speed and the number of graphene encapsulation rounds. Using protein (ferritin) solution as an example, it has been confirmed by finite element analysis and the controlled experiments that the GNP allows the delivery of ferritin solution at the zeptoliter-scale. Furthermore, GNP is demonstrated as a new type of tip-shaped liquid cell, which is suitable for multiple nanocharacterization techniques. In particular, due to the ultra-sharp tip shape, isotope (13C)-labelled glucose solution encapsulated in GNP has been characterized by atom probe tomography (APT) in the laser-pulsed mode. Analysis of the mass spectrum and the reconstructed three-dimensional chemical maps reveals the quantitative distribution and the compositions of individual glucose molecules. The GNP is expected to be introduced to deliver liquid in the range of zeptoliters to attoliters, and brings a new capability for characterization of biological specimens in their near-native state.
Perovskite-based optoelectronic devices have gained significant attention due to their remarkable performance and low processing cost, particularly for solar cells. However, for perovskite light-emitting diodes (LEDs), non-radiative charge carrier recombination has limited electroluminescence (EL) efficiency. Here we demonstrate perovskite-polymer bulk heterostructure LEDs exhibiting record-high external quantum efficiencies (EQEs) exceeding 20%, and an EL half-life of 46 hours under continuous operation. This performance is achieved with an emissive layer comprising quasi-2D and 3D perovskites and an insulating polymer. Transient optical spectroscopy reveals that photogenerated excitations at the quasi-2D perovskite component migrate to lower-energy sites within 1 ps. The dominant component of the photoluminescence (PL) is primarily bimolecular and is characteristic of the 3D regions. From PL quantum efficiency and transient kinetics of the emissive layer with/without charge-transport contacts, we find non-radiative recombination pathways to be effectively eliminated. Light outcoupling from planar LEDs, as used in OLED displays, generally limits EQE to 20-30%, and we model our reported EL efficiency of over 20% in the forward direction to indicate the internal quantum efficiency (IQE) to be close to 100%. Together with the low drive voltages needed to achieve useful photon fluxes (2-3 V for 0.1-1 mA/cm2), these results establish that perovskite-based LEDs have significant potential for light-emission applications.
Ultrasound detection is one of the most important nondestructive subsurface characterization tools of materials, whose goal is to laterally resolve the subsurface structure with nanometer or even atomic resolution. In recent years, graphene resonators attracted attention as loudspeaker and ultrasound radio, showing its potential to realize communication systems with air-carried ultrasound. Here we show a graphene resonator that detects ultrasound vibrations propagating through the substrate on which it was fabricated. We achieve ultimately a resolution of $approx7$~pm/$mathrm{sqrt Hz}$ in ultrasound amplitude at frequencies up to 100~MHz. Thanks to an extremely high nonlinearity in the mechanical restoring force, the resonance frequency itself can also be used for ultrasound detection. We observe a shift of 120~kHz at a resonance frequency of 65~MHz for an induced vibration amplitude of 100~pm with a resolution of 25~pm. Remarkably, the nonlinearity also explains the generally observed asymmetry in the resonance frequency tuning of the resonator when pulled upon with an electrostatic gate. This work puts forward a sensor design that fits onto an atomic force microscope cantilever and therefore promises direct ultrasound detection at the nanoscale for nondestructive subsurface characterization.
We propose a frequency selective light trapping scheme that enables the creation of more visually-transparent and yet simultaneously more efficient semitransparent solar cells. A nanoparticle scattering layer and photonic stack back reflector create a selective trapping effect by total internal reflection within a medium, increasing absorption of IR light. We propose a strong frequency selective scattering layer using spherical TiO2 nanoparticles with radius of 255 nm and area density of 1.1% in a medium with index of refraction of 1.5. Using detailed numerical simulations for this configuration, we find that it is possible to create a semitransparent silicon solar cell that has a Shockley Queisser efficiency of 12.0%pm0.4% with a visible transparency of 60.2%pm1.3%, 13.3%pm1.3 more visibly-transparent than a bare silicon cell at the same efficiency.
Arrays of spin-torque nano-oscillators are promising for broadband microwave signal detection and processing, as well as for neuromorphic computing. In many of these applications, the oscillators should be engineered to have equally-spaced frequencies and equal sensitivity to microwave inputs. Here we design spin-torque nano-oscillator arrays with these rules and estimate their optimum size for a given sensitivity, as well as the frequency range that they cover. For this purpose, we explore analytically and numerically conditions to obtain vortex spin-torque nano-oscillators with equally-spaced gyrotropic oscillation frequencies and having all similar synchronization bandwidths to input microwave signals. We show that arrays of hundreds of oscillators covering ranges of several hundred MHz can be built taking into account nanofabrication constraints.
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