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Superconductivity in centrosymmetric topological superconductor candidate TaC

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 Added by Dayu Yan
 Publication date 2021
  fields Physics
and research's language is English




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We report the synthesis and physical properties of the single crystals of TaC, which are proposed to hold topological band structure as a topological superconductor (TSC) candidate. Magnetization, resistivity and specific heat measurements are performed and indicate that TaC is bulk superconductor with critical temperature of 10.3 K. TaC is a strongly coupled type-II superconductor and the superconducting state can be well described by s-wave Bardeen-Cooper-Schrieffer (BCS) theory with a single gap. The upper critical field (Hc2) of TaC shows linear temperature dependence, which is quite different from most conventional superconductors and isostructural NbC, which is proposed to manifest topological nodal-loops or type-II Dirac points as well as superconductivity. Our results suggest that TaC would be a new candidate for further research of TSCs.



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336 - Cong Ren , Hai Zi (1 2021
A notable characteristic of PbTaSe$_2$, a prototypical noncentrosymmetric (NCS) superconductor, is that its superconductivity can be modulated through a structural transition under hydrostatic pressure [Phys. Rev. B 95, 224508 (2017)]. Here we report on simultaneous pressure-sensitive point-contact Andreev reflection (PCAR) spectroscopy and bulk resistance measurements on PbTaSe$_2$, to elucidate the nature of the surface and bulk superconductivity and their evolution with hydrostatic pressure. It is found that in high pressure region the superconducting gap opening temperature $T_c^A$ is significantly lower that the bulk resistive transition temperature $T_c^R$, revealing a clear experimental signature of surface-bulk separation associated with enhanced antisymmetric spin-orbit coupling (ASOC). The PCAR spectra, reflecting the superconducting surface state, are analyzed with the Blonder-Tinkham-Klapwijk theory, yielding an isotropic $s$-wave full BCS-gap in the strong coupling regime. Analysis based on a modified McMillan formula indicates a sizable coupling strength contributed from ASOC for the superconducting surface state. These results suggest the coexistence of full gap $s$-wave superconductivity and topological surface states in PbTaSe$_2$, indicating that this NSC with significantly enhanced ASOC may offer a solid platform to investigate the topological aspect in the superconducting condensate.
Superconducting materials with a nontrivial band structure are potential candidates for topological superconductivity. Here, by combining muon-spin rotation and relaxation ($mu$SR) methods with theoretical calculations, we investigate the superconducting and topological properties of the rock-salt-type compounds NbC and TaC (with$T_c$ = 11.5 and 10.3 K, respectively). At a macroscopic level, the magnetization and heat-capacity measurements under applied magnetic field provide an upper critical field of 1.93 and 0.65 T for NbC and TaC, respectively. The low-temperature superfluid density, determined by transverse-field $mu$SR and electronic specific-heat data, suggest a fully-gapped superconducting state in both NbC and TaC, with a zero-temperature gap $Delta_0 = 1.90$ and 1.45 meV, and a magnetic penetration depth $lambda_0$ = 141 and 77 nm, respectively. Band-structure calculations suggest that the density of states at the Fermi level is dominated by the Nb $4d$- (or Ta $5d$-) orbitals, which are strongly hybridized with the C $p$-orbitals to produce large cylinder-like Fermi surfaces, similar to those of high-$T_c$ iron-based superconductors. Without considering the spin-orbit coupling (SOC) effect, the first Brillouin zone contains three closed node lines in the bulk band structure, protected by time-reversal and space-inversion symmetry. When considering SOC, its effects in the NbC case appear rather modest. Therefore, the node lines may be preserved in NbC, hence proposing it as a potential topological superconductor.
In recent years, signatures of Majorana fermions have been demonstrated experimentally in several superconducting systems. However, finding systems which can be scaled up to accommodate a large number of Majorana fermions for quantum computation remains a major challenge for experimentalists. In a recent work [1], signatures of a pair of Majorana zero modes (MZMs) were found in a new experimental platform formed by EuS islands deposited on top of a gold wire which were made superconducting through proximity coupling to a superconductor. In this work, we provide a theoretical explanation for how MZMs can be formed in EuS/Au/superconductor heterostructures. This simple experimental setup provides a new route for realizing a large number of Majorana fermions for quantum computations.
The discovery of signatures of topological superconductivity in superconducting bulk materials with topological surface states has attracted intensive research interests recently. Utilizing angle-resolved photoemission spectroscopy and first-principles calculations, here, we demonstrate the existence of topological nodal-line states and drumheadlike surface states in centrosymmetric superconductor SnTaS2, which is a type-II superconductor with a critical transition temperature of about 3 K. The valence bands from Ta 5d orbitals and the conduction bands from Sn 5p orbitals cross each other, forming two nodal lines in the vicinity of the Fermi energy without the inclusion of spin-orbit coupling (SOC), protected by the spatial-inversion symmetry and time-reversal symmetry. The nodal lines are gapped out by SOC. The drumheadlike surface states, the typical characteristics in nodal-line semimetals, are quite visible near the Fermi level. Our findings indicate that SnTaS2 offers a promising platform for exploring the exotic properties of the topological nodal-line fermions and gives a help to study topological superconductivity.
Superconductivity mediated by phonons is typically conventional, exhibiting a momentum-independent s-wave pairing function, due to the isotropic interactions between electrons and phonons along different crystalline directions. Here, by performing inelastic neutron scattering measurements on a superconducting single crystal of Sr0.1Bi2Se3, a prime candidate for realizing topological superconductivity by doping the topological insulator Bi2Se3, we find that there exist highly anisotropic phonons, with the linewidths of the acoustic phonons increasing substantially at long wavelengths, but only for those along the [001] direction. This observation indicates a large and singular electron-phonon coupling at small momenta, which we propose to give rise to the exotic p-wave nematic superconducting pairing in the MxBi2Se3 (M = Cu, Sr, Nb) superconductor family. Therefore, we show these superconductors to be example systems where electron-phonon interaction can induce more exotic superconducting pairing than the s-wave, consistent with the topological superconductivity.
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