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Register a new userSub-arcsecond Imaging of the Complex Organic Chemistry in Massive Star-forming Region G10.6-0.4
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Massive star-forming regions exhibit an extremely rich and diverse chemistry, which in principle provides a wealth of molecular probes, as well as laboratories for interstellar prebiotic chemistry. Since the chemical structure of these sources displays substantial spatial variation among species on small scales (${lesssim}10^4$ au), high angular resolution observations are needed to connect chemical structures to local environments and inform astrochemical models of massive star formation. To address this, we present ALMA 1.3 mm observations toward OB cluster-forming region G10.6-0.4 (hereafter G10.6) at a resolution of 0.14$^{primeprime}$ (700 au). We find highly-structured emission from complex organic molecules (COMs) throughout the central 20,000 au, including two hot molecular cores and several shells or filaments. We present spatially-resolved rotational temperature and column density maps for a large sample of COMs and warm gas tracers. These maps reveal a range of gas substructure in both O- and N-bearing species. We identify several spatial correlations that can be explained by existing models of COM formation, including NH$_2$CHO/HNCO and CH$_3$OCHO/CH$_3$OCH$_3$, but also observe unexpected distributions and correlations which suggest that our current understanding of COM formation is far from complete. Importantly, complex chemistry is observed throughout G10.6, rather than being confined to hot cores. The COM composition appears to be different in the cores compared to the more extended structures, which illustrates the importance of high spatial resolution observations of molecular gas in elucidating the physical and chemical processes associated with massive star formation.
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We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions representing different evolutionary stages, from early to evolved phases. We aim to identify potential correlations between the molecules and to trace their evolutionary sequence through the star formation process. We analysed spectra obtained at 3, 2, and 0.9 mm with the IRAM-30m telescope. We derived the main physical parameters for each species by fitting the molecular lines. We compared them and evaluated their evolution, also taking several other interstellar environments into account. We report detections in 20 sources, revealing a clear dust absorption effect on column densities. Derived abundances are ~$10^{-10}-10^{-7}$ for $CH_3OCHO$ and $CH_3OCH_3$, ~$10^{-12}-10^{-10}$ for $NH_2CHO$, and ~$10^{-11}-10^{-9}$ for $C_2H_5CN$. The abundances of $CH_3OCHO$, $CH_3OCH_3$, and $C_2H_5CN$ are very strongly correlated (r>0.92) across ~4 orders of magnitude. $CH_3OCHO$ and $CH_3OCH_3$ show the strongest correlations in most parameters, and a nearly constant ratio (~1) over a remarkable ~9 orders of magnitude in luminosity for a wide variety of sources: pre-stellar to evolved cores, low- to high-mass objects, shocks, Galactic clouds, and comets. This indicates that COMs chemistry is likely early developed and then preserved through evolved phases. Moreover, the molecular abundances clearly increase with evolution. We consider $CH_3OCHO$ and $CH_3OCH_3$ to be most likely chemically linked: they could e.g. share a common precursor, or be formed one from the other. We propose a general scenario for all COMs, involving a formation in the cold, earliest phases of star formation and a following increasing desorption with the progressive heating of the evolving core.
We have analyzed ALMA Cycle 5 data in Band 4 toward three low-mass young stellar objects (YSOs), IRAS 03235+3004 (hereafter IRAS 03235), IRAS 03245+3002 (IRAS 03245), and IRAS 03271+3013 (IRAS 03271), in the Perseus region. The HC$_{3}$N ($J=16-15$; $E_{rm {up}}/k = 59.4$ K) line has been detected in all of the target sources, while four CH$_{3}$OH lines ($E_{rm {up}}/k = 15.4-36.3$ K) have been detected only in IRAS 03245. Sizes of the HC$_{3}$N distributions ($sim 2930-3230$ au) in IRAS 03235 and IRAS 03245 are similar to those of the carbon-chain species in the warm carbon chain chemistry (WCCC) source L1527. The size of the CH$_{3}$OH emission in IRAS 03245 is $sim 1760$ au, which is slightly smaller than that of HC$_{3}$N in this source. We compare the CH$_{3}$OH/HC$_{3}$N abundance ratios observed in these sources with predictions of chemical models. We confirm that the observed ratio in IRAS 03245 agrees with the modeled values at temperatures around 30--35 K, which supports the HC$_{3}$N formation by the WCCC mechanism. In this temperature range, CH$_{3}$OH does not thermally desorb from dust grains. Non-thermal desorption mechanisms or gas-phase formation of CH$_{3}$OH seem to work efficiently around IRAS 03245. The fact that IRAS 03245 has the highest bolometric luminosity among the target sources seems to support these mechanisms, in particular the non-thermal desorption mechanisms.
We report 1.2 mm polarized continuum emission observations carried out with the Atacama Large Millimeter/submillimeter Array (ALMA) toward the high-mass star formation region G5.89-0.39. The observations show a prominent 0.2 pc north-south filamentary structure. The UCHII in G5.89-0.39 breaks the filament in two pieces. Its millimeter emission shows a dusty belt with a mass of 55-115 M$_{odot}$ and 4,500 au in radius, surrounding an inner part comprising mostly ionized gas with a dust emission only accounting about 30% of the total millimeter emission. We also found a lattice of convex arches which may be produced by dragged dust and gas from the explosive dispersal event involving the O5 Feldts star. The north-south filament has a mass between 300-600 M$_{odot}$ and harbours a cluster of about 20 millimeter envelopes with a median size and mass of 1700 au and 1.5 M$_{odot}$, respectively, some of which are already forming protostars. We interpret the polarized emission in the filament as mainly coming from magnetically aligned dust grains. The polarization fraction is ~4.4% in the filaments and 2.1% at the shell. The magnetic fields are along the North Filament and perpendicular to the South Filament. In the Central Shell, the magnetic fields are roughly radial in a ring surrounding the dusty belt between 4,500 and 7,500 au, similar to the pattern recently found in the surroundings of Orion BN/KL. This may be an independent observational signpost of explosive dispersal outflows and should be further investigated in other regions.
We have conducted mapping observations toward the n3 and n5 positions in the NGC,2264-D cluster-forming region with the Atacama Compact Array (ACA) of the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 3. Observations with 10000 au scale beam reveal the chemical composition at the clump scale. The spatial distributions of the observed low upper-state-energy lines of CH$_{3}$OH are similar to those of CS and SO, and the HC$_{3}$N emission seems to be predominantly associated with clumps containing young stellar objects. The turbulent gas induced by the star formation activities produces large-scale shock regions in NGC,2264-D, which are traced by the CH$_{3}$OH, CS and SO emissions. We derive the HC$_{3}$N, CH$_{3}$CN, and CH$_{3}$CHO abundances with respect to CH$_{3}$OH. Compared to the n5 field, the n3 field is farther (in projected apparent distance) from the neighboring NGC,2264-C, yet the chemical composition in the n3 field tends to be similar to that of the protostellar candidate CMM3 in NGC,2264-C. The HC$_{3}$N/CH$_{3}$OH ratios in the n3 field are higher than those in the n5 field. We find an anti-correlation between the HC$_{3}$N/CH$_{3}$OH ratio and their excitation temperatures. The low HC$_{3}$N/CH$_{3}$OH abundance ratio at the n5 field implies that the n5 field is an environment with more active star formation compared with the n3 field.
We present a composite model and radiative transfer simulations of the massive star forming core W33A MM1. The model was tailored to reproduce the complex features observed with ALMA at $approx 0.2$ arcsec resolution in CH$_3$CN and dust emission. The MM1 core is fragmented into six compact sources coexisting within $sim 1000$ au. In our models, three of these compact sources are better represented as disc-envelope systems around a central (proto)star, two as envelopes with a central object, and one as a pure envelope. The model of the most prominent object (Main) contains the most massive (proto)star ($M_starapprox7~M_odot$) and disc+envelope ($M_mathrm{gas}approx0.4~M_odot$), and is the most luminous ($L_mathrm{Main} sim 10^4~L_odot$). The model discs are small (a few hundred au) for all sources. The composite model shows that the elongated spiral-like feature converging to the MM1 core can be convincingly interpreted as a filamentary accretion flow that feeds the rising stellar system. The kinematics of this filament is reproduced by a parabolic trajectory with focus at the center of mass of the region. Radial collapse and fragmentation within this filament, as well as smaller filamentary flows between pairs of sources are proposed to exist. Our modelling supports an interpretation where what was once considered as a single massive star with a $sim 10^3$ au disc and envelope, is instead a forming stellar association which appears to be virialized and to form several low-mass stars per high-mass object.
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