No Arabic abstract
One of the most prevalent causes of bridge failure around the world is scour, the gradual erosion of soil around a bridge foundation due to fast-flowing water. A reliable technique for monitoring scour would help bridge engineers take timely countermeasures to safeguard against failure. Although vibration-based techniques for monitoring structural damage have had limited success, primarily due to insufficient sensitivity, these have tended to focus on the detection of local damage. High natural frequency sensitivity has recently been reported for scour damage. Previous experiments to investigate this have been limited as a result of the cost of full-scale testing and the fact that scaled-down soil structure models tested outside a centrifuge do not adequately simulate full-scale behaviour. This paper describes the development of what is believed to be the first-ever centrifuge-testing programme to establish the sensitivity of bridge natural frequency to scour. For the fundamental mode of vibration, these tests found up to a 40% variation in natural frequency for 30% loss of embedment. Models of three other types of foundation, which represent a shallow pad foundation, a deep pile bent and a deep monopile, were also tested in the centrifuge at different scour levels. The shallow foundation model showed lower frequency sensitivity to scour than the deep foundation models. The level of frequency sensitivity (3.1 to 44% per scour depth equivalent to 30% of embedment of scour) detected in this experiment demonstrates the potential for using natural frequency as an indicator of both local and global scour of bridges, particularly those with deep foundations.
A measure of nonclassicality of quantum states based on the volume of the negative part of the Wigner function is proposed. We analyze this quantity for Fock states, squeezed displaced Fock states and cat-like states defined as coherent superposition of two Gaussian wave packets.
The X-ray spectra of late type stars can generally be well fitted by a two temperature component model of the corona. We fnd that the temperature of both components are strong functions of stellar age, although the temperature of the hotter plasma in the corona shows a larger scatter and is probably affected by the activity of stars, such as flares. We confirm the power-law decay of the temperature of the hot plasma, but the temperature of the cool component decays linearly with log (age).
We explore chaos in the Kuramoto model with multimodal distributions of the natural frequencies of oscillators and provide a comprehensive description under what conditions chaos occurs. For a natural frequency distribution with $M$ peaks it is typical that there is a range of coupling strengths such that oscillators belonging to each peak form a synchronized cluster, but the clusters do not globally synchronize. We use collective coordinates to describe the inter- and intra-cluster dynamics, which reduces the Kuramoto model to $2M-1$ degrees of freedom. We show that under some assumptions, there is a time-scale splitting between the slow intracluster dynamics and fast intercluster dynamics, which reduces the collective coordinate model to an $M-1$ degree of freedom rescaled Kuramoto model. Therefore, four or more clusters are required to yield the three degrees of freedom necessary for chaos. However, the time-scale splitting breaks down if a cluster intermittently desynchronizes. We show that this intermittent desynchronization provides a mechanism for chaos for trimodal natural frequency distributions. In addition, we use collective coordinates to show analytically that chaos cannot occur for bimodal frequency distributions, even if they are asymmetric and if intermittent desynchronization occurs.
We use an optical centrifuge to excite coherent rotational wave packets in N$_2$O, CS$_2$ and OCS molecules with rotational quantum numbers reaching up to J=465, 690 and 1186, respectively. Time-resolved rotational spectroscopy at such ultra-high levels of rotational excitation can be used as a sensitive tool to probe the molecular potential energy surface at inter-nuclear distances far from their equilibrium values. Significant bond stretching in the centrifuged molecules results in the growing period of the rotational revivals, which are experimentally detected using coherent Raman scattering. We measure the revival period as a function of the centrifuge-induced rotational frequency and compare it with the numerical calculations based on the known Morse-cosine potentials.
Layered lead halide A2An-1PbnI3n+1 perovskites (2D LHPs) are attracting considerable attention as a more stable alternative with respect to APbI3 counterparts, a workhorse material for a new generation of solar cells. However, a critical analysis on the photostability of 2D perovskites comparing n = 1 to n > 3 and to APbI3 system is still missing. In this work, we perform a comparative study of BA$_2$MA$_{n-1}$Pb$_n$I$_{3n+1}$ (BA - butylammonium, MA - methylammonium) 2D LHPs with different layer number (n = 1-3), considered as study-case systems, and MAPbI3, as a reference. We discuss a stability testing protocol with general validity, comparing photometrical determination of iodine-containing products in nonpolar solvents, X-ray diffraction, and photoluminescence spectroscopy. We identify oxygen concentration as a critical factor affecting 2D perovskites photostability. This leads to a photocorrosion of LHPs that becomes highly dependent on the perovskite dimensionality and the chemical origin of atmosphere at the aging stage as confirmed by joint experimental and theoretical analyses. This mechanism, based on redox equilibriums with internal (I-/I2, Pb2+/Pb, RAH+/RA+H2) and external (O2/H2O) species, explains both a nonmonotonic dependence of 2D LHPs photostability in an inert atmosphere on the number n and a strong enhancement of photocorrosion rate under oxidizing environment.