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Roles of quantum coherences in thermal machines

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 Publication date 2020
  fields Physics
and research's language is English




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Some of the oldest and most important applications of thermodynamics are operations of refrigeration as well as production of useful energy. Part of the efforts to understand and develop thermodynamics in the quantum regime have been focusing on harnessing quantum effects to such operations. In this review we present the recent developments regarding the role of quantum coherences in the performances of thermal machines --the devices realising the above thermodynamic operations. While this is known to be an intricate subject, in part because being largely model-dependent, the review of the recent results allow us to identify some general tendencies and to suggest some future directions.



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The seminal work by Sadi Carnot in the early nineteenth century provided the blueprint of a reversible heat engine and the celebrated second law of thermodynamics eventually followed. Almost two centuries later, the quest to formulate a quantum theory of the thermodynamic laws has thus unsurprisingly motivated physicists to visualise what are known as `quantum thermal machines (QTMs). In this article, we review the prominent developments achieved in the theoretical construction as well as understanding of QTMs, beginning from the formulation of their earliest prototypes to recent models. We also present a detailed introduction and highlight recent progress in the rapidly developing field of `quantum batteries.
The precise estimation of small parameters is a challenging problem in quantum metrology. Here, we introduce a protocol for accurately measuring weak magnetic fields using a two-level magnetometer, which is coupled to two (hot and cold) thermal baths and operated as a two-stroke quantum thermal machine. Its working substance consists of a two-level system (TLS), generated by an unknown weak magnetic field acting on a qubit, and a second TLS arising due to the application of a known strong and tunable field on another qubit. Depending on this field, the machine may either act as an engine or a refrigerator. Under feasible conditions, determining this transition point allows to reduce the relative error of the measurement of the weak unknown magnetic field by the ratio of the temperatures of the colder bath to the hotter bath.
We explore the consequences of periodically modulating a quantum two-level system (TLS) with an asymmetric pulse when the system is in contact with thermal baths. By adopting the Floquet-Lindblad formalism for our analysis, we find that the unequal up and down time duration of the pulse has two main ramifications. First, the energy gap of the multiple sidebands or photon sectors created as a result of the periodic modulation are renormalized by a term which is dependent on both the modulation strength as well as the fraction of up (or down) time duration. Second, the weights of the different sidebands are no longer symmetrically distributed about the central band or zero photon sector. We illustrate the advantages of these findings in the context of applications in quantum thermal machines and thermometry. For a thermal machine constructed by coupling the TLS to two thermal baths, we demonstrate that the asymmetric pulse provides an extra degree of control over the mode of operation of the thermal machine. Further, by appropriately tuning the weight of the subbands, we also show that an asymmetric pulse may provide superior optimality in a recently proposed protocol for quantum thermometry, where dynamical control has been shown to enhance the precision of measurement.
Recent years have enjoyed an overwhelming interest in quantum thermodynamics, a field of research aimed at understanding thermodynamic tasks performed in the quantum regime. Further progress, however, seems to be obstructed by the lack of experimental implementations of thermal machines in which quantum effects play a decisive role. In this work, we introduce a blueprint of quantum field machines, which - once experimentally realized - would fill this gap. Even though the concept of the QFM presented here is very general and can be implemented in any many body quantum system that can be described by a quantum field theory. We provide here a detailed proposal how to realize a quantum machine in one-dimensional ultra-cold atomic gases, which consists of a set of modular operations giving rise to a piston. These can then be coupled sequentially to thermal baths, with the innovation that a quantum field takes up the role of the working fluid. In particular, we propose models for compression on the system to use it as a piston, and coupling to a bath that gives rise to a valve controlling heat flow. These models are derived within Bogoliubov theory, which allows us to study the operational primitives numerically in an efficient way. By composing the numerically modelled operational primitives we design complete quantum thermodynamic cycles that are shown to enable cooling and hence giving rise to a quantum field refrigerator. The active cooling achieved in this way can operate in regimes where existing cooling methods become ineffective. We describe the consequences of operating the machine at the quantum level and give an outlook of how this work serves as a road map to explore open questions in quantum information, quantum thermodynamic and the study of non-Markovian quantum dynamics.
We study coupled quantum systems as the working media of thermodynamic machines. Under a suitable phase-space transformation, the coupled systems can be expressed as a composition of independent subsystems. We find that for the coupled systems, the figures of merit, that is the efficiency for engine and the coefficient of performance for refrigerator, are bounded (both from above and from below) by the corresponding figures of merit of the independent subsystems. We also show that the optimum work extractable from a coupled system is upper bounded by the optimum work obtained from the uncoupled system, thereby showing that the quantum correlations do not help in optimal work extraction. Further, we study two explicit examples, coupled spin-$1/2$ systems and coupled quantum oscillators with analogous interactions. Interestingly, for particular kind of interactions, the efficiency of the coupled oscillators outperforms that of the coupled spin-$1/2$ systems when they work as heat engines. However, for the same interaction, the coefficient of performance behaves in a reverse manner, while the systems work as the refrigerator. Thus the same coupling can cause opposite effects in the figures of merit of heat engine and refrigerator.
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