Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userSulfur-driven Haze Formation in Warm CO2-rich Exoplanet Atmospheres
127
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relatively low concentrations (1.6%). It participates in both gas and solid phase chemistry, leading to the formation of other sulfur gas products (CH3SH/SO, C2H4S/OCS, SO2/S2, and CS2) and to an increase in solid haze particle production and compositional complexity. Our study shows that we may expect thicker haze with small particle sizes (20 to 140 nm) for warm CO2-rich exoplanet atmospheres that possess H2S.
rate research
Read More
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 h-1), but the particle size and production rate is dependent on the initial gas mixtures and the energy sources used in the simulation experiments. The gas phase mass spectra show that complex chemical processes happen in these atmospheres and generate new gas products that can further react to form larger molecules and solid haze particles. Two H2-rich atmospheres with similar C/O ratios (~0.5) yield different haze particles size, haze production rate, and gas products, suggesting both the elemental abundances and their bonding environments in an atmosphere can significantly affect the photochemistry. There is no methane (CH4) in our initial gas mixtures, although CH4 is often believed to be required to generate organic hazes. However, haze production rates from our experiments with different initial gas mixtures indicate that CH4 is neither required to generate organic hazes nor necessary to promote the organic haze formation. The variety and relative yield of the gas products indicate that CO and N2 enrich chemical reactions in H2-rich atmospheres.
We propose a classification of exoplanet atmospheres based on their H, C, O, N element abundances below about 600 K. Chemical equilibrium models were run for all combinations of H, C, N, O abundances, and three types of solutions were found, which are robust against variations of temperature, pressure and nitrogen abundance. Type A atmospheres contain H2O, CH4, NH3 and either H2 or N2, but only traces of CO2 and O2. Type B atmospheres contain O2, H2O, CO2 and N2, but only traces of CH4, NH3 and H2. Type C atmospheres contain H2O, CO2, CH4 and N2, but only traces of NH3, H2 and O2. Other molecules are only present in ppb or ppm concentrations in chemical equilibrium, depending on temperature. Type C atmospheres are not found in the solar system, where atmospheres are generally cold enough for water to condense, but exoplanets may well host such atmospheres. Our models show that graphite (soot) clouds can occur in type C atmospheres in addition to water clouds, which can occur in all types of atmospheres. Full equilibrium condensation models show that the outgassing from warm rock can naturally provide type C atmospheres. We conclude that type C atmospheres, if they exist, would lead to false positive detections of biosignatures in exoplanets when considering the coexistence of CH4 and CO2, and suggest other, more robust non-equilibrium markers.
Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for hazes produced under different energy sources, atmospheric compositions, and temperatures. The surface energies of the hazes were found to be the lowest around 400 K for the cold plasma samples, leading to the lowest removal rates. We show a suggestive correlation between haze surface energy and atmospheric haziness with planetary equilibrium temperature. We hypothesize that habitable zone exoplanets could be less hazy, as they would possess high-surface-energy hazes which can be removed efficiently.
Recent work has shown that sulfur hazes may arise in the atmospheres of some giant exoplanets due to the photolysis of H$_{2}$S. We investigate the impact such a haze would have on an exoplanets geometric albedo spectrum and how it may affect the direct imaging results of WFIRST, a planned NASA space telescope. For temperate (250 K $<$ T$_{rm eq}$ $<$ 700 K) Jupiter--mass planets, photochemical destruction of H$_{2}$S results in the production of $sim$1 ppmv of seight between 100 and 0.1 mbar, which, if cool enough, will condense to form a haze. Nominal haze masses are found to drastically alter a planets geometric albedo spectrum: whereas a clear atmosphere is dark at wavelengths between 0.5 and 1 $mu$m due to molecular absorption, the addition of a sulfur haze boosts the albedo there to $sim$0.7 due to scattering. Strong absorption by the haze shortward of 0.4 $mu$m results in albedos $<$0.1, in contrast to the high albedos produced by Rayleigh scattering in a clear atmosphere. As a result, the color of the planet shifts from blue to orange. The existence of a sulfur haze masks the molecular signatures of methane and water, thereby complicating the characterization of atmospheric composition. Detection of such a haze by WFIRST is possible, though discriminating between a sulfur haze and any other highly reflective, high altitude scatterer will require observations shortward of 0.4 $mu$m, which is currently beyond WFIRSTs design.
Central stages in the evolution of rocky, potentially habitable planets may play out under atmospheric conditions with a large inventory of non-dilute condensable components. Variations in condensate retention and accompanying changes in local lapse rate may substantially affect planetary climate and surface conditions, but there is currently no general theory to effectively describe such atmospheres. In this article, expanding on the work by Li et al. (2018), we generalize the single-component moist pseudoadiabat derivation in Pierrehumbert (2010) to allow for multiple condensing components of arbitrary diluteness and retained condensate fraction. The introduction of a freely tunable retained condensate fraction allows for a flexible, self-consistent treatment of atmospheres with non-dilute condensable components. To test the pseudoadiabats capabilities for simulating a diverse range of climates, we apply the formula to planetary atmospheres with compositions, surface pressures, and temperatures representing important stages with condensable-rich atmospheres in the evolution of terrestrial planets: a magma ocean planet in a runaway greenhouse state; a post-impact, late veneer-analogue planet with a complex atmospheric composition; and an Archean Earth-like planet near the outer edge of the classical circumstellar habitable zone. We find that variations in the retention of multiple non-dilute condensable species can significantly affect the lapse rate and in turn outgoing radiation and the spectral signatures of planetary atmospheres. The presented formulation allows for a more comprehensive treatment of the climate evolution of rocky exoplanets and early Earth analogues.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
