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Zero kinetic undercooling limit in the supercooled Stefan problem

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 Added by Mykhaylo Shkolnikov
 Publication date 2020
  fields Physics
and research's language is English




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We study the solutions of the one-phase supercooled Stefan problem with kinetic undercooling, which describes the freezing of a supercooled liquid, in one spatial dimension. Assuming that the initial temperature lies between the equilibrium freezing point and the characteristic invariant temperature throughout the liquid our main theorem shows that, as the kinetic undercooling parameter tends to zero, the free boundary converges to the (possibly irregular) free boundary in the supercooled Stefan problem without kinetic undercooling, whose uniqueness has been recently established in [DNS19], [LS18b]. The key tools in the proof are a Feynman-Kac formula, which expresses the free boundary in the problem with kinetic undercooling through a local time of a reflected process, and a resulting comparison principle for the free boundaries with different kinetic undercooling parameters.



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We consider the supercooled Stefan problem, which captures the freezing of a supercooled liquid, in one space dimension. A probabilistic reformulation of the problem allows to define global solutions, even in the presence of blow-ups of the freezing rate. We provide a complete description of such solutions, by relating the temperature distribution in the liquid to the regularity of the ice growth process. The latter is shown to transition between (i) continuous differentiability, (ii) Hu007folder continuity, and (iii) discontinuity. In particular, in the second regime we rediscover the square root behavior of the growth process pointed out by Stefan in his seminal paper [Ste89] from 1889 for the ordinary Stefan problem. In our second main theorem, we establish the uniqueness of the global solutions, a first result of this kind in the context of growth processes with singular self-excitation when blow-ups are present.
The supercooled Stefan problem and its variants describe the freezing of a supercooled liquid in physics, as well as the large system limits of systemic risk models in finance and of integrate-and-fire models in neuroscience. Adopting the physics terminology, the supercooled Stefan problem is known to feature a finite-time blow-up of the freezing rate for a wide range of initial temperature distributions in the liquid. Such a blow-up can result in a discontinuity of the liquid-solid boundary. In this paper, we prove that the natural Euler time-stepping scheme applied to a probabilistic formulation of the supercooled Stefan problem converges to the liquid-solid boundary of its physical solution globally in time, in the Skorokhod M1 topology. In the course of the proof, we give an explicit bound on the rate of local convergence for the time-stepping scheme. We also run numerical tests to compare our theoretical results to the practically observed convergence behavior.
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